Patents Represented by Attorney Daniel Woods
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Patent number: 6051730Abstract: A solid, water-soluble complex comprising:a) a water-miscible polysiloxane of the formula: ##STR1## wherein n is from 2 to 6; a is from 8 to 25; and b is from 0 to 25; and the oxyalkylene groups may be random or block mixtures; y is from 0 to 5; x is from 1 to 5; and R is selected from the group consisting of hydrogen, C.sub.1- C.sub.4 alkyl, and a C.sub.1- C.sub.4, alkyl ester; or ##STR2## wherein A is a linear or branched alkyl having 6 to 30 carbon atoms; G is a glycol moiety of the formula --R' (OCH.sub.2 CH.sub.2) .sub.m OR" wherein R' is a divalent alkylene group having 2 to 6 carbon atoms; R" is selected from the group consisting of hydrogen, C.sub.1- C.sub.4 alkyl, and a C.sub.1- C.sub.4 alkyl ester; m is 8 to 100; y is 0 to 5; X is 0.1 to 2.5; and z is 0.1 to 5.0; andb) a complex-forming agent of the formula: ##STR3## wherein X is O, S, Sc, or Te. These complexes are useful useful as adjuvants for dry agricultural chemicals such as pesticides and/or fertilizers.Type: GrantFiled: May 5, 1997Date of Patent: April 18, 2000Assignee: Rhodia Inc.Inventors: Norman R. Pallas, James L. Hazen
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Patent number: 6040288Abstract: Provided are methods of washing fabric articles in the presence of silicone oils to provide for color protection and/or fragrance retention in the washing of fabric articles with detergents. Fabric articles are washed in a washing medium comprised of a major amount by weight of water, a first minor amount by weight of a detergent and a second minor amount by weight of an aminosilicone having the formula: ##STR1## wherein: the variables are defined in the specification wherein said first minor amount by weight is greater than said second minor amount by weight. In preferred embodiments of this method, said washing medium is the product of mixing water with a composition comprised of said aminosilicone compound in association with an insoluble support. In particularly preferred embodiments, an aminosilicone compound wherein R.sup.1 and R.sup.8 are both alkoxy, (typically methoxy) is employed.Type: GrantFiled: February 20, 1998Date of Patent: March 21, 2000Assignee: Rhodia Inc.Inventors: Christine Popoff, Alwyn Nartey, Robert Gabriel, Eric Aubay
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Patent number: 6040484Abstract: The present invention relates to a process for the hydroxylation of phenolic compounds and, more particularly, to a process for the hydroxylation of phenols and phenolic ethers with hydrogen peroxide. The invention relates to a process for the hydroxylation of phenolic compounds using hydrogen peroxide, said process being characterized in that the reaction is carried out in the presence of an effective quantity of at least one rare earth or bismuth triflate.Type: GrantFiled: August 13, 1998Date of Patent: March 21, 2000Assignee: Rhodia ChimieInventors: Michel Costantini, Laurent Gilbert, Michel Spagnol
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Patent number: 6030938Abstract: A novel, salt-free monoamphopropionate amphoteric surfactant is prepared in yields of from 75% to 80%, from a reaction comprising an imidazoline and a mixture of acrylic acid and sodium acrylate in an aqueous medium. The acrylic acid/sodium acrylate mixture is comprised of the two components in a range of molar ratios of from about 1:6 to about 1:3, respectively, and by replacing methyl acrylate, the reaction does away with the production of methanol which is an unwanted, hazardous and toxic byproduct. The imidazoline reacts in amounts in excess of 90% resulting in the highly pure yields and any left over unreacted acrylic acid can be easily removed by treating it with sodium bisulfate.Type: GrantFiled: December 31, 1996Date of Patent: February 29, 2000Assignee: Rhodia Inc.Inventors: Shiming Wo, Ji Li, Mohamed Hashem, Rastko Vukov
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Patent number: 6030630Abstract: A cosmetic composition for the hair and/or skin comprising a water-dispersible sulfone copolyester with polyorganosiloxane units incorporating a plurality of recurrent sulfone polyester units and polyorganosiloxane units which have: a molecular mass number between 5000 and 45,000; a sulfur weight content of 0.5 to 6% compared with the said sulfone copolyesters with polyorganosiloxane units; and a silicium content of 0.05 to 20% by weight compared with the said sulfone copolyesters with polyorganosiloxane units.Type: GrantFiled: June 29, 1998Date of Patent: February 29, 2000Assignee: Rhodia ChimieInventors: Etienne Fleury, Jean-Marc Ricca
