Patents Represented by Attorney Clinton S. Janes, Jr.
  • Patent number: 5372860
    Abstract: A method for producing a glass panel for silicon device fabrication, which method comprises forming a noncrystalline, or mixed-phase, silicon film on a glass substrate, the glass having a strain point greater than 560.degree. C., and subjecting the filmed glass to a heat treatment comprising heating at a temperature of at least 550.degree. C. for a period of time sufficient to convert the silicon film to polycrystalline silicon and to compact the glass.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: December 13, 1994
    Assignee: Corning Incorporated
    Inventors: Francis P. Fehlner, Paul A. Sachenik
  • Patent number: 5371048
    Abstract: A dense barium crown glass consisting essentially of, as calculated in weight % on an oxide basis, 35-42% SiO.sub.2, 11-17% B.sub.2 O.sub.3, 5.5-7.7% Al.sub.2 O.sub.3, 35-42% BaO, 0.25-1.5% Li.sub.2 O. The glasses have a liquidus temperature bellow 900.degree. C. and a viscosity at the liquidus temperature that is greater than 1000 Pa.s (10,000 poises).
    Type: Grant
    Filed: October 18, 1993
    Date of Patent: December 6, 1994
    Assignee: Corning Incorporated
    Inventor: Lisa A. Tietz
  • Patent number: 5367012
    Abstract: This invention is directed to an alloy, and a method of producing an alloy, of increased resistance to moisture, comprising a melt mixture of at least one phosphate glass, at least one organic thermoplastic or thermosetting polymer, and an amount of a water soluble stabilizer component which provides a source of metal cations having a valency of 2.sup.+ or higher The amount of the stabilizer component added is that amount effective to improve the alloy's resistance to moisture. Preferably, the alloy is comprised of: (a) 5-80% of the matrix material; (b) 15-90% of the phosphate glass; and, (c) 0.1 to 40% of the stabilizer component. Additionally, the metal cations which are found in the stabilizer component and which form part of the insoluble surface layer are preferably selected from the group consisting of Ba.sup.2+, Mg.sup.2+, Ca.sup.2+, Al.sup.3+, Zn.sup.2+, Sr.sup.+2 and Fe.sup.3+.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: November 22, 1994
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Dana C. Bookbinder, James E. Dickinson, Jr., Brent M. Wedding
  • Patent number: 5364487
    Abstract: A method of applying a tough, abrasion-resistant, organic film to a back surface of a thin, glass body to form a glass-plastic composite, the method comprising preheating the film to a temperature at which residual solvent and moisture are removed from the film, preheating a presshead to a pressing temperature, pressing the film and the glass together, maintaining the glass-film assembly at a controlled temperature and pressure for a period of time to form a sealed composite body, and cooling the sealed body to solidify the glass-plastic composite.
    Type: Grant
    Filed: September 15, 1993
    Date of Patent: November 15, 1994
    Assignee: Corning Incorporated
    Inventors: Mark S. Friske, Ronald E. Johnson, Christine M. Reagan, Theresa A. Winer, Lung-Ming Wu
  • Patent number: 5332702
    Abstract: A fired, porous, zircon refractory body consisting essentially of zircon and having a sodium ion content, as an impurity, of less than 30 ppm. A furnace for making fused silica constructed with a crown and cup of such zircon refractory, and a method of making fused silica using such furnace.
    Type: Grant
    Filed: April 16, 1993
    Date of Patent: July 26, 1994
    Assignee: Corning Incorporated
    Inventors: Daniel R. Sempolinski, Latha I. Swaroop
  • Patent number: 5328874
    Abstract: This invention relates to the preparation of a glass exhibiting a transition temperature normally below about 300.degree., a working temperature below about 400.degree., while, at the same time, exhibiting excellent resistance to attack by water. Specifically, the present invention discloses a glass consisting essentially in terms of mole percent on the oxide basis, of 15-35% P.sub.2 O.sub.5, 1-25% SO.sub.3, 30-55% ZnO, 0-25% R.sub.2 O, wherein R.sub.2 O is selected from the group consisting of 0-25% Li.sub.2 O, 0-25% Na.sub.2 O, and 0-25% K.sub.2 O, and up to a total of 15% of optional ingredients in the indicated proportions selected from the group consisting of 0-10% Al.sub.2 O.sub.3, 0-10% MgO, 0-10% CaO, 0-10% SrO, 0-10% BaO, 0-10% MnO, 0-10% transition metal oxides and 0-15% Cl+F, as analyzed in weight percent.
