Abstract: Waterborne polyurethane dispersions are prepared by reacting (1) at least one polyisocyanate; (2) at least one active hydrogen containing compound, such as a polyol or a polyamide; and (3) preferably also at least one water-dispersability enhancing compound having water-dispersion enhancing groups, in order to form an isocyanate terminated prepolymer. The prepolymer subsequently is (1) optionally neutralized by reaction with at least one neutralizing agent, (2) dispersed in water, and then (3) chain extended by reaction with at least one of water, inorganic or organic polyamine having an average of about 2 or more primary and/or secondary amine groups, or combinations thereof. At least one plasticizer is introduced into the reaction mixture at any time during prepolymer formation or before the prepolymer is dispersed in water. The plasitcizer substantially or completely replaces other organic diluents or solvents. Various types of plasticizers may be employed, including reactive plasticizers.

Abstract: This invention relates to a blend of polymers having electrostatic dissipative properties. The blend in particular comprises a thermoplastic base polymer, electrostatic dissipative agent and acrylic ESD enhancer.

Abstract: A mixture of an amine-terminated liquid polymer and a non-cycloaliphatic epoxy resin cures rapidly at ambient temperatures under water while displacing water from substrate surfaces and bonding strongly thereto. The mixture comprises (A) 1 equivalent of at least one non-cycloaliphatic epoxy resin, (B) from about 0.01 to about 1.5 equivalents of at least one amine-terminated liquid polymer having a carbon-carbon backbone, (C) optionally, a chain extender or crosslinker, (D) optionally, a curing agent, and (E) optionally, other compounding ingredients. The mixture is useful as an underwater repair putty, adhesive, coating or the like.

Abstract: Amine molybdates retard smoke formation effectively when vinyl chloride and vinylidene chloride polymers burn.

Abstract: Hydroxyl-terminated liquid polymers having an aliphatic polymeric backbone and sulfide linkages near the terminal portions of the polymer molecule are prepared by polymerizing (1) at least one vinylidene monomer having at least one terminal CH.sub.2 .dbd.C< group per monomer molecule, together with (2) a mixture of at least one hydroxyl-containing disulfide and at least one hydroxyl-containing trisulfide. Use of the above disulfide-trisulfide mixture permits viscosity control during polymerization with substantially less disulfide required than if the disulfide alone were used, and the resulting polymers have less odor and discolor less upon heating than if the disulfide alone were used.

Abstract: Amine molybdates retard smoke formation effectively during burning of certain organic polymers.

Abstract: Amine molybdates retard smoke formation effectively when vinyl chloride and vinylidene chloride polymers burn.

Abstract: Hydroxyl-containing alkyl acrylate liquid polymers containing polymerized therein from about 1 weight percent to about 20 weight percent N-vinyl-2-pyrrolidone have improved clarity, and pressure-sensitive adhesives made from such liquid polymers have both improved clarity and adhesion.

Abstract: A pressure-sensitive adhesive comprises the reaction product of (A) at least one alkyl acrylate liquid polymer containing both terminal and random hydroxyl functionality, and (B) at least one prepolymer of a polyester glycol or a polyalkylene ether glycol with an excess amount of an aromatic diisocyanate. The adhesive has a full range of desirable adhesive properties, including excellent rolling ball tack, 180.degree. peel adhesion and shear adhesion. The adhesive is useful in both solvent and solvent-free systems.

Abstract: At least one alkylnorbornene, wherein the alkyl group contains from 8 to 12 carbon atoms, is copolymerized by ring opening with (1) at least one acyclic monoolefin or nonconjugated acyclic olefin and (2) optionally, dicyclopentadiene. These copolymers have substantially lower glass transition temperatures than lower alkylnorbornene copolymers and can be injection molded to make appliance housings and the like, or calendered and thermoformed to make, for example, automotive goods such as glovebox covers and the like.

Abstract: 1,2-Dihydrodicyclopentadiene is copolymerized by ring opening with (1) norbornene, at least one alkylnorbornene or a mixture thereof and (2) at least one acyclic monoolefin or nonconjugated acyclic olefin. The copolymers can be calendered and thermoformed, for example, to make rigid automotive goods such as glovebox covers, hubcaps, and the like.

Abstract: Dimethylnorbornene, isopropylnorbornene or a mixture thereof is copolymerized by ring opening with (1) at least one acyclic monoolefin or nonconjugated acyclic olefin and (2) optionally, dicyclopentadiene. The copolymers are thermoplastics which can be calendered and thermoformed, for example, to make rigid automotive goods such as glovebox covers, hubcaps and the like.

Abstract: Benzofuranylphenols are produced by (1) reacting glyoxal with a phenol in the presence of an acidic catalyst to form an acetal, and (2) thereafter partially hydrolyzing the acetal with an acidic or basic catalyst. Some benzofuranylphenols are effective stabilizers of organic materials against the deleterious effects of oxygen, heat and light. The stability of dienic polymers and styrene-acrylonitrile copolymers is particularly enhanced by incorporating stabilizing amounts of some benzofuranylphenols.

Abstract: Amine-terminated liquid polymers are prepared by reacting a carboxyl-terminated, ester-terminated or acid chloride-terminated liquid polymer having a carbon-carbon backbone with at least one aliphatic, alicyclic, heterocyclic or aromatic amine containing at least two secondary or mixed primary/secondary amine groups, but no more than one primary amine group per molecule. The novel amine-terminated polymers are useful as elastic vulcanizates, polymeric cure agents, tougheners and flexibilizers for epoxy resins, in paints and coatings, in sealants and adhesives, and the like.

Abstract: Certain thermoplastic polymer blends have tensile strengths greater than that of any one polymer component. The blends comprise (1) at least one ethylene-propylene-diene (EPDM) polymer, (2) at least one ethylene-ethyl acrylate (EEA) polymer, and (3) optionally, at least one polyethylene. The blends are prepared by mixing physically the polymer components under heat and shear conditions. No curing or crosslinking agents are needed to obtain the superior tensile strengths of the thermoplastic blends. The blends are useful to prepare tubing, sheet products, wire and cable insulation, molded items and the like.

Abstract: Amine molybdates retard smoke formation effectively during burning of certain organic polymers.

Abstract: Room-temperature-curable compositions can be prepared readily by mixing (A) 100 parts by weight of at least one non-cycloaliphatic epoxy resin and (B) from about 1 to about 1,000 parts by weight of at least one amine-terminated liquid polymer having a carbon-carbon backbone, (C) optionally, a chain extender or crosslinker and (D) optionally, a curing agent. The compositions are useful as castable elastomeric systems, as toughened structural plastics, as paints and coatings, as sealants and adhesives, and the like.

Abstract: Hydroxyl-containing liquid polymers having an aliphatic polymeric backbone and sulfide linkages near the terminal portions of the polymer molecule are prepared by polymerizing (1) at least one of selected vinylidene monomers having at least one terminal CH.sub.2 =C< group per monomer molecule, together with (2) at least one hydroxyl-containing disulfide in the presence of (3) ultraviolet radiation.

Abstract: At least one norbornene-type monomer is copolymerized with about 0% to about 95% by weight of dicyclopentadiene, based upon total polymer weight. The polymerization is primarily by ring opening and is conducted in the presence of (1) a catalyst comprising (a) at least one compound selected from the group consisting of dialkylaluminum iodides, alkylaluminum diiodides and mixtures of trialkylaluminum compounds with iodine, (b) at least one dialkylaluminum chloride or alkylaluminum dichloride and (c) at least one monomer- or solvent-soluble tungsten compound, and (2) at least one nonconjugated acyclic olefin having at least one hydrogen on each double-bonded carbon atom. Catalyst components (a) and (b) are charged before catalyst component (c). Use of a catalyst containing components (a), (b) and (c) produces easy-processing and substantially gel-free polymers, whereas a catalyst containing only (a) and (c) or only (b) and (c) produces heavily gelled polymers.

Abstract: At least one vinylidene halide monomer is polymerized in an aqueous emulsion medium in admixture with ammonium persulfate and at least one ammoniated anionic emulsifier, preferably also together with hydrogen peroxide. The polymerization process is maintained at a pH of at least about 8.5 using ammonium hydroxide. The polymerization process is conducted in the substantial absence of alkali metal ions. Polymerization is both rapid and linear. The resulting polymers have excellent heat stability and water whitening resistance.