Patents Represented by Attorney Daniel C. Block
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Patent number: 4448929Abstract: A protective colloid for use in an interfacial polymerization process comprising a graft copolymer of polyvinyl alcohol and methyl vinyl ether/maleic acid.Type: GrantFiled: June 1, 1982Date of Patent: May 15, 1984Assignee: Stauffer Chemical CompanyInventors: Marius Rodson, Herbert B. Scher
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Patent number: 4386955Abstract: Herbicidally active thiolcarbamates are employed in combination with certain 0-(substituted phenyl) N-methyl carbamates having the formula ##STR1## in which R.sup.4 is selected from the group consisting of ##STR2## R.sup.5 is selected from the group consisting of hydrogen, hydroxy, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.2 -C.sub.6 alkylthioalkoxy, and and thiocyanatomethyl,R.sup.6 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.3 alkyl, and C.sub.1 -C.sub.3 alkoxy, and n is zero or one.In a typical application, the O-(substituted phenyl) N-methyl carbamate is included in sufficient quantity to lessen the rate of soil degradation of the thiolcarbamate. As a result, the herbicidal effectiveness of the thiolcarbamate is enhanced and prolonged, rendering a single application of the herbicide effective over a longer period of time.Type: GrantFiled: April 20, 1981Date of Patent: June 7, 1983Assignee: Stauffer Chemical CompanyInventor: Daniel L. Hyzak
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Patent number: 4381936Abstract: Herbicidally active thiolcarbamates are employed in combination with certain substituted carbamates having the formula ##STR1## in which R.sup.4 and R.sup.5 are each methyl,R.sup.4 and R.sup.5 conjointly form C.sub.1 -C.sub.4 alkylenedioxy,R.sup.4 is --CF.sub.3 and R.sup.5 is hydrogen, orR.sup.4 is --CH.sub.2 Br and R.sup.5 is hydrogen.In a typical application, the carbamate is included in sufficient quantity to lessen the rate of soil degradation of the thiolcarbamate. As a result, the herbicidal effectiveness of the thiolcarbamate is enhanced and prolonged, rendering a single application of the herbicide effective over a longer period of time.Type: GrantFiled: July 20, 1981Date of Patent: May 3, 1983Assignee: Stauffer Chemical CompanyInventor: Daniel L. Hyzak
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Patent number: 4381195Abstract: Herbicidally active thiolcarbamates are employed in combination with certain N-methylcarbamoyloxy anilides having the formula ##STR1## in which R.sup.4 is selected from the group consisting of hydrogen and carbethoxymethyl,R.sup.5 is selected from the group consisting of C.sub.1 -C.sub.6 alkyl, halogenated C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.3 -C.sub.6 cycloalkyl, C.sub.3 -C.sub.5 alkanoylmethyl, C.sub.1 -C.sub.3 alkylamino, C.sub.1 -C.sub.3 dialkylamino, carbamylthiomethyl, and C.sub.2 -C.sub.4 carbalkoxyamino,R.sup.6 is selected from the group consisting of C.sub.1 -C.sub.3 alkyl, C.sub.2 -C.sub.4 alkanoylamino, and halogen,X is selected from the group consisting of oxygen and sulfur, andn is zero or one.In a typical application, the isonitrile is included in sufficient quantity to lessen the rate of soil degradation of the thiolcarbamate.Type: GrantFiled: April 20, 1981Date of Patent: April 26, 1983Assignee: Stauffer Chemical CompanyInventor: Daniel L. Hyzak
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Patent number: 4381196Abstract: Herbicidally active thiolcarbamates are employed in combination with certain O-(substituted phenyl) N-methylcarbamates having the formula ##STR1## in which R.sup.4 is selected from the group consisting of hydrogen and C.sub.1 -C.sub.3 alkyl,R.sup.5 is C.sub.1 -C.sub.3 alkyl,R.sup.6 is selected from the group consisting of hydrogen, formyl, C.sub.1 -C.sub.3 alkoxy, and N-methylcarbamoyloxy, andX is selected from the group consisting of oxygen and sulfur.In a typical application, the N-methylcarbamate is included in sufficient quantity to lessen the rate of soil degradation of the thiolcarbamate. As a result, the herbicidal effectiveness of the thiolcarbamate is enhanced and prolonged, rendering a single application of the herbicide effective over a longer period of time.Type: GrantFiled: April 20, 1981Date of Patent: April 26, 1983Assignee: Stauffer Chemical CompanyInventor: Daniel L. Hyzak
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Patent number: 4380468Abstract: Herbicidally active thiolcarbamates are employed in combination with certain substituted phenyl isonitriles having the formula ##STR1## in which R.sup.1 is selected from the group consisting of C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylthio, phenyl, halogen, benzylthio, and p-chlorobenzylthio, andR.sup.2 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, and halogen.In a typical application, the isonitrile is included in sufficient quantity to lessen the rate of soil degradation of the thiolcarbamate. As a result, the herbicidal effectiveness of the thiolcarbamate is enhanced and prolonged, rendering a single application of the herbicide effective over a longer period of time.Type: GrantFiled: October 2, 1981Date of Patent: April 19, 1983Assignee: Stauffer Chemical CompanyInventor: Raymond A. Felix