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Patent number: 6013840Abstract: The present invention concerns a process for the acylation of an aromatic ether.Preferably the invention relates to a process for the acylation of a substituted aromatic ether, in particular veratrol.The acylation process of the invention consists of reacting the ether with an acylation agent in the presence of a zeolitic catalyst, and is characterized in that the acylation reaction is carried out in the presence of an effective quantity of a catalyst comprising a faujasite type zeolite or a Y zeolite with the following physico-chemical characteristics:an atomic ratio denoted "global Si/Me.sup.1 " between the number of atoms of the element silicon and the number of atoms of every trivalent element Me.sup.1 contained in the zeolite in the range 2.4 to 90, preferably in the range 2.4 to 75, and more preferably in the range 2.4 to 60;an Me.sup.2 alkali metal content such that the atomic ratio Me.sup.2 /Me.sup.1(IV) between the number of atoms of alkali metal Me.sup.Type: GrantFiled: January 9, 1997Date of Patent: January 11, 2000Assignee: Rhodia ChimieInventors: Michel Spagnol, Laurent Gilbert, Eric Benazzi, Christian Marcilly
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Patent number: 6013185Abstract: Contaminated aqueous systems can be cleaned using an ultra-filtration system that allows for high recovery yields of the surfactant employed therein for recycle and reuse. The system employs specific nonionic surfactants which remain polar and solvated at the higher operating temperatures of the system. The surfactant/contaminant containing aqueous system is ultra-filtered resulting in the surfactant passing through with the permeate at extremely high yields for recovery and reuse.Type: GrantFiled: September 25, 1997Date of Patent: January 11, 2000Assignee: Rhodia Inc.Inventors: Mark E. Ventura, Manilal S. Dahanayake
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Patent number: 6004466Abstract: Contaminated aqueous systems can be cleaned using an ultra-filtration process that allows for the recovery of high yields of the surfactant employed therein for recycle and reuse. The system employs a specific class of sugar-derived nonionic surfactants which remain polar and solvated at the higher operating temperatures of the system. Specifically, these are sugar-derived nonionic surfactants more definitively known as the alkyl polyglycosides and the alkyl glucomides. The surfactant/contaminant-containing aqueous system is ultra-filtered resulting in the surfactant passing through with the permeate at extremely high yields for recovery and reuse.Type: GrantFiled: October 30, 1998Date of Patent: December 21, 1999Assignee: Rhodia Inc.Inventors: Paul-Joel Derian, Manilal S. Dahanayake, Mark Ventura, Jeremy LaCrosse
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Patent number: 5998349Abstract: The invention relates to a descaling formulation comprising cellulose microfibrils, in which at least 80% of the cells have primary walls and not more than 20% of the cells have secondary walls, with a degree of crystallinity of not more than 50%. The pH of the formulation is less than or equal to 1 and more particularly less than or equal to 0.5.Type: GrantFiled: April 2, 1998Date of Patent: December 7, 1999Assignee: Rhodia ChimieInventor: Veronique Guillou
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Patent number: 5989524Abstract: Silica compatible with flavors, exhibiting, at an RP/DA abrasivity lower than or equal to 10, a compatibility with flavors which is higher than 10% and, at an RP/DA abrasivity higher than 10, a compatibility with flavors of at least 30%. Process for the preparation of flavor-compatible silica by treating the surface of a silica originating from the reaction of an alkali metal silicate with an inorganic or organic acidic agent, the silica being in dry form or in an aqueous suspension, with the aid of an organic compound capable of developing hydrogen bonds or ionic bonds with, respectively, the Si--OH silanol groups or the SiO.sup.- anionic groups at the surface of the said silica to be treated, the said treated silica being subsequently, if necessary, isolated and/or washed and/or dried. Use in dentifrice compositions and dentifrice compositions including the said silica.Type: GrantFiled: July 18, 1997Date of Patent: November 23, 1999Assignee: Rhodia ChimieInventors: Adrien Dromard, Jean-Francois Viot
