Patents Represented by Attorney Cynthia L. Stokes
  • Patent number: 5587425
    Abstract: A method for preparing blends of a copolymer in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomer in the presence of a randomizer; (2) an initiator and monovinylaromatic monomer; (3) a mixture of monovinylaromatic and conjugated diene monomers; (4) a mixture of monovinylaromatic and conjuated diene monomers; (5) conjugated diene monomer; and (6) a coupling agent; and the polymodal tapered block copolymers prepared thereby. The copolymers are particularly useful neat or in blends for applications such as packaging and food or drink containers which require transparency and good environmental stress crack resistance.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: December 24, 1996
    Assignee: Phillips Petroleum Company
    Inventors: George A. Moczygemba, Nancy R. Knight, William J. Trepka, Nathan E. Stacy
  • Patent number: 5545690
    Abstract: A method for preparing tapered block copolymers which are particularly useful for blend components in blends with polymers of styrene. In the first embodiment of this invention the copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; and (4) a coupling agent; to produce a polymodal tapered block copolymer. In a second embodiment of the Invention tapered block copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; (4) a mixture of monovinylaromatic and conjugated diene monomers; and (5) a coupling agent; to produce a polymodal tapered block copolymer.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 13, 1996
    Assignee: Phillips Petroleum Company
    Inventors: William J. Trepka, George A. Moczygemba, Nathan E. Stacy, Ralph C. Farrar, Jr.
  • Patent number: 5502265
    Abstract: A process for polymerizing olefins with a catalyst system which comprises contacting a ribbon-like clay selected from the group consisting of sepiolites with a chromium solution. Preparation of said chromium solution comprises the steps offa) dissolving a chromium salt and a base in water by heating solution at a temperature in the range of about 20.degree. C. to about 100.degree. C. thereby producing a first chromium solution having a pH in the range of about 1.5 to 2.5;b) diluting said first chromium solution with water so as to produce a second chromium solution wherein first chromium solution is diluted such that the ratio of added water to first chromium solution is in the range of about 5 ml H.sub.2 O to about 10 mls H.sub.2 O to per ml first solution, and thereafter heating said second chromium solution at a temperature in the range of about 60.degree. C. to about 95.degree. C. for a time period in the range of about 60 to about 180 minutes.
    Type: Grant
    Filed: September 29, 1994
    Date of Patent: March 26, 1996
    Assignee: Phillips Petroleum Company
    Inventor: Joseph S. Shveima
  • Patent number: 5439983
    Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: July 27, 1994
    Date of Patent: August 8, 1995
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5412052
    Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: May 11, 1994
    Date of Patent: May 2, 1995
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5399628
    Abstract: A method for preparing tapered block copolymers in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomer in the presence of a randomizer; (2) an initiator and monovinylaromatic monomer; (3) a mixture of monovinylaromatic and conjugated diene monomers; (4) a mixture of monovinylaromatic and conjugated diene monomers; (5) conjugated diene monomer; and (6) a coupling agent; and the polymodal tapered block copolymers prepared thereby. The copolymers are particularly useful neat or in blends for applications such as packaging and food or drink containers which require transparency and good environmental stress crack resistance.
    Type: Grant
    Filed: December 2, 1993
    Date of Patent: March 21, 1995
    Assignee: Phillips Petroleum Company
    Inventors: George A. Moczygemba, Nancy R. Knight, William J. Trepka, Nathan E. Stacy
  • Patent number: 5376729
    Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: July 15, 1993
    Date of Patent: December 27, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5376611
    Abstract: A process for preparing pillared chromium ribbon-like silicate clay .alpha.-olefin catalysts is disclosed which comprises contacting a ribbon-like clay selected from the group consisting of sepiolites with a chromium solution. Preparation of said chromium solution comprises the steps of:a) dissolving a chromium salt and a base in water by heating solution at a temperature in the range of about 20.degree. C. to about 100.degree. C. thereby producing a first chromium solution having a pH in the range of about 1.5 to 2.5;b) diluting said first chromium solution with water so as to produce a second chromium solution wherein first chromium solution is diluted such that the ratio of added water to first chromium solution is in the range of about 5 ml H.sub.2 O to about 10 mls H.sub.2 O to per ml first solution, and thereafter heating said second chromium solution at a temperature in the range of about 60.degree. C. to about 95.degree. C.
