Patents Represented by Attorney Charles L. Harness
  • Patent number: 4385155
    Abstract: Poly(vinyl acetate) latex reacted with an aldehyde at acid pH to prepare crosslinked poly(vinyl alcohol) suitable as water-loss agent in drilling fluids.
    Type: Grant
    Filed: December 2, 1981
    Date of Patent: May 24, 1983
    Assignee: W. R. Grace & Co.
    Inventor: Alan S. Michaels
  • Patent number: 4364912
    Abstract: The Hill process for control of post-precipitation in wet process phosphoric acid can be made to work on low-iron phosphate rock, without the need of added perlite or other aluminum silicate.
    Type: Grant
    Filed: July 20, 1981
    Date of Patent: December 21, 1982
    Assignee: W. R. Grace & Co.
    Inventor: Richard N. Hill
  • Patent number: 4313752
    Abstract: Treatment of sugarcane with 2,2-Dimethylvaleric acid enhances growth.
    Type: Grant
    Filed: August 26, 1980
    Date of Patent: February 2, 1982
    Assignee: W. R. Grace & Co.
    Inventor: Sidney R. Siemer
  • Patent number: 4306991
    Abstract: This invention relates to an improved composition for inhibiting deposition of scale in aqueous systems. More specifically, it relates to the use of small quantities of an improved composition for preventing formation of scale and sludge deposits in steam generating boilers. The composition is characterized by the fact that by using a plurality of selected ingredients a synergistic effect is obtained. The ingredients comprise a copolymer of styrene sulfonic acid and maleic anhydride or maleic acid, along with a water soluble organophosphonic acid compound.
    Type: Grant
    Filed: July 31, 1980
    Date of Patent: December 22, 1981
    Assignee: Chemed Corporation
    Inventors: Chih M. Hwa, Dionisio G. Cuisia
  • Patent number: 4305915
    Abstract: Wet-process phosphoric acid products substantially free of post precipitation.
    Type: Grant
    Filed: July 3, 1979
    Date of Patent: December 15, 1981
    Assignee: W. R. Grace & Co.
    Inventor: Richard N. Hill
  • Patent number: 4301131
    Abstract: This invention is directed to an improvement in the Hill phosphoric acid process, whereby the Hill process can be used with high-iron phosphate rock. The improvement involves oxidation of divalent iron in an early stage of the Hill process, followed by addition of a soluble potassium compound to the acid in the crystallizer.
    Type: Grant
    Filed: November 28, 1980
    Date of Patent: November 17, 1981
    Assignee: W. R. Grace & Co.
    Inventor: Moises G. Sanchez
  • Patent number: 4298018
    Abstract: Method of pumping viscous liquids, e.g., detergents, using an eductor and a predetermined intermittent cycle.
    Type: Grant
    Filed: July 29, 1980
    Date of Patent: November 3, 1981
    Assignee: Chemed Corporation
    Inventor: William J. Haggard
  • Patent number: 4294809
    Abstract: Aeration of Hill phosphoric acid, preferably with perlite, and preferably with a chemical oxidant, e.g., H.sub.2 O.sub.2. Gives good post-precipitation control with high-iron phosphate rock, even in winter conditions.
    Type: Grant
    Filed: September 29, 1980
    Date of Patent: October 13, 1981
    Assignee: W. R. Grace & Co.
    Inventor: Richard N. Hill
  • Patent number: 4293311
    Abstract: In the Hill phosphoric acid process the crystallizer underflow is divided into a major stream and a minor stream. The major stream goes to the clarifier and the minor stream to the aluminum silicate addition vessel.
    Type: Grant
    Filed: January 10, 1980
    Date of Patent: October 6, 1981
    Assignee: W. R. Grace & Co.
    Inventor: Richard N. Hill
  • Patent number: 4279877
    Abstract: Improvement in the Hill phosphoric acid process. Fe.sup.++ in high iron feed is oxidized to Fe.sup.+++ to improve post-precipitation characteristics, optionally, a minor stream from the crystallizer is returned to the oxidation zone.
    Type: Grant
    Filed: January 10, 1980
    Date of Patent: July 21, 1981
    Assignee: W. R. Grace & Co.
