Abstract: The invention is directed to bridged metallocene catalyst complexes that are sufficiently soluble in aliphatic solvents to be particularly suitable for solution olefin polymerization processes such that olefin copolymers can be prepared with high molecular weights and catalyst activities particularly at high polymerization reaction temperatures. More specifically, the invention particularly relates to a polymerization process for ethylene copolymers having a density of about 0.850 to about 0.940 comprising contacting, under solution polymerization conditions at a reaction temperature at or above 60° C. to 250° C.
Abstract: The described invention provides a low fouling, high particle density polymerization process and an olefin polymerization cocatalyst activator composition comprising a cross-linked polymer bead having a surface area of from about 1 to 20 m2/g to which are bound a plurality of non-coordinating anions, where the polymeric support comprises ligands covalently bound to the central metal or metalloid atoms of said anions, and an effective number of cationic species to achieve a balanced charge. The invention also provides an olefin polymerization catalyst compositions comprising the reaction product of a) the foregoing cocatalyst activator, and b) an organometallic transition metal compound having ancillary ligands, at least one labile ligand capable of abstraction by protonation and at least one labile ligand into which an olefinic monomer can insert for polymerization.
Type:
Grant
Filed:
March 26, 1999
Date of Patent:
July 30, 2002
Assignee:
Exxon Mobil Chemical Patents Inc.
Inventors:
John F. Walzer, Jr., Anthony J. Dias, Jean M J Frechet, Stephen B. Roscoe
Abstract: A hot melt pressure sensitive adhesive for use with oriented polypropylene films is provided. The adhesive composition comprises an elastomeric component which is a blend of styrene-isoprene block copolymers and styrene-butadiene block copolymers mixed with a tackifier component. The tackifier component is a blend of at least two hydrocarbon resins, the first being compatible with the styrene-isoprene block copolymer and the second being compatible with the styrene-butadiene block copolymer.