Abstract: The present invention is directed to a method for making a wide variety of general-purpose cermets and for radioactive waste disposal from ceramic powders prepared from urea-dispersed solutions containing various metal values. The powders are formed into a compact and subjected to a rapid temperature increase in a reducing atmosphere. During this reduction, one or more of the more readily reducible oxides in the compact is reduced to a selected substoichiometric state at a temperature below the eutectic phase for that particular oxide or oxides and then raised to a temperature greater than the eutectic temperature to provide a liquid phase in the compact prior to the reduction of the liquid phase forming oxide to solid metal. This liquid phase forms at a temperature below the melting temperature of the metal and bonds together the remaining particulates in the cermet to form a solid polycrystalline cermet.
Type:
Grant
Filed:
April 1, 1981
Date of Patent:
May 17, 1983
Assignee:
The United States of America as represented by the United States Department of Energy
Inventors:
W. Scott Aaron, Donald L. Kinser, Thomas C. Quinby
Abstract: A method for producing a cesium-retentive waste form, characterized by a high degree of compositional stability and mechanical integrity, is provided by subjecting a cesium-loaded zeolite to heat under conditions suitable for stabilizing the zeolite and immobilizing the cesium, and coating said zeolite for sufficient duration within a suitable environment with at least one dense layer of pyrolytic carbon to seal therein said cesium to produce a final, cesium-bearing waste form. Typically, the zeolite is stabilized and the cesium immobilized in less than four hours by confinement within an air environment maintained at about 600.degree. C. Coatings are thereafter applied by confining the calcined zeolite within a coating environment comprising inert fluidizing and carbon donor gases maintained at 1,000.degree. C. for a suitable duration.
Type:
Grant
Filed:
September 3, 1981
Date of Patent:
March 15, 1983
Assignee:
The United States of America as represented by the United States Department of Energy
Inventors:
Peter Angelini, Walter J. Lackey, David P. Stinton, Raymond E. Blanco, Walter D. Bond, Wesley D. Arnold, Jr.
Abstract: An enzymatic method for continuous, on-line and rapid detection of diagnostically useful biomarkers, which are symptomatic of disease or trauma-related tissue damage, is disclosed. The method is characterized by operability on authentic samples of complex biological fluids which contain the biomarkers.
Type:
Grant
Filed:
April 28, 1981
Date of Patent:
November 2, 1982
Assignee:
The United States of America as represented by the United States Department of Energy
Inventors:
William D. Bostick, Mark S. Denton, Stanley R. Dinsmore