    Type: Grant
    Filed: October 18, 1993
    Date of Patent: July 12, 1994
    Assignee: Corning Incorporated
    Inventors: George H. Beall, Joseph E. Pierson
  • Patent number: 5322819
    Abstract: A non-photochromic R.sub.2 O-B.sub.2 O.sub.3 -SiO.sub.2 glass containing a cuprous or cuprous-cadmium halide crystal phase, having a sharp spectral cutoff at about 400 nm, the glass composition consisting essentially of, in cation percent, 35-73% SiO.sub.2, 15-45% B.sub.2 O.sub.3, 0-12% Al.sub.2 O.sub.3, the Al.sub.2 O.sub.3 being less than 10% when the SiO.sub.2 is over 55%, 0-12% Li.sub.2 O, 0-20% Na.sub.2 O, 0-12% K.sub.2 O, the Li.sub.2 O+Na.sub.2 O+K.sub.2 O being 4.75-20%, 0-5% CaO+BaO+SrO, 0.125-1.0% Cu.sub.2 O, 0-1% CdO, 0-5% ZrO.sub.2, 0-0.75% SnO.sub.2, 0-1% As.sub.2 O.sub.3 and/or Sb.sub.2 O.sub.3, the glass containing 0-1.75%. Cl, 0-1.0% Br, 0.25-2.0% Cl+Br and 0-2% F by weight, and having an R-value, calculated in mole percent of 0.15-0.45, the R-value not exceeding 0.30, except as the glass composition meets at least one condition selected from the group: up to 12 cation % Li.sub.2 O, less than 10 cation % Al.sub.2 O.sub.3, at least 0.3 cation % Cu.sub.2 O and 0.50-2.0% Cl+Br.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: June 21, 1994
    Assignee: Corning Incorporated
    Inventors: Roger J. Araujo, David W. Morgan
  • Patent number: 5312689
    Abstract: An improved, laminated, ophthalmic lens structure, and method of producing the structure. The structure comprises two adjacent layers of dissimilar, organic plastic materials, either or both of which contain matter that tends to migrate. The improvement comprises a barrier layer that is intermediate the adjacent organic plastic layers; that is impermeable to migrating matter; and that is composed of a polyolefin polymeric material modified by the presence of acid or anhydride functional groups.
    Type: Grant
    Filed: February 22, 1993
    Date of Patent: May 17, 1994
    Assignee: Corning Incorporated
    Inventors: David Dasher, E. Robert Fretz, Jr., Mark S. Friske, Ronald E. Johnson
  • Patent number: 5300464
    Abstract: Glass or crystal particles of nanocrystalline size having a minor dimension of 0.1 to 100 Angstrom units. They may be prepared by controlled thermal separation of phase-separable glasses. Preferred crystal forms are zinc pyrophosphate and lithium disilicate. A crystallizable glass is combined with phyllosilicate particles and sintered to form an oriented composite body. During slow sintering, the crystal grows epitaxially on the phyllosilicate.
    Type: Grant
    Filed: December 16, 1992
    Date of Patent: April 5, 1994
    Assignee: Corning Incorporated
    Inventor: Hermann L. Rittler
  • Patent number: 5300170
    Abstract: Apparatus and method for transfer and application of an offset, heat release decal to an article surface. A thin, supported, silicone membrane is indexed through successive work positions where the membrane is heated, picks up a heated decal and brings the decal into contact with the article surface for printing.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: April 5, 1994
    Assignee: Corning Incorporated
    Inventor: John Donohoe
  • Patent number: 5288669
    Abstract: This invention relates to glasses exhibiting refractive indices higher than 1.880, Abbe numbers of at least 29, densities lower than 4.1, good chemical durability and stability against devitrification, and an integrated transmission over the range of 380-800 nm at a thickness of 10 mm greater than 79%, the glasses consisting essentially, expressed in terms of weight percent on the oxide basis, of______________________________________ SiO.sub.2 5-8 B.sub.2 O.sub.3 15-21 ZrO.sub.2 3-10 TiO.sub.2 7-17 Nb.sub.2 O.sub.5 20.5-26 ZrO.sub.2 + TiO.sub.2 + Nb.sub.2 O.sub.5 29-45 La.sub.2 O.sub.3 19-32 Y.sub.2 O.sub.3 0-9 CaO 8-16 SrO 0-5 BaO 0-5 MgO 0-5 CaO + SrO + BaO + MgO 8-16 ZnO 0-5 Li.sub.2 O 0-2 Na.sub.2 O 0-2 K.sub.2 O 0-2 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 0-2.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: February 22, 1994
    Assignee: Corning France S.A.