    Inventors: Richard N. Hill, Moises G. Sanchez
  • Patent number: 4278635
    Abstract: A method for boiler water treatment to retard corrosion due to dissolved oxygen. Hydroquinone and certain related compounds are highly effective oxygen scavengers for use in boiler water and thereby effect reduction of corrosion resulting from dissolved oxygen.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: July 14, 1981
    Assignee: Chemed Corporation
    Inventor: Herman Kerst
  • Patent number: 4256703
    Abstract: To a coal-fired furnace that uses electrostatic precipitation or a mechanical collector to collect fly ash, a mix of magnesia-alumina or magnesia-talc is added above the fireball (2600.degree.-3300.degree. F.). The additive increases the mean particle size of the fly ash and reduces its surface resistivity, thereby causing improved collection in the electrostatic precipitators or mechanical collector. Fine particulates containing heavy metals tend to be agglomerated; thus the invention permits recovery of substantial amounts of heavy metal contaminants that would otherwise be lost as stack emission.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: March 17, 1981
    Assignee: Chemed Corporation
    Inventors: Shyam N. S. Dixit, Douglas I. Bain, David A. Carter
  • Patent number: 4255259
    Abstract: This invention relates to an improved method for inhibiting deposition of scale in aqueous systems. More specifically, it relates to the use of small quantities of an improved composition for preventing formation of scale and sludge deposits in steam generating boilers. The composition is characterized by the fact that by using a plurality of selected ingredients a synergistic effect is obtained. The ingredients comprise a copolymer of styrene sulfonic acid and maleic anhydride or maleic acid, along with a water soluble organophosphonic acid compound.
    Type: Grant
    Filed: September 18, 1979
    Date of Patent: March 10, 1981
    Assignee: Chemed Corporation
    Inventors: Chih M. Hwa, Dionisio G. Cuisia
  • Patent number: 4250154
    Abstract: Prevention of re-post precipitation in concentrated wet process phosphoric acid by heating the acid at 55.degree. to 85.degree. C. thereby to dissolve solids without substantial re-post precipitation.
    Type: Grant
    Filed: October 22, 1979
    Date of Patent: February 10, 1981
    Assignee: W. R. Grace & Co.
    Inventor: Richard N. Hill
  • Patent number: 4248728
    Abstract: A paste type scouring cleanser containing colloidal magnesium aluminum silicate, alkali, optionally a bleach, zeolite, optionally an abrasive, a surfactant, and optionally sodium hexametaphosphate, all in aqueous dispersion.
    Type: Grant
    Filed: February 28, 1979
    Date of Patent: February 3, 1981
    Assignee: Chemed Corporation
    Inventor: Robert L. Puryear
  • Patent number: 4248846
    Abstract: This invention is directed to improvements in making wet process phosphoric acid substantially free from post-precipitation. The improvements include recycling to the reaction train a side stream produced by the process; cooling one or more of the streams of the process; and/or addition of sulfuric acid to an evaporator.
    Type: Grant
    Filed: July 3, 1979
    Date of Patent: February 3, 1981
    Assignee: W. R. Grace & Co.
    Inventor: Richard N. Hill
  • Patent number: 4245573
    Abstract: An additive, e. g., MgO.Mg silicate, is injected into the flue gas stream of a coal-or oil-fired furnace, at 2300-1700 deg. F., thereby reducing accumulation of sulfuric acid on the air heater inlet and outlet.
    Type: Grant
    Filed: December 22, 1978
    Date of Patent: January 20, 1981
    Assignee: Chemed Corporation
    Inventors: Shyam N. S. Dixit, Douglas I. Bain, David A. Carter
  • Patent number: 4242198
    Abstract: Improvement in the reduction of Mg, Ca, Na, K and Al in crude phosphoric acid using an ion exchange resin bed, comprising preclarifying the feed acid with flocculant polymer and placing a filter aid precoat on the resin bed. As part of the preclarification process, a compatible soluble sodium compound, such as sodium carbonate, is added to the feed acid to speed the flocculation process.
    Type: Grant
    Filed: March 12, 1979
    Date of Patent: December 30, 1980
    Assignee: W. R. Grace & Co.
    Inventor: Richard N. Hill
  • Patent number: 4242216
    Abstract: Dichlorodimethyl hydantoin stabilized for use in alkaline detergent formulations by forming granules or briquettes of a minimum size and hardness.
    Type: Grant
    Filed: September 27, 1979
    Date of Patent: December 30, 1980
    Assignee: Chemed Corporation
    Inventors: Denny E. Daugherty, Edwin R. Loder, Gary L. Young
  • Patent number: 4239526
    Abstract: Sucrose yield of sugarcane is increased by treating the cane crop a few weeks prior to harvest with a ripening agent comprising a substituted urea.
    Type: Grant
    Filed: September 4, 1979
    Date of Patent: December 16, 1980
    Assignee: W. R. Grace & Co.
    Inventor: Sidney R. Siemer