Abstract: A process for the preparation of 1,2-bis(acyloxyates) comprises acylation of epoxides with carboxylic anhydrides in the presence of a catalytic composition containing a tertiary amine and a carboxylic acid. Preferably, the carboxylic acid is a conjugate acid of the carboxylic anhydride. The carboxylic acid acts as a co-catalyst and its use in conjunction with the tertiary amine significantly increases the rate of reaction and results in higher selectivity. The catalytic composition may be prepared prior to acylation or in situ providing application versatility.
Abstract: Disclosed are orientable, heat setable, semi-crystalline copolyesters which have high glass transition temperatures. These copolyesters have high heat distortion temperatures along with excellent molding and film properties which makes them useful in packaging materials and molded parts. These copolyesters have repeat units from about 100 mol % 1,4-cyclohexanedimethanol, about 1-99 mol % terephthalic acid and about 99-1 mol % naphthalene dicarboxylic acid.
Abstract: A composition of paper comprising 99 to 10 weight percent cellulose fibers and 1 to 90 weight percent cored cellulose fibers that are uniformly dispersed within the paper. The cored cellulose fibers are composed of a cellulose sheath that is 4 to 15 weight percent of the weight of the fiber and a cellulose acetate core. The cored cellulose fibers contain no substantial crimp and have an average length of 1 to 7 mm, a density of 1.20 to about 1.35 gm/cc, a denier 1 to 30 grams per 9,000 meters and a uniform dispersion index of less than 0.15.
Type:
Grant
Filed:
July 28, 1995
Date of Patent:
November 12, 1996
Assignee:
Eastman Chemical Company
Inventors:
Tim J. Frederick, Melvin G. Mitchell, Lee R. Partin
Abstract: A label for containers comprises a foamed polyester film that has a density of less than 1 g/cm.sup.3. The foamed polyester film may be blown away in air and then floated away in water during the recycle process for containers. After separation from the containers the foamed polyester film may be reclaimed by a chemical process to recover raw materials for polyesters.
Abstract: Disclosed are polyester particles adapted to be extrusion blow molded into articles having improved rheological qualities and a process for producing such particles, said particles comprising a polyester having repeat units from about 40 to 100 mol % terephthalic acid, about 80-98 mol % ethylene glycol, about 0.5-10 mol % 1,4-cyclohexanedimethanol, about 3-10 mol % diethylene glycol, and about 0.05-1.
Type:
Grant
Filed:
March 17, 1995
Date of Patent:
June 4, 1996
Assignee:
Eastman Chemical Company
Inventors:
Randy S. Beavers, Karen L. Carman, Michael L. Cassell, Joseph F. Knight, James W. Mercer
Abstract: Disclosed are branched polyester compositions having an I.V. of at least about 0.7 dl/g and a melt viscosity sufficiently high to permit foaming during extrusion or molding operations. These branched polyesters are readily foamable with a wide range of foaming agents to provide low density shaped articles, films, and sheets. The branched polyesters comprise about 80 to about 99.9 wt % of a polyester and about 0.1 to about 20 wt % of an ethylene copolymer containing repeat units of ethylene and of a monomer selected from the group comprising acrylic acid, methacrylic acid, alkyl acrylate, alkyl methacrylate and vinyl alcohol.
Type:
Grant
Filed:
August 7, 1995
Date of Patent:
May 21, 1996
Assignee:
Eastman Chemical Company
Inventors:
Richard L. McConnell, Kishan C. Khemani
Abstract: Disclosed is an improved process for the continuous production of aromatic carboxylic acids by the liquid-phase oxidation of an alkyl aromatic compound with an oxygen-containing gas in the presence of oxidation catalyst which effectively utilizes the heat of reaction in the process of removing excess water generated from the reaction and minimizes the loss of solvent used as the carrier for the reaction catalyst. Operation of the process is improved by removing reactor off-gas directly into a water removal column for distillation. A portion of distillate condensed from the overhead aqueous vapors of the water removal column is refluxed to the fractionating zone of the water removal column.
Type:
Grant
Filed:
March 27, 1995
Date of Patent:
April 23, 1996
Assignee:
Eastman Chemical Company
Inventors:
James F. McGehee, Sunday O. Ogundiran, Robert Lin
Abstract: Disclosed are branched polyester compositions having an I.V. of at least about 0.7 dl/g and a melt viscosity sufficiently high to permit foaming during extrusion or molding operations. These branched polyesters are readily foamable with a wide range of foaming agents to provide low density shaped articles, films, and sheets.The branched polyesters comprise about 80 to about 99.9 wt % of a polyester and about 0.1 to about 20 wt % of an ethylene copolymer containing repeat units of ethylene and of a monomer selected from the group comprising acrylic acid, methacrylic acid, alkyl acrylate, alkyl methacrylate and vinyl alcohol.
Type:
Grant
Filed:
May 8, 1995
Date of Patent:
January 9, 1996
Assignee:
Eastman Chemical Company
Inventors:
Richard L. McConnell, Kishan C. Khemani
Abstract: Disclosed are polyester particles adapted to be extrusion blow molded into articles having improved rheological qualities and a process for producing such particles, said particles comprising a polyester having repeat units from about 40 to 100 mol % terephthalic acid, about 80-98 mol % ethylene glycol, about 0.5-10 mol % 1,4-cyclohexanedimethanol, about 3-10 mol % diethylene glycol, and about 0.05-1.
Type:
Grant
Filed:
September 6, 1994
Date of Patent:
August 15, 1995
Assignee:
Eastman Chemical Company
Inventors:
Randy S. Beavers, Karen L. Carman, Michael L. Cassell, Joseph F. Knight, James W. Mercer