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Patent number: 4219547Abstract: Insecticidally active compounds are described herein, which are defined by the following generic formula ##STR1## wherein X is oxygen or sulfur;R is lower alkyl or lower alkoxy;R.sub.1 is hydrogen or lower alkyl;R.sub.2 is selected from the group consisting of lower alkoxy, NH.sub.2, NHCH.sub.3, N(CH.sub.3).sub.2, ##STR2## R.sub.3 is selected from the group consisting of methyl, methoxy, SCH.sub.3, NO.sub.2, and ##STR3## R.sub.4 is selected from the group consisting of hydrogen, chlorine, and methyl; andR.sub.5 is hydrogen or chlorine.Type: GrantFiled: March 18, 1976Date of Patent: August 26, 1980Assignee: Stauffer Chemical CompanyInventor: Arnold D. Gutman
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Patent number: 4178297Abstract: This invention relates to the preparation of unsaturated alcohols useful as flavor and fragrance compounds. More specifically, this invention relates to the preparation of predominately cis-unsaturated alcohols by reacting a cis-1-alkenylaluminum dialkyl compound with an epoxide compound followed by hydrolysis. The alkenyl moiety has one or more double bond carbon-to-carbon linkage and from 5 to 20 carbon atoms that can be optionally substituted with the substituents selected from alkyl and aromatic radicals having 1 to 12 carbon atoms.Type: GrantFiled: November 16, 1978Date of Patent: December 11, 1979Assignee: Texas Alkyls, Inc.Inventors: Spencer C. Watson, Dennis B. Malpass, G. Scott Yeargin
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Patent number: 4174350Abstract: This invention relates to herbicidal active compounds and their use. The compounds of this invention correspond to the formula: ##STR1## wherein R is selected from cyclopropyl, ethyl, furyl, benzyl, methyl, and 3,4-methylenedioxy-benzyl; R.sub.1 is selected from chloro and trifluoromethyl; R.sub.2 is selected from hydrogen, 4-chloro, 4-propargyloxy, and 5-chloro; R.sub.3 is selected from ethyl, chloroethyl, isobutyl, allyl and propargyl.Type: GrantFiled: February 21, 1978Date of Patent: November 13, 1979Assignee: Stauffer Chemical CompanyInventor: Edmund J. Gaughan
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Patent number: 4144250Abstract: This invention relates to herbicidal active compounds and their use. The compounds of this invention correspond to the formula: ##STR1## wherein R is selected from cyclopropyl, ethyl, furyl, benzyl, methyl, and 3,4-methylenedioxybenzyl; R.sub.1 is selected from chloro and trifluoromethyl; R.sub.2 is selected from hydrogen, 4-chloro, 4-propargyloxy, and 5-chloro; R.sub.3 is selected from ethyl, chloroethyl, isobutyl, allyl and propargyl.Type: GrantFiled: February 21, 1978Date of Patent: March 13, 1979Assignee: Stauffer Chemical CompanyInventor: Edmund J. Gaughan
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Patent number: 4140705Abstract: This invention relates to herbicidal active compounds and their use. The compounds of this invention correspond to the formula: ##STR1## wherein R is selected from cyclopropyl, ethyl, furyl, benzyl, methyl, and 3,4-methylenedioxybenzyl; R.sub.1 is selected from chloro and trifluoromethyl; R.sub.2 is selected from hydrogen, 4-chloro, 4-propargyloxy, and 5-chloro; R.sub.3 is selected from ethyl, chloroethyl, isobutyl, allyl and propargyl.Type: GrantFiled: February 21, 1978Date of Patent: February 20, 1979Assignee: Stauffer Chemical CompanyInventor: Edmund J. Gaughan
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Patent number: 4136153Abstract: This invention relates to the substantial reduction of emission of noxious gases into the atmosphere. More specifically, this invention relates to a system for saturating mist eliminators in conjunction with the sulfuric acid plant to remove SO.sub.3 gas during an upset condition upstream of the mist eliminators. The system involves the spraying of sulfuric acid onto conventional mist eliminators to substantially saturate the same so that when contact is made with the mist eliminators by the SO.sub.3 gas the same will be absorbed and be removed and will be prevented from being emitted to the atmosphere.Type: GrantFiled: February 21, 1975Date of Patent: January 23, 1979Assignee: Stauffer Chemical CompanyInventors: Terrence M. Robertson, Larry G. Smith
