Abstract: The present disclosure is directed to an optical filter that advantageously approximates sunlight that is both durable and stable for long periods of time when subject to harsh light intensity, thermal and moisture loads of accelerating weathering devices. The optical filter includes a glass having a lead content of between 0.5% and 50% by weight. In some examples, the filter can be constructed to have a thickness of 0.7 mm to 10 mm. In another aspect of the disclosure, the optical filter is part of an optical filter assembly suitable for manipulating spectral power distribution. The optical filter assembly includes a lead glass optical filter having a lead content of between 0.5% and 50% by weight and an ultraviolet transmissive optical filter. In one example, the ultraviolet transmissive optical filter is constructed from quartz glass. The ultraviolet transmissive optical filter can further include an infrared absorbing coating.

Abstract: The present invention relates to an imaged article comprising a substrate having a primed surface layer. The primed surface layer is comprised of a base polymer having a solubility parameter, molecular weight (Mw) and glass transition temperature within a specified range. The presence of the primer improves the overall image quality by improving at least one property including ink uptake, dot gain, color density and/or ink adhesion. Preferred primer compositions are soluble at least in part in the ink composition resulting in an increase in ink layer thickness that further improves the durability and/or day/night color balance. A variety of substrates may be primed including various sheeting for traffic control signage and commercial graphic films for advertising and promotional displays.

Abstract: The invention relates to methods of making a master and replicas thereof including tooling and retroreflective sheeting. The invention further relates to the corresponding master, tooling and in particular retroreflective sheeting. The method comprises forming V-shaped grooves in a substrate (e.g. metal plate) wherein the intersections of three grooves form cube-corner elements. The cube-corner elements are substantially the same size throughout the array. The master as well as corresponding tooling and sheeting preferably have an average groove spacing within the range of about 0.0005 inches (0.0127 mm) to about 0.007 inches (0.1778 mm) throughout the array and more preferably an average groove spacing of less than about 0.004 inches (0.1016 mm).

Abstract: A method of producing a substrate for a plasma display panel by providing a rib on a base, which comprises the steps of contacting a rib precursor containing a first photo-setting initiator having a first absorption edge and a first photo-setting component closely with said base; filling a mold, obtained by photo-setting of a second photo-setting initiator having a second absorption edge whose wavelength is shorter than a wavelength corresponding to said first absorption edge of said first photo-setting initiator, with said rib precursor; exposing said rib precursor to light having a wavelength longer than a wavelength corresponding to said second absorption edge, thereby setting said rib precursor; and removing said mold.

Abstract: Described are articles, laminates, sheets, coatings, retroreflective articles, pigments containing thioxanthone compounds that are fluorescent colorants.

Abstract: A method of producing barrier ribs for a plasma display panel substrate, which comprises the steps of: (a) partially filling a groove portion of a mold with a first photosensitive glass-ceramic paste selected from a photosensitive black glass-ceramic paste and a photosensitive white glass-ceramic paste, and curing the paste by irradiating with radiation; (b) supplying a second photosensitive glass-ceramic paste, which is different from the first photosensitive glass-ceramic paste, selected from the photosensitive black glass-ceramic paste and the photosensitive white glass-ceramic paste, on a glass base, and laminating the mold with the glass base through the second paste to form a laminate; (c) irradiating the laminate with radiation to form a rib precursor molded article composed of two white and black layers; (d) removing the mold from the glass base and the rib precursor molded article to transfer the rib precursor molded article to the glass base; and (e) sintering the rib precursor molded article to for

Abstract: The present invention relates to optical elements comprising fluorochemical surface treatments. The invention further relates to materials such as retroreflective sheetings, pavement markings and beaded projection screens comprising a binder and the surface treated optical elements. The fluorochemical surface treatment is substantially free of perfluoroalkyl groups having more than four carbon atoms. Preferably, the surface treatment is a polyfluoropolyether-based compound comprising at least one polar group or polar group-containing organic radical.

Abstract: The present invention relates to articles comprising a retroreflective sheeting, a release liner and an adhesive layer sandwiched between the substrate and release liner and methods of manufacturing such articles. The release liner has a relatively high coefficient of friction and has shrinkage properties that are substantially the same as or greater than the retroreflective sheeting. The article exhibits good roll stability, being substantially free of defects when supplied in a roll form.

Abstract: A method for molding and aligning microstructures on a patterned substrate using a microstructured mold. A slurry containing a mixture of a ceramic powder and a curable fugitive binder is placed between the microstructure of a stretchable mold and a patterned substrate. The mold can be stretched to align the microstructure of the mold with a predetermined portion of the patterned substrate. The slurry is hardened between the mold and the substrate. The mold is then removed to leave microstructures adhered to the substrate and aligned with the pattern of the substrate. The microstructures can be thermally heated to remove the binder and optimally fired to sinter the ceramic powder.

Abstract: A pavement marking composition, methods of applying, and pavement markings produced therefrom. The composition is a two-part coating composition having an amine component including one or more aspartic ester amines and optionally one or more amine-functional coreactants, an isocyanate component including one or more polyisocyanates, and material selected from the group of fillers, extenders, pigments, and combinations thereof.

Abstract: An apparatus is provided for producing a substrate for PDP, which can easily reduce ununiformity of a dielectric layer and defects of ribs. The apparatus is so constituted that it comprises: a table for the plate, a rib precursor supplying portion for providing a precusor of the ribs on the plate, a pliable mold having at least groove portions provided in parallel with each other at a fixed distance, which is disposed on the precursor of the ribs provided on the plate, a mold pressing portion for applying a pressure to the mold, thereby to contact the mold closely with the plate via the precursor of the ribs, and a driving portion for moving the mold pressing portion along the groove portions of the mold.

Abstract: The present invention relates to optical elements comprising fluorochemical surface treatments. The invention further relates to articles such as retroreflective sheetings, pavement markings and beaded projection screens comprising a binder and the surface treated optical elements. The surface treatment comprises at least one fluoropolymer selected from a) fluoropolymers comprising a fluorinated hydrocarbon backbone and side chains comprising at least one of fluoroalkyl, fluoroether alkyl, fluoroalkoxy and mixtures thereof; and b) fluoropolymers comprising a hydrocarbon backbone and side chains comprising at least one of fluoroether alkyl, fluoroalkoxy and mixtures thereof.

Abstract: A photocurable thermally transferable composition containing a multifunctional monomer that is substantially non-liquid at room temperature and a thermoplastic binder is disclosed. The composition is suitable for use in thermal transfer ribbons. After thermal transfer, the compositions are photocured to provide a durable, weatherable image on a graphic article.

Abstract: Thermal transfer articles of the invention comprising a carrier, optionally a release layer, a color layer releasably adhered thereto, and optionally an adherence layer on the bottom side of the color layer. Also graphic imaging compositions and methods for thermal transfer using such articles and compositions and graphic articles made by such methods. The transfer articles 1) exhibit thermoplastic, low cohesive properties during transfer such that good image resolution and transfer is achieved and 2) are radiation crosslinked after transfer such that a durable image is formed.

Abstract: The present invention relates to articles having a printed surface as well as flexible coating and film compositions that are printable in combination with exhibiting stain resistance. The composition comprises a hard component having an elongation of less than about 150%, a soft component having an elongation of greater than about 200%, and a cross-linking agent. The hard component preferably comprises a hydroxy functional thermoplastic polyurethane, hydroxy functional acrylic polymer, polymeric polyol or mixture thereof. The soft component preferably comprises a hydroxy functional thermoplastic urethane, polymeric polyol, or mixture thereof; whereas the cross-linking agent is preferably an isocyanate.

Abstract: The present invention relates to primed substrates comprising radiation cured ink jetted images and methods of ink jet printing radiation curable inks that employ applying a primer. The imaged articles are durable for outdoor usage. A variety of polymeric sheets may be primed including various sheeting for signage and commercial graphic films for advertising and promotional displays.

Abstract: The invention relates to new thioxanthone compounds having utility as fluorescent dyes and processes for their manufacture.

Abstract: The present invention relates to a method of printing polymer films and corresponding articles. The invention is useful for providing dimensional stability during printing and/or improving the print quality, particularly for contact or thermal printing methods such as thermal mass transfer printing.

Abstract: The present invention relates to a method for making a substantially cylindrical tool from a substantially planar substrate, wherein the tooling has at least one patterned surface. The resulting tooling includes a patterned surface with a sufficiently strong weld that is capable of producing an article having a pattern surface that has a relatively narrow and preferably cosmetically pleasing seam line. Such articles include retroreflective sheeting, structured abrasive articles, adhesive articles suitable for use in personal care products, and the like.

Abstract: Retroreflective pavement marking material comprising on the top surface thereof an enclosed-lens retroreflective sheet that comprises a monolayer of retroreflective elements wherein first portions of the monolayer are arranged in an upwardly contoured profile and second portions of the monolayer are arranged a lower, substantially planar position.