Abstract: A photopolymerizable composition, which contains a polymeric binder, a compound which can be polymerized by free radicals and has at least one terminal ethylenic double bond and a photoinitiator combination comprising an N-heterocyclic compound, a thioxanthone derivative and a dialkylamino compound, is highly photosensitive and produces photoresist stencils with vertical side walls.

Abstract: Systems, apparatus combinations and methods for producing a powder coating are provided wherein a stream of a powder coating precursor including at least one resin and at least one additional powder coating ingredient is contacted with a process fluid effective to reduce the viscosity of the powder coating precursor to allow processing of the powder coating precursor at a lower temperature.

Abstract: A photopolymerizable composition, which contains a polymeric binder, a compound which can be polymerized by free radicals and has at least one terminal ethylenic double bond and a photoinitiator combination comprising an N-heterocyclic compound, a thioxanthone derivative and a dialkylamino compound, is highly photosensitive and produces photoresist stencils with vertical side walls.

Abstract: A stabilized aqueous solution of a diazo compound has the formula: ##STR1## where X.sup.1 is selected from nitro and chloro, X.sup.2 is selected from nitro, chloro and hydrogen, and Y is an acid-derived anion. The solution has a pH of about 1.5 or below and a diazo concentration of about 2 wt % or less. The solution is useful as an extractant/developer for petroleum fuel markers.

Abstract: A thermoplastic resin containing a flame-retarding magnesium hydroxide has its workability enhanced by a sorbitan ester in admixture with the resin and flame retardant. An admixture of the resin, magnesium hydroxide, and ester may be either a mixture of discrete particles of each of said components of the composition or a mixture of the resin and a magnesium hydroxide powder whose particles have a coating of the ester.

Abstract: Coating powder compositions comprise A) between about 60 and about 90 wt %, relative to total weight of A) plus B) plus C), of an acrylic polymer having a weight average molecular weight of between about 1000 and about 30,000, a carboxylic acid equivalent weight of from about 300 to about 1000 and a glass transition temperature of about 45.degree. C. or above and B) between about 5 and about 30 wt %, relative to total weight of A) plus B) plus C) of an adduct prepared from i) between about 20 and about 50 wt %, relative to total weight of i) plus ii), of a curing agent reactive with carboxylic acid groups and ii) between about 50 and about 80 wt %, relative to total weight of i) plus ii), of a polyester resin formed primarily from linear aliphatic diols and dicarboxylic acids, the polyester having functional groups reactive with said curing agent i), and C) between about 2 and about 30 wt % relative to the total weight of A) plus B) plus C) of a curing agent reactive with carboxylic acid groups.

Abstract: Coating powder compositions comprise A) between about 60 and about 90 wt %, relative to total weight of A) plus B) plus C), of an acrylic polymer having a weight average molecular weight of between about 1000 and about 30,000, a carboxylic acid equivalent weight of from about 300 to about 1000 and a glass transition temperature of about 45.degree. C. or above and B) between about 5 and about 30 wt %, relative to total weight of A) plus B) plus C) of an adduct prepared from i) between about 20 and about 50 wt %, relative to total weight of i) plus ii), of a curing agent reactive with carboxylic acid groups and ii) between about 50 and about 80 wt %, relative to total weight of i) plus ii), of a polyester resin formed primarily from linear aliphatic diols and dicarboxylic acids, the polyester having functional groups reactive with said curing agent i), and C) between about 2 and about 30 wt % relative to the total weight of A) plus B) plus C) of a curing agent reactive with carboxylic acid groups.

Abstract: A composition and method for stripping tin or tin-lead alloys, and any underlying copper-tin intermetallic, from a copper surface. The composition includes an aqueous solution of approximately 5-60% nitric acid by weight, approximately 0.5-30% ferric nitrate by weight, and a nitric acid stabilizer selected from the group consisting of an amino-triazole, an amino-isoxazole, and a linear amino sulfone in the form H.sub.2 N--SO.sub.2 --R, where R is any alkyl or benzene group, wherein the stabilizer is present at a concentration sufficient to inhibit exothermic conditions, emission of toxic NOx gas, and copper attack. A soluble source of halogen ion, such as hydrochloric acid, can be added to the composition to yield a uniform, reflective, bright pink copper appearance, and to further reduce sludge formation. In addition, sludge formation can be eliminated by adding a soluble source of sulfate ion (SO.sub.4.sup.-2) to the composition.

