Patents Represented by Attorney, Agent or Law Firm Catherine Menes
  • Patent number: 6705398
    Abstract: A method for assessing the fracture pressure closure is proposed. This method includes first injecting a fluid into the formation at a first generally constant rate Q to create a fracture, and then, dropping the pumping rate to significantly smaller feed rate q so that the volume of the fracture becomes constant, in other words. As the fracture volume becomes constant at equilibrium, the well is shut-in. The wellbore pressure is monitored and the closure pressure is determined from the analysis of the wellbore pressure using a time-function of the dimensionless “shut-in” time, defined as the ratio of time since shutting to pumping time. This method provides a way of estimating the friction component of the monitored wellbore pressure due to the fracture tortuosity and friction. It is applicable to the art of fracturing subterranean formations and more particularly to the process of designing and analyzing stimulation treatments.
    Type: Grant
    Filed: June 24, 2002
    Date of Patent: March 16, 2004
    Assignee: Schlumberger Technology Corporation
    Inventor: Xiaowei Weng
  • Patent number: 6703352
    Abstract: Viscoelastic surfactant based aqueous fluid systems useful as thickening agents in various applications, e.g. to suspend particles produced during the excavation of geologic formations. The surfactants are zwitterionic/amphoteric surfactants such as dihydroxyl alkyl glycinate, alkyl ampho acetate or propionate, alkyl betaine, alkyl amidopropyl betaine and alkylimino mono- or di-propionates derived from certain waxes, fats and oils. The thickening agent is used in conjunction with an inorganic water-soluble salt or organic additive such as phthalic acid, salicylic acid or their salts.
    Type: Grant
    Filed: August 9, 2002
    Date of Patent: March 9, 2004
    Assignee: Schlumberger Technology Corporation
    Inventors: Manilal S. Dahayanake, Jiang Yang
  • Patent number: 6686323
    Abstract: A surfactant composition for use in well treatment, particularly for removing oil-based mud deposits from a well prior to cementing, comprises an alkylpolyglucoside in a solution of a mutual solvent for water and hydrocarbon. The composition can be used to formulate a chemical wash by dissolving the composition at a concentration of about 1%-10% (e.g. 5%) by weight in water or brine.
    Type: Grant
    Filed: June 12, 2002
    Date of Patent: February 3, 2004
    Assignee: Schlumberger Technology Corporation
    Inventors: Frederik Nilsson, Sylwia Komocki
  • Patent number: 6675895
    Abstract: The combination of the cement contamination laboratory measurements and the field log measurement allows to perform the evaluation of cement placement and quality related to the designed percentage cement displacement coverage and set-up times in the casing annulus. Since the logging time after the cement job is completed is known, a comparison between the acoustic impedance or compressive strength measured using the USI log and the acoustic impedance or the compressive strength measured in the laboratory, a level of mud contamination can be derived at every point across the wellbore. From the laboratory correlations, cement strength prediction with time can be established. This new product will give the operator an accurate tool to recommend performing remedial cementing with a higher success rate.
    Type: Grant
    Filed: July 31, 2002
    Date of Patent: January 13, 2004
    Assignee: Schlumberger Technology Corporation
    Inventors: Gamal Shehab, John F. Vaeth, Lucian K. Johnston
  • Patent number: 6668922
    Abstract: A method for designing acid treatments provides for the selection of optimal treatment for well stimulation wherein reservoir characteristics are obtained to further select the reaction kinetic data on the minerals of interests, the treatment to the reservoir is scaled up using a mathematical model and real time damage are computed based on bottomhole pressure and injection rate and compared to that predicted by the mathematical model to adjust the treatment. The model generated facilitates optimization of matrix treatments by providing a rapid quantitative evaluation of various treatment strategies for a formation. Stimulation with non-traditional fluid recipes containing mixtures of inorganic and organic acids, and chelating agents can be readily computed. The computed values can then be used in an economic model to justify the additional costs associated with the use of the non-traditional fluids.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: December 30, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Murtaza Ziauddin, Joel Robert
  • Patent number: 6667280
    Abstract: This Invention relates to a novel reversible thickener, i.e., a fluid whose viscosity can be carefully modulated—from very low viscosity to sufficient viscosity to act as a barrier to further flow; particularly preferred embodiments are directed to fluids and methods for stimulating hydrocarbon low viscosity to sufficient viscosity to act as a barrier to further flow; particularly preferred—bearing formations—i.e., to increase the production of oil/gas from the formation. In particular, the Present Invention is directed to a family of fluids (and methods incorporating those fluids) intended to be pumped through a wellbore and into the hydrocarbon-bearing formation.