    Inventors: Luc Grateau, Pascale Laborde, Michel Prassas
  • Patent number: 5288668
    Abstract: This invention is directed to the production of borosilicate glasses displaying a pink coloration and a chromaticity at a thickness of 4 mm with Illuminant C within the ranges of:x=0.3115-0.4200y=0.3170-0.3600Y=15-92%The glasses consist essentially, expressed in terms of weight percent on the oxide basis, of______________________________________ SiO.sub.2 65-85 B.sub.2 O.sub.3 <20 Na.sub.2 O 0-8 K.sub.2 O 0-8 Na.sub.2 O + K.sub.2 O 2-8 Al.sub.2 O.sub.3 1-6 MnO.sub.2 0.05-1.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: February 22, 1994
    Assignee: Corning Incorporated
    Inventor: Paul L. Netter
  • Patent number: 5286683
    Abstract: This invention is directed to the production of glasses exhibiting transition temperatures below 375.degree. C., preferably below 350.degree. C., and superior resistance to attack by boiling water. The glasses contain at least 10% copper, as expressed in terms of CuO, the predominant proportion of the copper being present in the Cu.sup.+2 oxidation state. The glasses consist essentially, in mole percent, of______________________________________ Li.sub.2 O 0-15 MgO 0-15 B.sub.2 O.sub.3 0-5 Na.sub.2 O 0-20 CaO 0-20 ZnO 0-37 K.sub.2 O 0-10 SrO 0-20 Sb.sub.2 O.sub.3 0-36 Tl.sub.2 O 0-15 BaO 0-20 CeO.sub.2 0-3 Li.sub.2 O + Na.sub.2 O + 12-30 MgO + 0-25 MoO.sub.3 0-7 K.sub.2 O + Tl.sub.2 O CaO + SrO + BaO CuO 10-50 Al.sub.2 O.sub.3 + B.sub.2 O.sub.3 0-5 RE.sub.2 O.sub.3 0-2 P.sub.2 O.sub.5 28-36 Al.sub.2 O.sub.3 0-5 WO.sub.3 0-7 MnO 0-20 ______________________________________wherein at least two alkali metal oxides are present and up to 12% by weight fluoride may optionally be present.
    Type: Grant
    Filed: November 5, 1992
    Date of Patent: February 15, 1994
    Assignee: Corning Incorporated
    Inventor: Bruce G. Aitken
  • Patent number: 5283212
    Abstract: This invention relates to thallium tellurite glasses possessing a high Verdet constant and high optical nonlinearity, as well as good visible and infrared transmission, making them suitable materials for the fabrication of active optical devices. The glasses consist essentially, expressed in terms of cation percent, of 5-74.5% TeO.sub.2, 0.5-20% SiO.sub.2, 4-50% TlO.sub.0.5, and 0-71% PbO, wherein PbO+T10.sub.0.5.gtoreq.25 %, TeO.sub.2 +SiO.sub.2 .gtoreq.25%, and TeO.sub.2 +SiO.sub.2 +TlO.sub.0.5 +PbO constitutes at least 65% of the total composition.
    Type: Grant
    Filed: December 17, 1992
    Date of Patent: February 1, 1994
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Douglas W. Hall, Mark A. Newhouse
  • Patent number: 5283211
    Abstract: This invention relates to thallium germanate, tellurite, and antimonite glasses possessing high optical nonlinearity, as well as good visible and infrared transmission, making them suitable materials for the fabrication of active optical devices.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: February 1, 1994
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Douglas W. Hall, Mark A. Newhouse
  • Patent number: 5281249
    Abstract: A method and apparatus for imparting a predetermined contour to an ophthalmic glass lens.The method comprises positioning a forming manifold in the base of a reshaping chamber, the upper surface of the manifold having a surface contour that is the reverse of the bottom contour surface of the reshaped lens, positioning the lens blank in the chamber, heating the lens blank to a temperature at which the blank deforms, and establishing a continuous, lateral flow of gas on the upper surface of the forming manifold whereby the glass is supported while it sags to the desired shape.The apparatus comprises a reshaping chamber, a source of heat to bring a lens blank to its deforming temperature, a forming manifold having an upper surface contour that is the reverse of the desired contour on the lower surface of the reshaped lens blank, and means to supply a continuous, lateral flow of gas on the upper surface of the manifold whereby the glass blank is supported while it deforms to the desired shape.
