Patents Represented by Attorney Charles E. Bricker
  • Patent number: 6541161
    Abstract: An electrolyte for an electrochemical cell consisting of a di-lithium phthalocyanine.
    Type: Grant
    Filed: September 10, 2001
    Date of Patent: April 1, 2003
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventor: Lawrence G. Scanlon, Jr.
  • Patent number: 6437081
    Abstract: Oxyallyl pendent polymer system having repeating units of the formulae hereinafter referred to as structure A, wherein x has a value of about 0.1 to 1.0 and y has a value of 1.0-x, and hereinafter referred to as structure B, wherein the sum of p+q has a value of about 0.1 to 1.0, r has a value of 1.0-(p+q) and the molar ratio of p:q is about 9:1 to 1:9, wherein Bz is a benzazole unit selected from the group consisting of wherein X is —O—, —S— or —NH—, and R is selected from the group consisting of and wherein Ar is an aromatic group.
    Type: Grant
    Filed: February 13, 2001
    Date of Patent: August 20, 2002
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Fred E. Arnold, Thuy D. Dang, Robert J. Spry, Max D. Alexander
  • Patent number: 6432683
    Abstract: A method for the preparation of 2-aminomuconate which comprises adding 2-aminophenol to a mixture of 2-aminophenol 1,6-dioxygenase, 2-aminomuconic semialdehyde dehydrogenase and NAD+ (nicotinamide adenine dinucleotide, oxidized form) in a buffer, and recovering a fraction containing 2-aminomuconate from the mixture.
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: August 13, 2002
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Zhongqi He, Jim C. Spain
  • Patent number: 6392009
    Abstract: Benzobisazole polymers having repeating units of the formula wherein Z is wherein X is —S—, —O— or —NH—.
    Type: Grant
    Filed: February 13, 2001
    Date of Patent: May 21, 2002
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Fred E. Arnold, Thuy D. Dang, Narayanan Venkatasubramanian
  • Patent number: 6362313
    Abstract: Allyl pendent benzazole polymer system having repeating units of the formula: wherein Bz is a benzazole unit selected from the group consisting of wherein X is —O—, —S— or —NH—, and R is selected from the group consisting of wherein Ar is an aromatic group; and wherein x has a value of about 1.0 to 0.1 and y has a value of 1.0−x.
    Type: Grant
    Filed: February 13, 2001
    Date of Patent: March 26, 2002
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Fred E. Arnold, Thuy D. Dang
  • Patent number: 6359149
    Abstract: Provided are novel, electropolymerizable monomers of the formulae: wherein R1,R2 and R3 are selected from the group consisting of —H, —O(CH2)nCH3, wherein n has a value of 0 to 11 and m has a value of 1 to 4, and wherein no more than one of R2 and R3 is —H. Also provided are polymers resulting from the electropolymerization of these monomers.
    Type: Grant
    Filed: February 2, 2000
    Date of Patent: March 19, 2002
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Loon-Seng Tan, Balasubramanian Sankaran
  • Patent number: 6355765
    Abstract: A wholly aromatic copolyester having repeating units of the formula: wherein Ar1 is wherein Q is selected from the group consisting of —H, —CH3, —CF3, —Cl, —Br, and —C6H5; wherein Ar2 is selected from the group consisting of wherein X is selected from the group consisting of —Br, —Cl, —CH3 and —C6H5; wherein Ar3 is wherein Ar4 is selected from the group consisting of wherein m has a value of 0.05 to 0.95 and n has a value of 100-m, is characterized by accessible nematic-isotropic transition temperatures providing outstanding orientational order and mechanical properties.
    Type: Grant
    Filed: September 25, 2000
    Date of Patent: March 12, 2002
    Assignee: United States of America as represented by the Secretary of the Air Force
    Inventors: Patrick T. Mather, Devdatt S. Nagvekar, Hong G. Jeon, Loon-Seng Tan
  • Patent number: 6340398
    Abstract: A method for enhancing the oxidation resistance of substrates fabricated from metallic molybdenum and alloys containing at least 50% molybdenum which comprises depositing silicon on the surface of the substrate under conditions which cause the formation of an outer layer of MoSi2. Also disclosed is a method for enhancing the oxidation resistance of other substrates, such as carbon-carbon and metals and alloys which show minimal reaction with molybdenum under the coating conditions, which comprises depositing a layer of molybdenum on the surface, then depositing silicon on the molybdenum layer under conditions which cause the formation of an outer layer of MoSi2.