    Type: Grant
    Filed: January 22, 2002
    Date of Patent: December 23, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Frank F. Chang, Qi Qu, Matthew J. Miller
  • Patent number: 6660693
    Abstract: Methods are provided for increasing the production of hydrocarbons from shaly formations that contain adsorbed condensed hydrocarbon gases by treating such formations with dewatering compositions comprising surfactants that cause the surfaces of the formation to be or to remain oil-wet. The methods may be used in stimulation (acidizing or acid fracturing or hydraulic fracturing), remediation or workover, and in enhancing flow from natural fractures or from unstimulated formations.
    Type: Grant
    Filed: August 8, 2001
    Date of Patent: December 9, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Matthew J. Miller, Curtis L. Boney, Kevin W. England, Jerald J. Hinkel
  • Patent number: 6656265
    Abstract: The present invention provides a cementing composition for an oil well or the like with porosity of less than 50%, and with a solid phase constituted by 35% to 65% (by volume) hollow microspheres, 20% to 45% Class G Portland cement, and 5% to 25% of Class G Portland micro-cement. The invention is used to cement conductor pipes in arctic zones or in deep water holes.
    Type: Grant
    Filed: July 17, 2001
    Date of Patent: December 2, 2003
    Assignee: Schlumberger Technology Corp.
    Inventors: André Garnier, Michel Michaux, Philippe Revil
  • Patent number: 6656266
    Abstract: Cementing compositions which are particularly suitable for squeeze cementing operations, comprise an aqueous phase, and a micro-cement, the aqueous phase including an aqueous suspension comprising a vinyl acetate type polymer obtained by chemically cross-linking a polyvinyl compound, a nanolatex and an anionic surfactant with a cloud point of more than 80° C.
    Type: Grant
    Filed: September 20, 2001
    Date of Patent: December 2, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Véronique Barlet-Gouedard, Pierre Maroy, Bruno Langlois, Roland Reeb
  • Patent number: 6645288
    Abstract: The present invention provides cementing compositions for oil wells or the like comprising an hydraulic binder and reinforcing particles constituted by a flexible material of low compressibility, and with an average grain size of less than 500 &mgr;m. The compositions of the invention are of particular advantage when cementing zones which are subjected to extreme dynamic stresses, such as perforation zones and the junctions of a multi-branch lateral well. They are also highly suitable for producing plugs.
    Type: Grant
    Filed: June 18, 2001
    Date of Patent: November 11, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Bernard Dargaud, Sylvaine Le Roy-Delage, Marc Thiercelin
  • Patent number: 6638896
    Abstract: The Invention relates to fluids and techniques to optimize/enhance the production of hydrocarbon from subterranean formations (e.g., “completion fluids”), in particular, fluids and techniques are. disclosed and claimed which remove wellbore damage and near-wellbore damage in the form of coating formed from drilling and production-related operations (“filtercake”); the techniques can be applied either by themselves or in conjunction with other completion operations, such as gravel packing; preferred embodiments are chelating agent and enzyme systems in a viscoelastic surfactant (VES) matrix.
    Type: Grant
    Filed: August 30, 2000
    Date of Patent: October 28, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Raymond J. Tibbles, Mehmet Parlar, Frank F. Chang, Diankui Fu, Jonathan Mark Davison, Elizabeth W. A. Morris, Antje M. Wierenga, Palathinkara S. Vinod
  • Patent number: 6637517
    Abstract: The improved recovery of hydrocarbons from subterranean formations by hydraulically fracturing a subterranean formation is accomplished. Fracturing fluids using a viscosifying surfactant fluid containing viscosifying micelles, for example, wormlike micelles, are useful to improve recovery of hydrocarbons and limit the loss of fracturing fluid into the formation fracture face. The invention further relates to novel fracturing and acidizing methods useful for increasing hydrocarbon production, limiting water production, resisting fracturing fluid loss into the subterranean formation, and reducing the equipment requirements in mixing and pumping fracturing fluid. The action of viscosifying micelles of surfactant in aqueous zones of the subterranean formation diverts fracturing fluid or acid from the aqueous zones to the hydrocarbon-bearing zones and also facilitates the flowback of increased amounts of hydrocarbons once a fractured well is placed back on production.
    Type: Grant
    Filed: January 17, 2002
    Date of Patent: October 28, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Mathew M. Samuel, Frank F. Chang, Roger J. Card, Ronnie L. Thomas
  • Patent number: 6632778
    Abstract: Herein is described a fluid that is useful in consolidating a formation without the use of a gravel pack and screen. In particular, the fluid is useful in consolidating heterogeneous formations where the permeability is not uniform over-the total formation thickness, e.g. a formation having at least a first layer and a second layer, wherein the permeability of the first layer is greater than that of the second layer. The fluid comprises at least one of a resin, a curing agent, and a surfactant, wherein the fluid is self-diverting. Optionally, a catalyst or other additives, such as an oil wetting agent, can be used. Fluids of the present invention are self-diverting, i.e.
