Abstract: Hydroquinone is obtained in greater than 95 percent yield through a nonaqueous recovery process compatible with the methyl isobutyl ketone (MIBK) based diisopropylbenzene dihydroperoxide isolation process. Hydroquinone, from the Hock-splitting reaction, is precipitated (after most of the reaction solvent is distilled off), separated, repulped in acetone, crystallized and separated again. The supernatant from the first separation step contains hydroquinone along with tars. This stream is subjected to a purification process comprising a series of distillation and extraction steps so that the hydroquinone in that stream can be recycled back into the process.

Abstract: Latex is stabilized by the addition of small amounts of salts of maleic anhydride/alpha-methylstyrene adduct and maleic anhydride/alpha-methylstyrene dimer adduct. The adduct salt is incorporated into the emulsifier solution used in the emulsion polymerization system.

Abstract: Stable surface-active agents are produced by neutralizing the reaction product of maleic anhydride adducts of alpha-methylstyrene compounds and alpha-methylstyrene dimer compounds with sodium and potassium hydroxide solution.

Abstract: 2,6-Di tert alkyl-4-vinylphenols are copolymerized in free radical emulsion polymerization systems to form self-stabilizing polymers. Such polymers have the advantage that the antioxidant cannot be extracted or volatilized from the polymer.

Abstract: Phenolic age resistors such as 4-(3,5-ditertiary butyl-4-hydroxyphenyl)-2-butyl 2-methyl-4-thia-6-octanoyloxy-hexanoate are used as antioxidants in diene rubbers, such as butadiene-styrene types and in polyolefins, such as polypropylene.

Abstract: Compounds such as bis[1-(4-anilinophenoxy)-2-propyl] 4,7-dithiadecanedioate and [3-(4-anilinophenoxy)-2-hydroxypropyl] 4,7-dithiadecanedioate are provided by reactions between 4-anilinophenoxy alcohols and epoxides and a dicarboxylic acid. The bis(4-anilinophenoxy) ester products are useful as antioxidants in polymers.

Abstract: Compounds such as 1-(4-anilinophenoxy)-3-dodecanethio-2-propanol are formed by reaction between an epoxypropoxydiphenylamine and a thiol, an alcohol or an amine. The compounds produced are useful as antioxidants for natural and synthetic elastomers.