Patents Represented by Attorney, Agent or Law Firm Charles Q. Buckwalter
  • Patent number: 5456729
    Abstract: The present invention is directed to a sensitizer provided as a foam that may be used individually and/or added to explosives, propellants, and/or pyrotechnics.
    Type: Grant
    Filed: April 9, 1992
    Date of Patent: October 10, 1995
    Assignee: ICI Canada Inc.
    Inventors: Fortunato Villamagna, Arun K. Chattopadhyay, Ming C. Lee
  • Patent number: 5454889
    Abstract: The present invention is directed to intimately combining petroleum products with ammonium nitrate prills forming a coating thereon, whereby said coating is tackified and free flowing.
    Type: Grant
    Filed: August 19, 1993
    Date of Patent: October 3, 1995
    Assignees: ICI Canada Inc., ICI Explosives USA Inc.
    Inventors: Melvin A. McNicol, Fortunato Villamagna, J. P. Michel Couture
  • Patent number: 5454890
    Abstract: A cap-sensitive emulsion explosive capable of being used in packaged explosive products. The explosive contains ammonium nitrate prills of a bulk density of 0.70 to 1.00 g/cc, with a particle density of 1.25 to 1.40 g/cc. A polysuccinic anhydride based emulsifying agent is used as an emulsifying agent. Packaged explosives prepared according to the present invention have improved package stability, and allow for control of the ratio of shock energy to heave energy.
    Type: Grant
    Filed: February 8, 1993
    Date of Patent: October 3, 1995
    Assignee: ICI Canada Inc.
    Inventors: William B. Evans, Anh D. Nguyen
  • Patent number: 5449400
    Abstract: A stable indelible colored ink composition for invalidating bank notes or similar valuables by staining them permanently, comprises at least one of di- or tri-phenylguanidine.
    Type: Grant
    Filed: May 3, 1994
    Date of Patent: September 12, 1995
    Assignee: Imperial Chemical Industries PLC
    Inventors: Greg Van Lint, Samuel T. Bebbington
  • Patent number: 5449424
    Abstract: Precipitation of fine azide core particles with in-situ coating with suspended tiny oxide particles, followed by concentration of the dilute suspension of these bodies to form a slurry with residual dissolved azide in the liquor, and finally converting the slurry in to solid aggregates of the pyrotechnic bodies by e.g. prilling whereby liquid phase evaporation releases dissolved azide causing the pyrotechnic bodies to be adhered together in to larger aggregates.
    Type: Grant
    Filed: September 21, 1993
    Date of Patent: September 12, 1995
    Assignees: Imperial Chemical Industries PLC, ICI Canada Inc.
    Inventors: Raymond Oliver, Ian J. Kirby, Sek K. Chan
  • Patent number: 5447090
    Abstract: The present invention is directed to a delivery system for bulk explosives whereby said system is remotely controlled by electronic or electrical controls.
    Type: Grant
    Filed: September 16, 1993
    Date of Patent: September 5, 1995
    Assignee: ICI Explosives USA Inc.
    Inventor: Robert G. Adams
  • Patent number: 5435249
    Abstract: A shock tube initiator comprises a core charge having an oxidizer-rich fuel-oxidizer mixed particle system the mixed particle system containing co-mingled particles of finely comminuted organic dyestuff of the phthalocyanine family or a similarly thermally-stable organic dyestuff in sufficient quantity to impart a distinct color to the charge, the dyestuff being a material which does not decompose below 250.degree. C.
    Type: Grant
    Filed: October 20, 1993
    Date of Patent: July 25, 1995
    Assignee: Imperial Chemical Industries PLC
    Inventors: Geoffrey F. Brent, Malcolm D. Harding
  • Patent number: 5427031
    Abstract: A detonator for detonation of explosives which provides protection of a primer charge from sympathetic initiation and provides efficient detonation of a base charge. The detonator is comprised of, a hollow detonator shell having first and second ends, said detonator shell has inserted therein a delay element and a primer capsule. Said delay element is positioned within the first end of the shell and has a core running therethrough. The primer capsule has a protective frustrum top having an opening centrally located therein and a tubular bottom. The primer capsule is inserted into the second end of the shell such that the core of the delay element is in contact with the opening in the frustrum top. The primer capsule top contains a primer charge and the bottom contains primer charge and a small amount of base charge material. The top is constructed with heavy walls such that the primer charge is protected.
    Type: Grant
    Filed: May 20, 1993
    Date of Patent: June 27, 1995
    Assignee: ICI Explosives USA Inc.