    Type: Grant
    Filed: May 2, 2000
    Date of Patent: October 14, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Joseph A. Ayoub, John P. Crawshaw, Paul W. Way
  • Patent number: 6631764
    Abstract: A method of gravel packing a wellbore which has at least one aperture therein that provides a fluid flow path between the wellbore and an adjacent subterranean formation. At least a part of the formation adjacent to the open hole has a filter cake coated thereon that comprises a water and oil emulsion. The method of gravel packing comprises injecting into the wellbore a gravel pack composition that comprises gravel and a carrier fluid. The carrier fluid comprises an aqueous liquid having a pH that is outside the range at which the filter cake emulsion is stable. The aqueous liquid is present in an amount effective to invert the water in oil emulsion in the filter cake when the carrier fluid comes into contact with the filter cake. As a result, gravel is deposited at or adjacent to the aperture in the wellbore and some of the filter cake is removed.
    Type: Grant
    Filed: February 6, 2001
    Date of Patent: October 14, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Mehmet Parlar, Colin J. Price-Smith, Raymond J. Tibbles, Shrihari Kelkar, Mark E. Brady, Elizabeth W. A. Morris
  • Patent number: 6616751
    Abstract: A cementing composition comprising a hydraulic cement powder dispersed in a solvent that is miscible both with water and hydrocarbons to make a slurry. The cement powder can be made up simply of hydraulic cement materials or can be a mixture of such materials with particles that are inert or reactive with cement. The composition can also include surfactants or retarders. The composition is used to plug water production in a well while leaving hydrocarbon production unaffected.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: September 9, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Pierre Maroy, Jack Maberry
  • Patent number: 6613720
    Abstract: The effect of various chemical or biological agents in well treatment fluids can be delayed by sequestering the agents in the discontinuous phase of an emulsion for a period of time, before the emulsion is destabilized by exposure to at least one of: (1) a change in temperature, (2) a change in pH, (3) a change in salinity, (4) a change in alcohol concentration, (5) a change in stabilizing surfactant concentration, (6) a change in organic ion concentration, (7) a change in destabilizing surfactant concentration, (8) a change in surfactant adsorbent material concentration, (9) an ultrasonic pulse, and (10) an electrical field. Upon exposure to the emulsion destabilizing condition, the agent sequestered in the discontinuous phase of the emulsion is released into the continuous phase of the fluid composition, where it can have its intended effect.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: September 2, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Jean Pierre Feraud, Michael D. Parris, Richard D. Hutchins, Stanley Bruce McConnell, Erik B. Nelson, Keith Dismuke
  • Patent number: 6608005
    Abstract: Non-aqueous base wellbore fluids characterized by enhanced electrical conductivity due to formulation with specified ionic liquids are disclosed. Drilling, completion, and workover methods utilizing the wellbore fluids are also disclosed.
    Type: Grant
    Filed: April 9, 2001
    Date of Patent: August 19, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Bentley J. Palmer, Diankui Fu, Roger Card, Edgar Volpert
  • Patent number: 6605570
    Abstract: Herein is disclosed a well completion or stimulation fluid, comprising (i) a carrier fluid; (ii) a viscoelastic surfactant; and (iii) a fluid loss control additive (FLA) comprising at least one polymer and at least one crosslinker. The fluid may further comprise proppant or gravel, if it is intended for use as a fracturing fluid or a gravel packing fluid, although such uses do not require that the fluid comprise proppant or gravel. Also disclosed herein are methods of fracturing a subterranean formation, comprising (i) providing a fracturing fluid discussed above and (ii) injecting the fracturing fluid into the formation at a pressure sufficiently high to fracture the formation. In addition, disclosed herein are methods of gravel packing a wellbore, comprising (i) providing a gravel packing fluid discussed above and (ii) injecting the gravel packing fluid into the wellbore.
    Type: Grant
    Filed: May 8, 2001
    Date of Patent: August 12, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Matthew J. Miller, Mathew Samuel, Palathinkara S. Vinod, Thomas N. Olsen
  • Patent number: 6599863
    Abstract: The invention provides a method of fracturing, including the provision and use of a fracturing fluid suspension containing an effective amount of a solid particulate breaker material having delayed breaking or degradation characteristics, additionally including an amount of durable fibers and/or platelets sufficient to enhance wellbore solids, such as proppant, transport. In a preferred aspect, solid particulate matter, which comprises or is composed of a specified organic polymeric compound or composition having an average molecular weight of at least 10,000, or a mixture of such compounds or compositions, and which solid organic polymeric matter reacts or decomposes, as described, is combined in a fracturing fluid with or containing a specified gellant and proppant, to form a fracturing fluid suspension, and the suspension formed is pumped downwell and deposited as a gelled suspension in the subterranean formation, generally under fracturing conditions.
    Type: Grant
    Filed: August 20, 1999
    Date of Patent: July 29, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Bentley J. Palmer, Jesse Lee
  • Patent number: D483299
    Type: Grant
    Filed: December 7, 1999
    Date of Patent: December 9, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Terry L. McCafferty, Joseph K. Flowers, Matthew E. Wilson