    Type: Grant
    Filed: June 1, 1993
    Date of Patent: January 25, 1994
    Assignee: Corning Incorporated
    Inventors: Leslie E. Hampton, John W. Nelson
  • Patent number: 5281562
    Abstract: A non-photochromic R.sub.2 O--B.sub.2 O.sub.3 --SiO.sub.2 glass containing a cuprous or cuprous-cadmium halide crystal phase, having a sharp spectral cutoff at about 400 nm, the glass composition consisting essentially of, in cation percent, 35-73% SiO.sub.2, 15-45% B.sub.2 O.sub.3, 0-12% Al.sub.2 O.sub.3, the Al.sub.2 O.sub.3 being less than 10% when the SiO.sub.2 is over 55%, 0-12% Li.sub.2 O, O-20% Na.sub.2 O, 0-12% K.sub.2 O, the Li.sub.2 O+Na.sub.2 O+K.sub.2 O being 4.75-20%, 0-5% CaO+BaO+SrO, 0.125-1.0% Cu.sub.2 O, 0-1% CdO, 0-5% ZrO.sub.2, 0-0.75% SnO.sub.2, 0-1% As.sub.2 O.sub.3 and/or Sb.sub.2 O.sub.3, the glass containing 0-1.75% Cl, 0-1.0% Br, 0.25-2.0% Cl+Br and 0-2% F by weight, and having an R-value, calculated in mole percent of 0.15-0.45, the R-value not exceeding 0.30, except as the glass composition meets at least one condition selected from the group: up to 12 cation % Li.sub.2 O, less than 10 cation % Al.sub.2 O.sub.3, at least 0.3 cation % Cu.sub.2 O and 0.50-2.0% Cl+Br.
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: January 25, 1994
    Assignee: Corning Incorporated
    Inventors: Roger J. Araujo, David W. Morgan
  • Patent number: 5281399
    Abstract: A refractory body assembly includes a refractory container, a refractory body having multiple gas passageways and positioned within the container, and a barrier layer in the intermediate space. The barrier layer is a rigid foam which, in a basic form, may be composed essentially of a crystalline aluminum phosphate, and may be produced by heating a mixture of a source of phosphorous, an organic liquid buffer and a source of aluminum. The assembly may further include a positioning ring for positioning and maintaining the refractory body in a central position until the barrier layer becomes rigid.
    Type: Grant
    Filed: July 19, 1991
    Date of Patent: January 25, 1994
    Assignee: Corning Incorporated
    Inventor: Hermann Rittler
  • Patent number: 5281560
    Abstract: Lead-free, tin phosphate glasses contain 25-50 mole percent P.sub.2 O.sub.5, 30-70% SnO, 0-15% ZnO, the mole ratio of SnO:ZnO being greater than 5:1, and an effective amount up to 25% total of at least one oxide in the indicated proportion selected from the group consisting of up to 25% R.sub.2 O, wherein R.sub.2 O consists of 0-25% Li.sub.2 O, 0-25% Na.sub.2 O, and 0-25% K.sub.2 O, up to 20% B.sub.2 O.sub.3, up to 5% Al.sub.2 O.sub.3, up to 5% SiO.sub.2, and up to 5% WO.sub.3. The glasses are particularly useful as sealing glass frits in sealing material to join component parts in electrical and electronic devices. The sealing glass material may contain mill additions to reduce the effective coefficient of thermal expansion in a seal, as well as a strength reinforcing additive having a coefficient of thermal expansion preferably below 120.times.10.sup.-7 /.degree.C.
    Type: Grant
    Filed: June 21, 1993
    Date of Patent: January 25, 1994
    Assignee: Corning Incorporated
    Inventors: Gaylord L. Francis, Robert Morena
  • Patent number: 5275979
    Abstract: Thermally induced color is developed in a glass article containing a silver halide crystal phase by including in the glass batch a thermal reducing agent, retaining the thermal reducing agent in its lower valence state while meltinq the batch and forming the glass article and subsequently heat treating the article to partially reduce the silver halide crystal phase.
    Type: Grant
    Filed: October 30, 1992
    Date of Patent: January 4, 1994
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, David W. Morgan, Michel Prassas, Dennis W. Smith