    Type: Grant
    Filed: May 6, 1993
    Date of Patent: December 27, 1994
    Assignee: Phillips Petroleum Company
    Inventor: Joseph S. Shveima
  • Patent number: 5368099
    Abstract: The use of a dextrin as the carbon source for achieving a complete nutrient medium capable of sustaining microbial activity in subterranean formations is disclosed.
    Type: Grant
    Filed: November 4, 1992
    Date of Patent: November 29, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Mary E. Davey, Diane Gevertz, Gary E. Jenneman, Scott T. Kellogg, Willis A. Wood, J. Bennett Clark
  • Patent number: 5363913
    Abstract: A novel process for sustaining microbial activity in subterranean formations which comprises introducing in addition to microbial nutrients, a sequestering anion. This process may include the sequential injection of sources of individual nutrient components which are deficient in said subterranean formation, whereby the injected phosphorus source is more readily transportable due to the presence of a sequestering agent in the formation.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: November 15, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Gary E. Jenneman, James B. Clark
  • Patent number: 5362869
    Abstract: Novel yeast extracts from Candida utilis which can be used as flavor enhancers and emulsifiers are disclosed. One flavor enhancing extract and one emulsifying extract is derived from raw Candida utilis; one flavor enhancing extract and one emulsifying extract is derived from pasteurized Candida utilis.
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: November 8, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Edward G. Schanus, Marinelle McPherson
  • Patent number: 5360064
    Abstract: The present invention provides a process for sustaining microbial activity in subterranean formations which comprises introducing as a microbial nutrient, an organic phosphate, This process may include the sequential injection of sources of individual nutrient components which are deficient in said subterranean formation, whereby the injected phosphorus source is an organic phosphate.
    Type: Grant
    Filed: December 22, 1992
    Date of Patent: November 1, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Gary E. Jenneman, J. Bennett Clark
  • Patent number: 5357000
    Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: April 26, 1993
    Date of Patent: October 18, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5341875
    Abstract: The present invention provides a process for injecting microbial nutrients into a subterranean formation wherein microorganism are provided a phosphorus nutrient source, and said phosphorus nutrient source into said formation under acid conditions.
    Type: Grant
    Filed: December 22, 1992
    Date of Patent: August 30, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Gary E. Jenneman, Bennett Clark
  • Patent number: 5337820
    Abstract: A novel process for sustaining microbial activity in subterranean formations which comprises introducing as a microbial nutrient, a scale inhibitor. This process may include the sequential injection of sources of individual nutrient components which are deficient in said subterranean formation, whereby the injected phosphorus source is selected from the group consisting of an organic phosphate and an organic phosphonate.
    Type: Grant
    Filed: December 22, 1992
    Date of Patent: August 16, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Gary E. Jenneman, J. Bennett Clark
  • Patent number: 5334685
    Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: September 10, 1992
    Date of Patent: August 2, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5331021
    Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: September 24, 1993
    Date of Patent: July 19, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5327967
    Abstract: A novel process for sustaining microbial activity in subterranean formations which comprises introducing as a microbial nutrient, a phosphite salt. This process may include the sequential injection of sources of individual nutrient components which are deficient in said subterranean formation, whereby the injected phosphorus source is selected from the group consisting of a phosphite salt and a phosphorous acid.
    Type: Grant
    Filed: December 22, 1992
    Date of Patent: July 12, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Gary E. Jenneman, J. Bennett Clark
  • Patent number: 5290870
    Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: May 21, 1993
    Date of Patent: March 1, 1994
    Assignee: Philliips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5290871
    Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: May 21, 1993
    Date of Patent: March 1, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh