Patents Represented by Attorney D. Sandford
  • Patent number: 4762540
    Abstract: Noise suppression and particle separation apparatus for flows of high pressure, high velocity, particle-laden, gaseous fluid, such as geothermal steam, comprises a gaseous fluid conduit that has axially installed around its discharge end a larger diameter, cylindrical inner expansion chamber having a number of flow-dividing fluid discharge openings at which fluid flow diffusing elements are connected for receiving and diffusing the flow of gaseous fluid from the apertures. A still-larger diameter, cylindrical noise suppression chamber is axially mounted around the inner chamber and flow diffusing elements. The diffusion elements increase the fluid flow noise frequency range and sound deadening material installed in the outer chamber absorbs noise in this higher frequency range so that the venting fluid noise level outside the apparatus is no more than about 95 dB.
    Type: Grant
    Filed: August 27, 1987
    Date of Patent: August 9, 1988
    Assignee: Union Oil Company of California
    Inventors: David M. Ruiz, Alvin S. Timmons
  • Patent number: 4759983
    Abstract: Normally tacky, pressure sensitive adhesive compositions comprise one or more polymers containing pendant functional groups attached to a polymer backbone and having the formula: ##STR1## in which R.sub.
    Type: Grant
    Filed: May 30, 1986
    Date of Patent: July 26, 1988
    Assignee: Union Oil Company of California
    Inventors: Gaylen M. Knutson, Paul J. Steinwand, Joseph J. Wilczynski, Lonnie T. Spada
  • Patent number: 4756888
    Abstract: A method is disclosed for controlling the deposition of metal-containing scales, such as iron silicate scale, from a hot, aqueous, geothermal brine or the like, without substantial corrosion of brine handling equipment. The brine is contacted with (1) an amount of an acid sufficient to reduce the pH of the brine between 0.1 and 0.5 unit and (2) a greater than stoichiometric amount of a reducing agent for reducing trivalent iron and manganese cations in a high temperature brine solution to divalent ions. An overall decrease in scale deposition, especially of iron silicate scale, is achieved while a silver-rich scale can be recovered from silver-containing brines.
    Type: Grant
    Filed: December 29, 1983
    Date of Patent: July 12, 1988
    Assignee: Union Oil Company of California
    Inventors: Darrell L. Gallup, John W. Jost
  • Patent number: 4755265
    Abstract: Methods for depositing metals on or removing metals from substrates are provided which involve the use of electrolytic cells comprising an anode and cathode, sulfuric acid, and a chalcogen-containing compound soluble in said bath and having the empirical formula ##STR1## wherein X is a chalcogen, each of R.sub.1 and R.sub.2 is selected from hydrogen, NR.sub.3 R.sub.4 and NR.sub.5, at least one of R.sub.1 and R.sub.2 is other than hydrogen, each of R.sub.3 and R.sub.4 is hydrogen or a monovalent organic radical, and R.sub.5 is a divalent organic radical, in which the molar ratio of the chalcogen compound to sulfuric acid is about 1 or more, and the molar ratio of water to the combination of acid and chalcogen compound is about 20 or less.
    Type: Grant
    Filed: March 3, 1987
    Date of Patent: July 5, 1988
    Assignee: Union Oil Company of California
    Inventor: Donald C. Young
  • Patent number: 4755469
    Abstract: A method for tagging an oil so that subsequently it may be identified as to source by incorporating into the oil as a tracer material an oil-soluble or oil-dispersible Group VIB, Group VIIB or lanthanum series rare earth metal salt of a fatty acid. The so-tagged oil may be utilized in any desired manner. Thereafter, an oil suspected to contain at least a portion of the so-tagged oil is analyzed for the presence of the added metal moiety. The method is especially useful in tracing a complex oleaginous and petroliferous material so that it may be recovered and identified following a theft or spill or to trace the flow of such oil injected through a subterranean reservoir.
    Type: Grant
    Filed: September 27, 1982
    Date of Patent: July 5, 1988
    Assignee: Union Oil Company of California
    Inventors: William E. Showalter, Elihu Goldish, Ronald J. Lukasiewicz
  • Patent number: 4754438
    Abstract: The invention is an apparatus for obtaining a step function response signal from a geophone, comprising: (1) a controllable source of current; (2) a means for producing a switching pulse; (3) an electronic connecting means for applying current from the source to the geophone, while the pulse is being produced; and (4) an electronic connecting means for conducting the response signal from the geophone to a data acquisition system, after the pulse has been produced. Preferably, a time delay means is used to delay the connecting of the signal to the data acquisition system, for a time after the pulse has been produced.
    Type: Grant
    Filed: May 15, 1985
    Date of Patent: June 28, 1988
    Assignee: Union Oil Company of California
    Inventor: Otis G. Erich, Jr.
  • Patent number: 4752452
    Abstract: The invention is a process and apparatus useful for preparing an aqueous ammonia solution at a temperature below the boiling point thereof by single stage dilution of anhydrous ammonia with water. In the invention, an anhydrous ammonia fluid comprising ammonia vapor is mixed with water to provide an aqueous ammonia fluid at a first temperature above the boiling point of said aqueous ammonia fluid, the aqueous ammonia fluid is cooled to a second temperature above the boiling point of said aqueous ammonia fluid, and the cooled aqueous ammonia fluid is then indirectly contacted with liquid anhydrous ammonia to further cool said aqueous ammonia fluid to a temperature below its boiling point and thereby heat the liquid anhydrous ammonia to vaporize at least a portion thereof. The heated anhydrous ammonia fluid is utilized in the process of this invention to provide the aqueous ammonia fluid.
    Type: Grant
    Filed: March 10, 1983
    Date of Patent: June 21, 1988
    Assignee: Union Oil Company of California
    Inventors: Bruce A. Harbolt, Perry L. Murata
  • Patent number: 4745977
    Abstract: A method for resisting corrosion while conducting a flow of hot corrosive geothermal fluid, particularly brine, comprises flowing the fluid through fluid flow conducting elements, such as production pipe and fittings formed from a metastable beta titanium-base alloy. Preferably the element is formed of a beta and alpha titanium-base alloy formed by heating a particular composition to form a metastable beta titanium matrix and then heat treating the matrix to increase the tensile strength of the matrix by at least about 10,000 psi with a total minimum ultimate tensile strength being about 170,000 psi. The particular composition is comprised essentially of between about 2 and about 10 weight percent of one or more beta eutectoid elements selected from the group consisting of iron, manganese, chromium and cobalt, with weight percentage limits in each such individual element being respectively about 5, about 5.5, about 9 and about 4.
    Type: Grant
    Filed: April 12, 1985
    Date of Patent: May 24, 1988
    Assignee: Union Oil Company of California
    Inventors: William W. Love, Carl J. Cron
  • Patent number: 4746222
    Abstract: Apparatus for the mixing and cooling of hot, particulate matter, such as hot, retorted oil shale, comprises a plurality of enclosed, vertically spaced apart, converging vessels through which the material to be mixed and cooled is flowed. At least the lowermost vessel is configured for a packed bed flow of the material and has mounted therein, on a vertical drive shaft, a mixer blade assembly having a plurality of similar mixing blades which are upwardly inclined at an angle, A.sub.1, of between about 30.degree. and about 75.degree. and preferably within about .+-.15.degree. of the sidewall angle of the vessels. The blades are mounted so as to have an angle of attack, A.sub.2, relative to the rotational direction of travel, of between about 20.degree. and about 60.degree.. A constant angle of attack along each mixing blade is assured by making the angle, A.sub.3, between the blade leading edge and the blade base to be related to the blade inclination and attack angles in accordance with the relationship:A.sub.
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: May 24, 1988
    Assignee: Union Oil Company of California
    Inventors: Delwin E. Cobb, Chien-Cheng J. Shih, Charles F. Griswold
  • Patent number: 4743669
    Abstract: Certain urea-sulfuric acid components, comprised of urea and sulfuric acid in a 1/4 to 7/4 molar ratio, contain a monourea adduct of sulfuric acid, which is catalytically active for promoting organic chemical reactions. The invention provides methods employing such urea-sulfuric acid components for catalyzing organic reactions such as oxidation, oxidative addition, reduction, reductive addition, esterification, transesterification, hydrogenation, isomerization (including racemization of optical isomers), alkylation, polymerization, demetallization of organometallics, nitration, Friedel-Crafts reactions, and hydrolysis. Novel catalysts are disclosed which involve combinations of the urea-sulfuric component with one or more transition metal halides and/or with one or more surfactants. The surfactant-containing compositions are particularly useful for the treatment of materials containing lipophilic substances.
    Type: Grant
    Filed: October 3, 1985
    Date of Patent: May 10, 1988
    Assignee: Union Oil Company of California
    Inventor: Donald C. Young
  • Patent number: 4726144
    Abstract: The invention is directed to the fumigation of soils, enclosed spaces, agricultural products and other commodities, etc., using compositions which decompose to form carbon disulfide and certain other biocidal materials. Such fumigation can be used to control bacteria, fungi, insects, nematodes, rodents, and weeds.Fumigant compositions are described herein as "thiocarbonates," including, without limitation, salts of trithiocarbonic acid and tetrathiocarbonic acid, compositions having empirical formulae intermediate to these acid salts (such as MCS.sub.3.7, wherein M is a divalent metal ion), and compositions containing substances in addition to thiocarbonates [such as a stabilized ammonium tetrathiocarbonate which contains ammonium sulfide, i.e., (NH.sub.4).sub.2 CS.sub.4.(NH.sub.4).sub.2 S].The compositions are generally water soluble and can be prepared, stored, and used in aqueous solutions.
    Type: Grant
    Filed: November 16, 1984
    Date of Patent: February 23, 1988
    Assignee: Union Oil Company of California
    Inventors: Donald C. Young, James A. Green, II
  • Patent number: 4701555
    Abstract: The biuret content of biuret-containing urea is reduced by contacting a solution or melt of biuret-containing urea with a polar adsorbent under conditions sufficient to remove at least a portion of biuret from the urea. The resulting biuret-containing adsorbent can be regenerated for further use by contact with a polar desorbent under conditions sufficient to desorb at least a portion of the biuret contained on the adsorbent. Optionally, biuret can be recovered by recovering the biuret-containing desorbent, and biuret concentration in the desorbent can be increased by recycling the biuret-containing desorbent into contact with biuret-containing adsorbents, and biuret can be recovered from the desorbent by low temperature crystallization.
    Type: Grant
    Filed: July 10, 1985
    Date of Patent: October 20, 1987
    Assignee: Union Oil Company of California
    Inventors: Donald C. Young, James A. Green, II
  • Patent number: 4699633
    Abstract: This invention provides a method for treating an aerosol comprising electrostatically charged particles, suspended in a gas, to separate said particles from said gas, which comprises mixing said aerosol, in the absence of electrostatically charged water particles, with another aerosol including particles having the opposite charge to provide flocculated particles having a substantially neutral charge, and separating said flocculated particles from said gas.The method of this invention is useful for treating an aerosol emission from a power plant or a smelter which emission generally comprises positively charged particles. The emission may be mixed with a negatively charged aerosol comprising particulate sulfur to neutralize said positively charged particles and thereby flocculate said particulate sulfur. The neutralized particles are passed into a liquid water phase to provide an aqueous solution and flocculated sulfur, which may be separated from said aqueous solution as an insoluble sulfur phase.
    Type: Grant
    Filed: October 5, 1984
    Date of Patent: October 13, 1987
    Assignee: Union Oil Company of California
    Inventor: Donald C. Young