Patents Represented by Attorney Clifford C. Dougherty
  • Patent number: 6534448
    Abstract: An acidizing composition and a method of acidizing a hydrocarbon bearing subterranean formation in the presence of ferric ions are provided. The acidizing composition includes an aqueous mineral acid solution, an electron donor agent and an electron transfer agent, the electron transfer agent being a source of molybdenum ions. When the aqueous mineral acid solution includes hydrochloric acid in an amount greater than approximately 17% by weight, the acidizing composition further includes a supplemental electron transfer agent, the supplemental electron transfer agent being a source of iodide ion or iodine. The electron donor agent and electron transfer agent function together to reduce ferric ion present in the mineral acid solution to ferrous ion which in turn prevents ferric hydroxide and/or free sulfur from precipitating out of the solution and reduces the formation of sludge in crude oil in the formation.
    Type: Grant
    Filed: November 2, 2000
    Date of Patent: March 18, 2003
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Michael M. Brezinski
  • Patent number: 6531427
    Abstract: Methods and compositions for reducing the precipitation of aluminum compounds following the contact of an aluminum containing subterranean formation with an acid solution containing hydrofluoric acid are provided. In accordance with the methods, a hydroxy carboxylic acid is combined with the hydrofluoric acid solution and the subterranean formation is contacted with the resulting acid solution.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: March 11, 2003
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Chris E. Shuchart, Rick D. Gdanski
  • Patent number: 6506711
    Abstract: Methods and compositions for reducing the precipitation of fluoride compounds following the contact of an aluminum containing subterranean formation with an acid solution containing hydrofluoric acid are provided. In accordance with the methods, a hydroxy carboxylic acid is combined with the hydrofluoric acid solution and the subterranean formation is contacted with the resulting acid solution.
    Type: Grant
    Filed: June 20, 1995
    Date of Patent: January 14, 2003
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Chris E. Shuchart, Rick D. Gdanski
  • Patent number: 6415865
    Abstract: An acidizing composition and a method of acidizing a hydrocarbon bearing subterranean formation in the presence of ferric ions are provided. The acidizing composition includes a strong mineral acid solution, an electron donor agent, a primary electron transfer agent and a secondary electron transfer agent. The primary electron transfer agent is a source of rhenium ions. The secondary electron transfer agent is a source of iodide ion or iodine. The electron donor agent and primary and secondary electron transfer agents function together to reduce ferric ion present in the mineral acid solution to ferrous ion which in turn prevents ferric hydroxide and/or free sulfur from precipitating out of the solution and reduces the formation of sludge in crude oil in the formation. The particular electron transfer agents used in connection with the invention function with virtually all known electron donor agents.
    Type: Grant
    Filed: March 8, 2001
    Date of Patent: July 9, 2002
    Inventor: Michael M. Brezinski
  • Patent number: 6315045
    Abstract: Methods and acidizing compositions for reducing the corrosion of the metal surfaces of tubular goods and the like and reducing the precipitation of metal sulfide from the acidizing compositions are provided. The methods basically comprise the steps of combining an aldol-amine adduct with an aqueous acid solution to preferentially react with sulfide ions subsequently dissolved by the aqueous acid solution and thereby prevent subsequently dissolved metal ions from reacting therewith and precipitating, and then introducing the aqueous acid solution containing the aldol-amine adduct into a well or other location to be acidized.
    Type: Grant
    Filed: March 7, 2000
    Date of Patent: November 13, 2001
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Michael M. Brezinski
  • Patent number: 6225261
    Abstract: A composition and method for acidizing a formation in the presence of ferric ion, free sulfur and/or sulfides is disclosed. The composition employs a ferric ion reducing agent and a sulfide reactant separately or in combination. The ferric ion reducing agent is a thioalkyl acid. The sulfide reactant compounds include &agr;-diketones and saturated and &agr;-unsaturated cyclic ketones. In another aspect, the reducing activity of the thioalkyl acid is accelerated by the presence of a catalytic quantity of a compound or mixture of compounds which yield in acid solution cuprous ion, cupric ion or combinations thereof with iodide ion.
    Type: Grant
    Filed: June 7, 1993
    Date of Patent: May 1, 2001
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Michael M. Brezinski, Tommy R. Gardner, Karen L. King, James L. Lane, Jr.