    Inventor: Arthur F. Bowman
  • Patent number: 5395559
    Abstract: A process for the production of explosives grade ammonium nitrate prill (EGAN) comprises the steps of(A). producing seed ammonium nitrate prill as substantially monosized prills; and then(B). fattening using melt/solution of ammonium or mixed nitrates, with drying and thermal treatments, the seed prill in an inclined rotating jacketed pan granulator or a cascade of such pans to produce a final fattened EGAN prill product preferably having at most about 4 mm diameter.
    Type: Grant
    Filed: May 5, 1993
    Date of Patent: March 7, 1995
    Assignees: Imperial Chemical Industries, PLC, ICI Canada Inc.
    Inventors: Aida Kaldas, Raymond Oliver
  • Patent number: 5354520
    Abstract: Explosive grade ammonium nitrate (EGAN) prills are made by a process comprising the steps of:a. continuously spraying a 95 to 98% by weight solution/melt of ammonium nitrate (or a mixture of ammonium nitrate and minor proportions of one or more other EGAN--acceptable nitrates) in/with water under spray-head conditions causing the emergent jets to break into cascades of substantially mono-sized droplets;b. allowing the formed droplets to fall within a vertical duct;c. continuously feeding a stream of cooling gas upwards through the duct to effect cooling and solidification of the falling droplets and some removal of moisture so as to form substantially mono-sized EGAN prills of up to about 4 mm diameter, andd.
    Type: Grant
    Filed: May 5, 1993
    Date of Patent: October 11, 1994
    Assignees: ICI Chemical Industries PLC, ICI Canada Inc.
    Inventors: Raymond Oliver, Ronald O. Peddie
  • Patent number: 5208419
    Abstract: A method of producing a coloured shock tubing comprising a visibly coloured hollow tube having an inner coating of a reactive material wherein the core loading of the reactive material in the tube may be measured by radiation absorption. The visible colouration of the hollow tube is effected by the addition of a coloured compound, which compound is essentially transparent to the radiation used to measure core loading. A one stage extrusion process may be utilized to prepare a shock tube wherein core loading is easily measured during production, and verified after production.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: May 4, 1993
    Assignee: ICI Canada Inc.
    Inventors: Robert C. Greenhorn, Jacques Lafond
  • Patent number: 5204492
    Abstract: A detonator assembly is provided which increases versatility, reliability and safety by initiating any amount of signal transmission lines up to about 8 without emitting excessive noise or shrapnel which can cause cut off or safety hazards. The detonator assembly comprises a low strength detonator with a single charge of preferably lead azide. A high confinement connection block houses the low strength detonator and comprises a retention block in which the low strength detonator is inserted and a confining wall which surrounds the closed end of the low strength detonator. One to about eight signal transmission lines can be inserted through a gap in the confining wall and operatively confined adjacent the closed end of the low strength detonator.
    Type: Grant
    Filed: October 30, 1991
    Date of Patent: April 20, 1993
    Assignee: ICI Explosives USA Inc.
    Inventors: Merritt Jacob, Peter F. Reiss, Samual G. Stednitz
  • Patent number: 4915612
    Abstract: An extrusion die assembly for making honeycomb structures of ceramics, glass, and other extrudable materials. The assembly is provided with an apertured, flow controlling forming plate placed against the input (upstream) surface of the extrusion die. The forming plate has a central opening through which the batch material to the input face of the die passes. A series of angularly spaced, flow controlling openings lies radially outwardly of the rim of this central opening. These forming plate openings are axially aligned with a shim reservoir downstream of the discharge slots of the die. This arrangement permits both the flow volume and rate of the batch material being extruded to the skin forming portions of the die assembly to be at least partially independently controlled relative to the flow volume to the main, radially central portion of the extrudate. By this construction, the formation of air checks in the shim reservoir and the formation of rippled skin on the extrudate is inhibited.
    Type: Grant
    Filed: January 26, 1989
    Date of Patent: April 10, 1990
    Assignee: Corning Incorporated
    Inventors: John R. Gangeme, Richard D. Putt
  • Patent number: 4912077
    Abstract: This invention is directed to the preparation of articles exhibiting catalytic activity and, in particular, to articles which are exceptionally suitable for catalytically converting gases from organically fueled power plants, internal combustion engines, and other fluid and gaseous catalysis. The inventive articles comprise a unitary composite structure consisting essentially of a catalytically active precious metal and/or a base metal which, the base metals in particular, become catalytically active upon oxidation. The catalysts are integrally combined with a supporting structural metal.
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: March 27, 1990
    Assignee: Corning Incorporated
    Inventors: Irwin M. Lachman, Mallanagouda D. Patil, Jimmie L. Williams, Raja R. Wusirika
  • Patent number: 4892857
    Abstract: An apparatus for use in liquid-phase, gas-phase and mixed-phase reactions is disclosed for providing an efficient flow-through design within which results a low pressure drop. The apparatus may be used as a catalyst or electrocatalyst and consists essentially of a ceramic substrate having thin walls with open porosity wherein said walls define a plurality of cells extending substantially longitudinally parallel through-and-through the substrate. The substrate includes an electrically conductive layer, having a resistivity of no greater than about 100 ohm-cm. The apparatus exhibits an improved structural geometry and provides greater meniscus control.
    Type: Grant
    Filed: May 20, 1987
    Date of Patent: January 9, 1990
    Assignee: Corning Incorporated
    Inventors: David L. Tennent, Gerald D. Fong, Christine L. Hoaglin
  • Patent number: 4888317
    Abstract: A structure with encapsulated catalyst-agglomerate bodies which are integral to a porous structure is presented. The catalysts may be singly and/or multiply dispersed on and/or throughout a high surface area material and subsequently mixed with batch material prior to firing the structure. This results in a structure wherein encapsulated catalyst-agglomerate bodies in a porous structure exhibit the same catalytic activity as in a break in aged catalyst coated substrate.
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: December 19, 1989
    Assignee: Corning Incorporated
    Inventors: Thomas P. DeAngelis, Irwin M. Lachman, Raja R. Wusirika
  • Patent number: 4877766
    Abstract: A rigid mini-monolith structure formed by extrusion from a die. Such structures are useful as catalyst supports for treating exhaust gases from automobile. The structure is in the shape of a right circular cylinder with a plurality of internal cells extending along the substrate and an opening on both ends. In order to provide maximum crushing strength of the structure, as well as permitting uniform intercell wall thickness at the downstream face of the extrusion die which forms the structure, the majority of the cells are formed in the transverse cross section of a truncated (circular) sector and have the property that they each possess the same hydraulic diameter, although not all are of the same transverse cross sectional shape. The invention also is defined by a novel extrusion die formed by a plurality of concentric, collared tubes provided with longitudinally running slots in the tubes and notches on the collars, the tubes being radially spaced from each other.
    Type: Grant
    Filed: July 18, 1988
    Date of Patent: October 31, 1989
    Assignee: Corning Incorporated
    Inventor: Rodney I. Frost
  • Patent number: 4876227
    Abstract: This invention is directed to the production of oxide-boride-silicon nitride ceramics consisting essentially of ceramic bodies of oxide and boride phases which have silicon nitride added to improve the properties of the ceramic body for use as wear material, durable interface material, and cutting tool inserts. The addition of Si.sub.3 N.sub.4 to the oxide-boride body provides a durable ceramic material which provides a range of cutting speeds that may be utilized in both turning and milling operations.
    Type: Grant
    Filed: August 24, 1988
    Date of Patent: October 24, 1989
    Assignee: Corning Incorporated
    Inventor: Thomas P. DeAngelis
  • Patent number: 4855265
    Abstract: This invention relates to the high temperature stabilization of aluminum titanate and aluminum titanate-mullite compositions by the addition of iron oxide. It has been found that iron oxide concentrations greater than 5 weight percent and as high as approximately 25 weight percent have a stabilization effect at high temperatures on aluminum titanates. The resultant ceramic body is further enhanced by the addition of from 0.1 to 5 weight percent rare earth oxide.
    Type: Grant
    Filed: April 4, 1988
    Date of Patent: August 8, 1989
    Assignee: Corning Incorporated
    Inventors: John P. Day, Robert J. Locker
  • Patent number: 4800187
    Abstract: A method is provided of crystallizing strong-bound zeolites on the surfaces of a monolithic ceramic substrate by hydrothermally treating the substrate, in the presence of active silica, with a caustic bath to zeolitize the silica. According to various embodiments of the invention, the active silica can be present as a component of the caustic bath, in the form of a dried coating pre-deposited on the substrate, or as a separate phase of the monolithic substrate, homogeneous dispersed within the ceramic material.
    Type: Grant
    Filed: October 28, 1987
    Date of Patent: January 24, 1989
    Assignee: Corning Glass Works
    Inventors: Irwin M. Lachman, Mallanagouda D. Patil