Abstract: Citraconic anhydride is made by the vanadium-catalyzed gas-phase air oxidation of mesityl oxide at about 200-500.degree.C. and atmospheric pressure with a contact time of less than 1 second. Preferred catalysts are vanadium oxide and vanadate salts. Preferred O.sub.2 /mesityl oxide molar ratios are about 10:1 to 100:1.
Abstract: New organic compounds, comprising tris(polyhalophenoxy)-s-triazines, e.g., tris-(2,4,6-tribromophenoxy)-s-triazine. These new compounds have demonstrated utility as fire retardant additives for various polymers.
Abstract: Novel copolymers are prepared in the novel process comprising copolymerizing an N-substituted aziridine with a vicinal epoxide or episulfide. Compounds having at least one active hydrogen, such as water or an alcohol, may be advantageously included as coreactants in the process. The structure of the copolymers, exclusive of any chain-extending or terminal groups, is defined by alternating ring-opened units of the N-substituted aziridine monomer and the epoxide or episulfide monomer. The copolymers are useful as stabilizers for chlorinated solvents, rubber cure accelerators, antioxidants, surfactants, lubricants, acid scavengers, dye-retention aids, retention aids for starch, and as flocculants.
Type:
Grant
Filed:
January 11, 1974
Date of Patent:
January 27, 1976
Assignee:
The Dow Chemical Company
Inventors:
Prella M. Phillips, Clarence R. Dick, Joseph M. Baggett
Abstract: An aqueous solution of propylene glycol monomethyl ether is a more effective coolant for rotary (Wankel) engines and less toxic than is gaseous alkylene glycol.