  • Patent number: 5505260
    Abstract: The present invention provides a single trip system for placing perforating apparatus and sand control equipment in a wellbore. This system includes a casing string equipped with extendible pistons and a pumpable activator plug for extending the pistons. Additionally, this system utilizes a single gravel-pack and completion tool string. Further, this system includes a means for opening the extendible pistons to fluid flow.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: April 9, 1996
    Assignee: Conoco Inc.
    Inventors: Eric E. Andersen, Larry K. Moran, Richard M. Hodge, Nobuo Morita
  • Patent number: 5454867
    Abstract: A dry, agglomerated cement material, a method of preparing the dry, agglomerated cement material, a method of cementing, and an apparatus for agglomerating particulate materials. The dry, agglomerated cement material comprises a plurality of particles of a cement bonded together by a water-soluble binder material. The dry, agglomerated cement material is prepared by depositing the water-soluble binder material on the particles such that the binder material bonds the particles together. The inventive agglomerated cement material can be conveniently transported by both pneumatic and non-pneumatic means. The method of cementing comprises the step of mixing the agglomerated cement material with water to form a cement slurry.
    Type: Grant
    Filed: April 5, 1994
    Date of Patent: October 3, 1995
    Assignee: Halliburton Company
    Inventors: Lance E. Brothers, J. Erlan Longendelpher, Donald W. Lindsey, Frank L. Sands, Kevin D. Edgley
  • Patent number: 5411670
    Abstract: A method and coating composition for producing protective coatings on metal surfaces of tubular goods, equipment and so forth used in processes associated with oxidative environments to inhibit corrosive effects of the oxidative environments thereon. The coating composition includes an aqueous liquid carrier and a corrosion inhibiting combination of a specific condensation product and an antimony compound. The antimony compound is activated by the condensation product and enhances the degree of protection achieved.
    Type: Grant
    Filed: July 26, 1993
    Date of Patent: May 2, 1995
    Assignee: Halliburton Company
    Inventor: Michael L. Walker
  • Patent number: 5366643
    Abstract: The invention relates to a method and composition for acidizing a subterranean formation employing an acidic solution comprising hydrochloric acid solution containing a corrosion inhibitor present in a corrosion-reducing effective amount. The corrosion inhibitor comprises the product of the reaction of (i) a compound having at least one reactive hydrogen atom and having no groups reactive under the conditions of reaction other than hydrogen, (ii) a carbonyl compound having at least one hydrogen atom on the carbon atom adjacent to the carbonyl group, (iii) an aldehyde, (iv) a fatty compound and an acid source which is admixed with a source of antimony ions.
    Type: Grant
    Filed: May 24, 1993
    Date of Patent: November 22, 1994
    Assignee: Halliburton Company
    Inventor: Michael L. Walker
  • Patent number: 5346012
    Abstract: Fine particle size cement compositions and methods of using such compositions for cementing in a subterranean zone penetrated by a well bore are provided. The compositions are basically comprised of a fine particle size hydraulic cement, a fine particle size pozzolanic material and sufficient water to form a pumpable slurry.
    Type: Grant
    Filed: February 1, 1993
    Date of Patent: September 13, 1994
    Assignee: Halliburton Company
    Inventors: James F. Heathman, Ronald J. Crook
  • Patent number: 5321062
    Abstract: A substituted alkoxy benzene having the formula ##STR1## wherein R, R.sub.1, R.sub.2 and R.sub.3 are each a hydrocarbon radical having from 1 to 8 carbon atoms and x is 0 or 1 is provided. The substituted alkoxy benzene is very useful as a wetting aid for enhancing the ability of hardenable polyepoxide resin compositions to coat and bond to material (e.g., particulate material) in high temperature applications. The substituted alkoxy benzene does not significantly accelerate the curing rate of the resins. A polyepoxide resin composition for coating and bonding to a material, a composition useful for forming a hard permeable mass in a remote location and a method of continuously forming and suspending consolidatible resin composition coated particulate material in a gelled aqueous carrier liquid and transporting the coated particulate material to a remote location where the material is consolidated are also provided.
    Type: Grant
    Filed: October 20, 1992
    Date of Patent: June 14, 1994
    Assignee: Halliburton Company
    Inventors: Bruce E. Landrum, Jimmie D. Weaver, Joseph R. Murphey
  • Patent number: 5034140
    Abstract: A concentrate which forms an acid internal microemulsion well treatment composition when added to an acid treatment fluid. The concentrate comprises in the range of from about 20% to about 98% by weight of a hydrocarbon carrier fluid, in the range of from about 1% to about 50% by weight of an alkyl alcohol having from 4 to 18 carbon atoms and in the range of from about 1% to about 50% by weight of an emulsifying agent comprising at least one compound selected from the group consisting of sulfate esters, phosphate esters, alkyl aromatic sulfonic acids, amine salts having ester or amide linkages, quaternary ammonium compounds having ester of amide linkages, propoxylated fatty acids, and propoxylated alcohols. Also disclosed are an acid internal microemulsion well treatment composition and a method of treating a subterranean formation to increase the production of hydrocarbons therefrom.
    Type: Grant
    Filed: November 27, 1989
    Date of Patent: July 23, 1991
    Assignee: Halliburton Company
    Inventors: Tommy R. Gardner, Walter R. Dill, William G. F. Ford, Karen L. King
  • Patent number: 5008026
    Abstract: A concentrate which forms an acid and/or water external microemulsion when added to a treatment fluid. The concentrate comprises an alkyl alcohol having in the range of from 4 to 18 carbon atoms, an emulsifying agent, a mutual solvent selected from the group consisting of glycol ethers and alkyoxylates of glycol ethers, and a co-solvent selected from the group consisting of polyethylene glycol, primary alcohols and alkyoxylates of alkyl alcohols. Also disclosed are an acid and/or water external microemulsion well treatment composition and a method of treating a subterranean formation to increase the production of hydrocarbons therefrom.
    Type: Grant
    Filed: January 12, 1990
    Date of Patent: April 16, 1991
    Assignee: Halliburton Company
    Inventors: Tommy R. Gardner, Walter R. Dill, William G. F. Ford, Karen L. King
  • Patent number: 4981601
    Abstract: An improved method and composition for reducing the production of sludge when contacting a subterranean formation containing oil which is subject to sludging with an aqueous acid solution. An anti-sludging agent such as a quaternary ammonium salt of a fatty amine, and one or more other additives are combined with the aqueous acid solution along with a dispersing agent which forms the aqueous acid solution and additives into a long-term homogeneous composition.
    Type: Grant
    Filed: February 2, 1989
    Date of Patent: January 1, 1991
    Assignee: Halliburton Company
    Inventor: William G. F. Ford
  • Patent number: 4827638
    Abstract: An apparatus for supporting a work article on a work surface. The apparatus includes a base member having an opening therein, a work article support member attached to and positioned above the base member, the work article support member having an opening therein positioned in at least partial alignment with the opening of the base member, and means attached to the base member and positioned between the base member and the work surface for allowing the base member and the work article support member to rotate with respect to the work surface. A storage tray having an opening positioned in at least partial alignment with the openings of the base member and the work article support member can be attached to the base member and positioned between the base member and the work article support member.
    Type: Grant
    Filed: January 6, 1988
    Date of Patent: May 9, 1989
    Inventor: Gerald A. Peters
  • Patent number: 4786051
    Abstract: An exercising apparatus that utilizes a hydraulic ram to provide resistance to force applied by the operator of the apparatus is provided. The apparatus includes a frame and an exercise bar. The exercise bar has a first end and a second end, and is pivotally attached between its first and second ends to the frame. A first exercising means is attached to the first end of the exercise bar, and a second exercising means is attached to the second end of the exercise bar. The exercising means allow the user of the apparatus to move the exercise bar relative to the frame. First and second user support means for supporting the user while the user operates the first and second exercising means to move the exercise bar are positioned adjacent the first and second exercising means, respectively, forming a first exercise station and a second exercise station.
    Type: Grant
    Filed: October 30, 1986
    Date of Patent: November 22, 1988
    Inventor: Joe E. Mullican
  • Patent number: 4706834
    Abstract: An apparatus for protecting the open end of the female half of a metallic hydraulic line coupler when the female half is not coupled to the male half of the coupler is provided. The apparatus includes a magnetic cover member releasably attachable to the female half of the coupler by the exertion of magnetic force thereon. The cover member has a first surface which completely covers the open end of the female half of the coupler when the cover member is magnetically attached thereto. Magnetic force deflecting means are attached to the magnetic cover member for redirecting at least a substantial portion of any of the magnetic force directed away from the female half of the coupler toward the female half of the coupler.
    Type: Grant
    Filed: February 6, 1987
    Date of Patent: November 17, 1987
    Inventors: Michael K. Farney, Jackson Kile