Abstract: Systems and apparatus combinations for producing a powder coating are provided wherein a stream of a powder coating precursor including at least one resin and at least one additional powder coating ingredient is contacted with a process fluid effective to reduce the viscosity of the powder coating precursor to allow processing of the powder coating precursor at a lower temperature.

Abstract: A polyester-based coating composition capable of forming a striated pattern on a metal surface at a film thickness less than half of that of PVC plastisol films is provided by a thixotropic composition having a thix index of from about 1.5 to about 3 and comprising a hydroxy-functional polyester, a thixotropy-inducing rheologic agent and curing agent. The striated coating is applied to sheet metal in a coil coating operation by introducing the composition into a paint pan of a coil coater, transferring said composition from said paint pan to an applicator roll by rotating a pick-up roll in contact with the composition and with said applicator roll; continuously withdrawing a sheet of metal from a coil thereof and coating said sheet by contacting it with the applicator roll; curing the coating on said sheet by passing the sheet through an oven at an elevated temperature; and continuously rewinding said sheet into a coil.

Abstract: A composition and method for stripping tin or tin-lead alloys, and any underlying copper-tin intermetallic, from a copper surface. The composition includes an aqueous solution of approximately 5-60% nitric acid by weight, approximately 0.5-30% ferric nitrate by weight, and a nitric acid stabilizer selected from the group consisting of an amino-triazole, an amino-isoxazole, and a linear amino sulfone in the form H.sub.2 N-SO.sub.2 -R, where R is any alkyl or benzene group, wherein the stabilizer is present at a concentration sufficient to inhibit exothermic conditions, emission of toxic NOx gas, and copper attack. A soluble source of halogen ion, such as hydrochloric acid, can be added to the composition to yield a uniform, reflective, bright pink copper appearance, and to further reduce sludge formation. In addition, sludge formation can be eliminated by adding a soluble source of sulfate ion (SO.sub.4.sup.-2) to the composition.

Abstract: A waterborne photoimageable composition, developable in alkaline aqueous solution, which is hardenable to form a hard, permanent layer suitable as a solder mask, comprisesA) between about 25 and about 40 wt % of a latex acrylic binder polymer having an acid number between about 125 and about 200 and a number average molecular weight of between about 20,000 and about 80,000,B) between about 13 and about 30 wt % of a waterborne epoxy resin having an epoxy equivalent weight of between about 100 and about 700,C) between about 20 and about 35 wt % of photopolymerizable, multi-functional .alpha.,.beta.-ethylenically unsaturated monomer and/or short-chain oligomer having a molecular weight between about 500 and about 2000,D) between about 4 and about 20 wt % of a free-radical generating chemical system,E) between about 0.5 and about 10 wt % of an epoxy curative and/or cure catalyst, andF) between about 3 and about 12 wt % surfactant(s), the weight percentages being based on total weight of A)-F).

Abstract: In a coating powder composition comprising A) a polyester resin having carboxyl functionality so as to provide an acid number of between about 15 and about 100, plus B) epoxy curative at a stoichiometric equivalent relative to said polyester resin of between about 0.7 and about 1.3, blooming in the cured coating resulting therefrom is reduced or eliminated by incorporating within the polyester resin A) the monomer 2-butyl, 2-ethyl, 1,3-propane diol (BEPD) at a level to provide between 2 and 25 mole percent of the hydroxyl functionality relative to total hydroxyl functionality of hydroxyl-functional monomers forming the polyester resin.

Abstract: A polyester-based coating composition capable of forming a striated pattern on a metal surface at a film thickness less than half of that of PVC plastisol films is provided by a thixotropic composition having a thix index of from about 1.5 to about 3 and comprising a hydroxy-functional polyester, a thixotropy-inducing rheologic agent and curing agent. The striated coating is applied to sheet metal in a coil coating operation by introducing the composition into a paint pan of a coil coater, transferring said composition from said paint pan to an applicator roll by rotating a pick-up roll in contact with the composition and with said applicator roll; continuously withdrawing a sheet of metal from a coil thereof and coating said sheet by contacting it with the applicator roll; curing the coating on said sheet by passing the sheet through an oven at an elevated temperature; and continuously rewinding said sheet into a coil.

Abstract: An electrically chargeable dielectric coating powder and a triboelectric coating process for applying the powder to wood substrates are described. The coating powder is a mass of finely divided, heat fusible dielectric plastic material having an average particle size (Mv) of between 30 and 45 microns and a particle size distribution (all percents defined in weight percent) of:95%-100% smaller than 88 microns,5%-15% smaller than 15.56 microns and0%-6% smaller than 11 microns.Preferably the coating powder has 0% larger than 88 microns and an Mv=about 30-40, preferably 35-40 microns. More preferably the particle distribution further includes10%-15% smaller than 15.56 microns and4%-6% smaller than 11 microns, andan Mv of between about 35 and 36 microns. Most preferably the particle distribution further includes:about 11.5% smaller than 15.56 microns andabout 4.3% smaller than 11 microns, andan Mv of about 35.9. Preferably the powder is a thermosetting resin composition.

Abstract: Powdered coating compositions and methods for obtaining improved wrinkled finishes with epoxy powder coatings are provided which utilize a color stabilizer effective to avoid an excessive red color shift upon cure of the composition.

Abstract: Powdered coating compositions and methods for obtaining improved wrinkled finishes with epoxy powder coatings are provided which utilize curing agents other than commercially available methylenedisalicylic acid.

Abstract: An electrically chargeable dielectric coating powder and a triboelectric coating process for applying the powder to substrates are described. The coating powder is a mass of finely divided, heat fusible dielectric plastic material having an average particle size (Mv) of between 30 and 45 microns and a particle size distribution (all percents defined in weight percent) of:95%-100% smaller than 88 microns,5%-15% smaller than 15.56 microns and0%-6% smaller than 11 microns.Preferably the coating powder has 0% larger than 88 microns and an Mv=about 30-40, preferably 35-40 microns. More preferably the particle distribution further includes10%-15% smaller than 15.56 microns and4%-6% smaller than 11 microns, andan Mv of between about 35 and 36 microns. Most preferably the particle distribution further includes:about 11.5% smaller than 15.56 microns andabout 4.3% smaller than 11 microns, andan Mv of about 35.9. Preferably the powder is a thermosetting resin composition.

Abstract: An electrically chargeable dielectric coating powder and a triboelectric coating process for applying the powder to wood substrates are described. The coating powder is a mass of finely divided, heat fusible dielectric plastic material having an average particle size (Mv) of between 30 and 45 microns and a particle size distribution (all percents defined in weight percent) of:95%-100% smaller than 88 microns,5%-15% smaller than 15.56 microns and0%-6% smaller than 11 microns.Preferably the coating powder has 0% larger than 88 microns and an Mv=about 30-40, preferably 35-40 microns. More preferably the particle distribution further includes10%-15% smaller than 15.56 microns and4%-6% smaller than 11 microns, andan Mv of between about 35 and 36 microns. Most preferably the particle distribution further includes:about 11.5% smaller than 15.56 microns andabout 4.3% smaller than 11 microns, andan Mv of about 35.9. Preferably the powder is a thermosetting resin composition.

Abstract: A pyrotechnic grain or body of a gas generant having a consolidated or pressed-on, particulate inert burn inhibitor layer thereon. The inhibitor may be a metal oxide, metal sulfide, silica, silicate compound or mixtures thereof. The metal oxide is preferably iron oxide. The metal sulfide is preferably molybdenum disulfide. The preferred inhibitor is a silicate compound, most preferably bentonite. The inhibitor layer most preferably covers only one face or side of the generant body, though it may cover both faces or less than the entire area of one or both faces. The generant may be any conventional formulation which generates nitrogen-containing gas, preferably an azide, and most preferably sodium azide. The generant body may be any shape, preferably a washer-shaped disc. An automotive gas bag inflator may contain a plurality of the composite, inhibited generant bodies, preferably a stack or side by side assembly of such composite, inhibited wafers.