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Patent number: 4133815Abstract: This invention relates to the preparation of unsaturated alcohols useful as flavor and fragrance compounds. More specifically, this invention relates to the preparation of predominantly cis-unsaturated alcohols by reacting a cis-1-alkenylaluminum dialkyl compound with an epoxide compound followed by hydrolysis. The alkenyl moiety has one or more double bond carbon-to-carbon linkage and from 5 to 20 carbon atoms that can be optionally substituted with the substituents selected from alkyl and aromatic radicals having 1 to 12 carbon atoms.Type: GrantFiled: March 11, 1976Date of Patent: January 9, 1979Assignee: Texas Alkyls, Inc.Inventors: Spencer C. Watson, Dennis B. Malpass, G. Scott Yeargin
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Patent number: 4127400Abstract: A process of manufacturing liquid fertilizer from ortho phosphoric acid is described herein. Specifically, the process involves extracting ortho phosphoric acid from phosphate rock using sulfuric acid in the usual manner. The ortho phosphoric acid is then concentrated to a P.sub.2 O.sub.5 content of 30-58% by weight. The wet process ortho phosphoric acid is then ammoniated at a carefully controlled pH in a range of about 3.0 to 5.5. Water and commercial clays are added to the ammoniated phosphoric acid during ammoniation or after ammoniation. A stable non-gelling suspension fertilizer results.Type: GrantFiled: October 21, 1974Date of Patent: November 28, 1978Assignee: Stauffer Chemical CompanyInventors: Alfred W. Petersen, Robert B. Calvin
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Patent number: 4123526Abstract: Compounds which are useful as insecticide activators are described herein. The compounds are defined by the following formula: ##STR1## wherein R is selected from the group consisting of lower alkoxy, dimethyl, trimethyl, halogen, dihalogen, trifluoromethyl, acetyl, acetamido, carbomethoxy, carbethoxy, methylenedioxy and ##STR2## and R' is methyl or ethyl.Type: GrantFiled: December 24, 1975Date of Patent: October 31, 1978Assignee: Stauffer Chemical CompanyInventors: George B. Large, Leland S. Pitt
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Patent number: 4110357Abstract: This invention relates to the preparation of unsaturated alcohols useful as flavor and fragrance compounds. More specifically, this invention relates to the preparation of predominately cis-unsaturated alcohols by reacting a cis-1-alkenyl-aluminum dialkyl compound with an epoxide compound followed by hydrolysis. The alkenyl moiety has one or more double bond carbon-to-carbon linkage and from 5 to 20 carbon atoms that can be optionally substituted with the substituents selected from alkyl and aromatic radicals having 1 to 12 carbon atoms.Type: GrantFiled: November 8, 1976Date of Patent: August 29, 1978Assignee: Texas Alkyls, Inc.Inventors: Spencer C. Watson, Dennis B. Malpass, G. Scott Yeargin
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Patent number: 4095970Abstract: Novel compounds of the formula ##STR1## wherein R is lower alkyl, cycloalkyl, cycloalkylmethyl, aryl, or aralkyl are useful as plant growth regulators.Type: GrantFiled: June 16, 1976Date of Patent: June 20, 1978Assignee: Stauffer Chemical CompanyInventor: Alan A. MacDonald
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Patent number: 4088687Abstract: This invention relates to herbicidal active compounds and their use. The compounds of this invention correspond to the formula: ##STR1## wherein R is selected from cyclopropyl, ethyl, furyl, benzyl, methyl, and 3,4-methylenedioxybenzyl; R.sub.1 is selected from chloro and trifluoromethyl; R.sub.2 is selected from hydrogen, 4-chloro, 4-propargyloxy, and 5-chloro; R.sub.3 is selected from ethyl, chloroethyl, isobutyl, allyl and propargyl.Type: GrantFiled: February 6, 1976Date of Patent: May 9, 1978Assignee: Stauffer Chemical CompanyInventor: Edmund J. Gaughan
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Patent number: 4083970Abstract: A composition of matter is described herein which is useful as an activated insecticide.Type: GrantFiled: February 22, 1977Date of Patent: April 11, 1978Assignee: Stauffer Chemical CompanyInventors: George B. Large, Leland S. Pitt
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Patent number: 4081041Abstract: A system for collecting dust during drilling operations in a mine with a roof drill machine is described herein. The system consists of a mobile roof drilling machine having a conical shaped dust-collecting bowl adjacent to the surface being drilled. It is provided with annular space between the drill and the conical dust-collecting system to allow the drill to be injected into the roof of the mine. The system has a strong suction mechanism tangentially associated on each side of the dust-collecting system so as to provide a swirling motion of the falling dust particles.Type: GrantFiled: February 22, 1977Date of Patent: March 28, 1978Assignee: Stauffer Chemical Company of WyomingInventors: Michael J. Perri, Glen A. Zumwalt