Abstract: A method for selectively extracting metal values from manganese bearing ores such as marine nodules. The ore is initially leached to solubilize manganese and other desirable metals as nitrates. The resulting solution is then treated with manganous hydroxide to selectively precipitate metals such as copper, nickel and cobalt. The enriched mixture of metal hydroxides is separated from the manganese nitrate solution, which is decomposed to recover high purity MnO.sub.2.