Abstract: Disclosed is a storage stable blend of a long chain polyol and a short chain diol wherein the diol is present in an amount whereby the diol and polyol form an incompatible blend. The blend is rendered storage stable by the addition of a compatibilizing amount of a phenol.
Abstract: Thermoset polymers are prepared by reacting an ethylenically unsaturated resin monomer and a bicyclic amide acetal with a polyisocyanate in the absence or presence of a vinyl monomer. Reaction rates are suitable for effecting RIM processing. The resultant polymers exhibit improved impact resistance. Further variation in physical properties can be achieved through the use of a diol chain extender for the polyisocyanate.
Type:
Grant
Filed:
August 5, 1987
Date of Patent:
September 13, 1988
Assignee:
Ashland Oil, Inc.
Inventors:
Anil B. Goel, Timothy A. Tufts, Joseph G. Holehouse
Abstract: Fiber reinforced molding compounds wherein the resinous matrix is a thermosetting linear polymer characterized in constituting two oligomeric ethylenically unsaturated polyester segments joined through a polyurethane residue and having acryloyl or methacryloyl end groups.
Type:
Grant
Filed:
January 27, 1987
Date of Patent:
July 19, 1988
Assignee:
Ashland Oil, Inc.
Inventors:
William R. Dunnavant, Gilbert M. Gynn, Richard E. Field
Abstract: Thermoset polymers are prepared by reacting an ethylenically unsaturated resin monomer and a bicyclic amide acetal with a polyisocyanate in the absence or presence of a vinyl monomer. Reaction rates are suitable for effecting RIM processing. The resultant polymers exhibit improved impact resistance. Further variation in physical properties can be achieved through the use of a diol chain extender for the polyisocyanate.
Type:
Grant
Filed:
November 17, 1986
Date of Patent:
July 12, 1988
Assignee:
Ashland Oil, Inc.
Inventors:
Anil B. Goel, Timothy A. Tufts, Joseph G. Holehouse
Abstract: Disclosed is a storage stable blend of a long chain polyol and a short chain glycol wherein the glycol is present in an amount whereby the glycol and polyol form an incompatible blend. The blend is rendered storage stable by the addition of a compatibilizing amount of a salt wherein the salt is formed from a metal having a charge density of from about 1.25 to about 1.45.
Type:
Grant
Filed:
May 22, 1987
Date of Patent:
July 5, 1988
Assignee:
Ashland Oil, Inc.
Inventors:
Christopher T. Moss, Gary E. Kimes, Timothy A. Tufts