    Type: Grant
    Filed: April 4, 2000
    Date of Patent: January 22, 2002
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Triplicane A. Parthasarathy, Madan G. Mendiratta, Dennis M. Dimiduk
  • Patent number: 6326337
    Abstract: An oxidation-corrosion additive for enhancing the stability of PFPAEs which has the formula: wherein Q is —Rf or —S—Rf, Rf is a perfluoroalkyl or perfluoroalkylether group having 1 to 30 carbon atoms, x and y are integers, each having a value of 0-5, wherein the sum of x and y is in the range of 1 to 10. In the formula above, Rf may be linear or branched. The additive can be a single component or a mixture of components varying in the number and relative positions of x and y. The additive can be used alone or with other suitable additives in PFPAE base fluids.
    Type: Grant
    Filed: April 4, 2001
    Date of Patent: December 4, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Kalathil C. Eapen, Grace J. Chen, Wayne E. Ward, Harvey L. Paige
  • Patent number: 6326196
    Abstract: The cell line HeLa is transformed with the chromosomal insertion of the plasmid pSV2neoNR101, ATCC No. 69617. The transformed cells, HeLaNR1, produce diazoluminomelanin (DALM) intra cellularly when provided with nitrate, luminol and 3-amino-L-tyrosine•HC1 (3AT). The modified cells can be used to study mechanisms for radiofrequency and light radiation interactions with carcinoma of the cervix. The effects of drugs, hormones, and cytokines that affect the expression of nitric oxide synthase and its activity can also be studied to understand the effects of these materials on cervix cells.
    Type: Grant
    Filed: January 22, 2001
    Date of Patent: December 4, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Jill E. Parker, Johnathan L. Kiel
  • Patent number: 6309703
    Abstract: This invention is a rapid low-cost technique for manufacturing thick high-performance carbon and ceramic composites in the form of uniformly densified near-net shaped structures. This is accomplished by impregnating composite preforms with low-viscosity wetting monomers which undergo polymerization followed by pyrolysis reactions in the preform ultimately creating ceramic and/or carbon matrices. Since the monomers possess low-molecular-weight they have low viscosities. Thus, if they wet the fiber and partially-densified preform they can easily impregnate even the smallest pores. Once inside the preforms, polymerization of the monomers is then initiated, resulting in a liquid matrix-precursor of the high molecular weight needed to produce a superior matrix (upon pyrolysis) with high efficiency.
    Type: Grant
    Filed: June 8, 1998
    Date of Patent: October 30, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Phillip G. Wapner, Wesley P. Hoffman, Steven Jones
  • Patent number: 6300502
    Abstract: Provided are chromophores with very large two-photon absorption cross-sections. One group of these chromophores has the formula: (T—Q)n—N—Phm wherein Q is a single bond or 1,4-phenylene, Ph is a phenyl group, n has a value of 1-3 and m has a value of 3−n, and wherein T is wherein R1 and R2 are alkyl groups having 1 to 20 carbon atoms, provided that when Q is a single bond, the value of n is 2 or 3. Another group of these chromophores has the formula: (T—Q)n—G—Phm wherein T is as defined above, Q is a single bond or 1,4-phenylene, Ph is a phenyl group, n has a value of 1-4 and m has a value of 4−n, and wherein G is a 4-arm core unit. Yet another group of these chromophores has the formula: (T—Q)n—G—Phm wherein T is as described previously, Q is a single bond or 1,4-phenylene, Ph is a phenyl group, n has a value of 1-6 and m has a value of 6−n, and wherein G is a 6-arm core unit.
    Type: Grant
    Filed: December 8, 2000
    Date of Patent: October 9, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Ramamurthi Kannan, Bruce A. Reinhardt, Loon-Seng Tan
  • Patent number: 6291621
    Abstract: Provided are novel, electropolymerizable monomers of the formulae: wherein R1, R2 and R3 are selected from the group consisting of —H, —O(CH2)nCH3, wherein n has a value of 0 to 11 and m has a value of 1 to 4, and wherein no more than one of R2 and R3 is —H. Also provided are polymers resulting from the electropolymerization of these monomers.
    Type: Grant
    Filed: February 23, 1999
    Date of Patent: September 18, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Loon-Seng Tan, Balasubramanian Sankaran
  • Patent number: 6291537
    Abstract: Controlled and thorough stabilization of pitch is provided by incorporating an oxidant into the pitch. In one embodiment of the invention, the oxidant is intimately mixed with the pitch. In another embodiment, the oxidant is encapsulated in a suitable encapsulant and the encapsulated oxidant is intimately mixed with the pitch. This material is particularly useful in the preparation of a carbon-carbon composite, but is also useful for preparing fibers and solid preforms.
    Type: Grant
    Filed: March 28, 2000
    Date of Patent: September 18, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: David L. Ciminelli, Partha P. Paul, Niraj Vasishtha
  • Patent number: 6251815
    Abstract: A thermal gradient resistant fiber-reinforced composite structure which has a hot operating side and an opposite cool operating side and a thickness &tgr; therebetween. In one embodiment, the composite has two regions: hot and cool. The hot region consists essentially of a fiber having a first coefficient of thermal expansion and a matrix material and the cool region consists essentially of a fiber having a second coefficient of thermal expansion and a matrix material. In this embodiment, the hot region has a thickness &tgr;H of about 10 to 90 percent of the total thickness &tgr; between the hot side and the cool side, and the cool region has a thickness &tgr;C of about 90 to 10 percent of the total thickness &tgr;. In a second embodiment, the composite has a hot operating side and an opposite cool operating side and a thickness &tgr;′ therebetween. In this embodiment, the composite has three regions: hot, intermediate and cool.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: June 26, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Triplicane A. Parthasarathy, Ronald J. Kerans
  • Patent number: 6248580
    Abstract: Dinitrotoluene present as a contaminant in a sample, is degraded by the steps of (a) providing a sample comprising dinitrotoluene; (b) adding to the sample at least one bacterial strain capable of degrading at least one dinitrotoluene isomer under aerobic conditions; (c) producing aerobic conditions in the sample; and (d) maintaining the aerobic conditions in the sample for a time that is sufficient for the bacteria to degrade said dinitrotoluene. In one embodiment, at least one bacterial strain capable of degrading the 2,4-dinitrotoluene isomer under aerobic conditions is added to the sample. In another embodiment, at least one bacterial strain capable of degrading the 2,6-dinitrotoluene isomer under aerobic conditions is added to the sample. In yet another embodiment, at least one bacterial strain capable of degrading both the 2,4-dinitrotoluene isomer and the 2,6-dinitrotoluene isomer under aerobic conditions is added to the sample.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: June 19, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Jim C. Spain, Shirley F. Nishino, Urs Lendenmann
  • Patent number: 6221942
    Abstract: A carbon-rich zirconia-silica sol is prepared by the steps of dissolving zirconyl nitrate hydrate in absolute ethanol, mixing the solution thus obtained with a silicon alkoxide, and mixing the latter solution with a polyelectrolyte. The resulting carbon-rich sol/polyelectrolyte mixture can be employed to coat continuous fiber tow or filaments, to make nanosized zircon powder and to make a porous zircon membrane material.
    Type: Grant
    Filed: August 23, 1999
    Date of Patent: April 24, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Emmanuel E. Boakye, Randall S. Hay, Triplicane A. Parthasarathy, M. Dennis Petry
  • Patent number: 6218344
    Abstract: Lubricants for satellite applications consist essentially of a base fluid having low volatility and a minor amount, i.e., about 0.1 to 10 weight percent, of a chlorinated tris(phenoxyphenyl)phosphate.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: April 17, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Lois J. Gschwender, Carl E. Snyder, Jr.
  • Patent number: H1988
    Abstract: Methods are presented to produce duplex (DP) microstructures, nearly lamellar (NL) microstructures, and fully TMT lamellar (TMTL) microstructures in gamma titanium aluminide alloy articles. The key step for obtaining a specific type of microstructure is the post-hot work annealing treatment at a temperature in a specific range for the desired microstructure. The annealing temperatures range from Te+100° C. to T&agr;−25° C. for duplex (DP) microstructures, from T&agr;−25° C. to T&agr;−5° C. for nearly lamellar (NL) microstructures, and from T&agr; to T&agr;+60° C. for fully TMT lamellar (TMTL) microstructures, where Te is the titanium-aluminum eutectoid temperature of the alloy and T&agr; is the alpha transus temperature of the alloy. The times required for producing specific microstructures range from 2 min to 15 hours depending on microstructural type, alloy composition, annealing temperature selected, material section size, and desired grain-size.
    Type: Grant
    Filed: June 30, 1998
    Date of Patent: September 4, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Young-Won Kim, Dennis M. Dimiduk
  • Patent number: H2006
    Abstract: A method for repairing scratches, dings, gouges or other minor imperfections in finishes applied by flame spraying, fluidized bed, hot flocking, electrostatic spray or electrostatic fluidized bed, which comprises dissolving a coating material in a suitable solvent, applying the resulting solution to a selected area, evaporating the solvent, and, optionally, curing the coating material.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: November 6, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventor: David F. Ellicks