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Patent number: 5932191Abstract: The present invention relates to silicas, in particular precipitated silicas, which can be used in particular as abrasive agents in toothpaste compositions. The silicas according to the invention have, first of all, low specific surfaces. Their BET specific surface is between 20 and 75 m.sup.2 /g, preferably between 35 and 64 m.sup.2 /g. The invention also relates to a process for their preparation and to the toothpaste compositions containing them.Type: GrantFiled: July 31, 1996Date of Patent: August 3, 1999Assignee: Rhone-Poulenc ChimieInventors: Yvonick Chevallier, Adrien Dromard
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Patent number: 5925603Abstract: Concentrated mixtures of three or more surfactants dissolved or dispersed in a stable form in water and which contain an acyl isethionate, an imidazoline surfactant, and at least one additional anionic surfactant are provided.Type: GrantFiled: December 15, 1997Date of Patent: July 20, 1999Assignee: Rhodia Inc.Inventor: Paul F. D'Angelo
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Patent number: 5922831Abstract: A polyamide resin comprising the reaction product obtained by the reaction of an acid component comprised of a major concentration of a dimer acid and minor concentration of a monobasic acid and an amine component comprised of a major concentration of a short-chain alkylenediamine, a first minor concentration of a medium-chain alkylenediamine and second minor concentration of a polyoxyalkylene diamine having a molecular weight greater than about 500 is provided. The polyamide resin is used to form a blend of containing the polyamide in a major amount by weight and a first minor amount by weight of a polar wax and a second minor amount by weight of a polyolefin elastomer. The composition is used to reinforce a footwear upper, e.g. as a print on box toe material.Type: GrantFiled: June 23, 1998Date of Patent: July 13, 1999Inventors: Dwight D. Heinrich, Reimar Heucher, Sandra Drahos
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Patent number: 5922671Abstract: Mild and environmentally benign bis-alkylphenol alkoxylated gemini surfactants of the formula: ##STR1## wherein R independently represents alkali, R.sub.1 independently represents hydrogen EO represents ethyleneoxy radicals alkyl, R.sub.2 independently represents hydrogen, --SO.sub.3 M, --P(O) (OM).sub.2, --CH.sub.2 COOM, --CH.sub.2 CHOHCH.sub.2 --SO.sub.3 HM, wherein M represents hydrogen, alkyl or alkaline earth metal, ammonium or an organic base salt; R.sub.3 represents alkylene of from one to about 10 carbon atoms or --C(O)--R.sub.4 --C(O)-- wherein R.sub.4 represents alkylene or aryl, and --O--R.sub.5 --O-- wherein R.sub.5 represents aliphatic or aromatic moieties with the proviso that when R.sub.3 is alkylene, then R.sub.2 is not hydrogen, and a and b are numbers ranging from one to about 100, with the proviso that when R.sub.2 is hydrogen, b is not zero.Type: GrantFiled: December 16, 1997Date of Patent: July 13, 1999Assignee: Rhodia Inc.Inventors: David James Tracy, Ruoxin Li, Jean-Marc Ricca
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Patent number: 5919980Abstract: Improved surfactant recovery for recycle and reuse upon ultrafiltration of a surfactant-containing aqueous solution can be obtained using a betaine or amide oxide amphoteric surfactant in the aqueous cleaner/contaminant solution. The surfactant passes through the ultrafiltration membrane with the water in the permeate in very high amounts while the contaminants and other undesirable components are held back in the retentate.Type: GrantFiled: March 10, 1997Date of Patent: July 6, 1999Assignee: Rhodia Inc.Inventors: Manilal S. Dahanayake, Yun Brian Yang, Mark E. Ventura
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Patent number: 5916935Abstract: A process of preparing a concentrate which is useful as a thickener for aqueous compositions is provided. The process comprises obtaining a solution of an associative thickener compound in an organic solvent capable of forming a low boiling azeotrope with water. The solution is essentially free of water at this point and is at a temperature above the boiling point of said low boiling azeotrope. Water is added to said solution and an azeotrope of water and said organic solvent is distilled. The rate of addition of water is sufficient to replace said azeotrope with water, but is insufficient to cause a second phase to form in the resulting mixture of said solution and said water. The process yields a concentrate of an associative thickener in water, which concentrate is essentially free of volatile organic solvents.Type: GrantFiled: July 28, 1997Date of Patent: June 29, 1999Assignee: Henkel CorporationInventors: Michael Wiggins, Dipak Shah, Reuben H. Grinstein
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Patent number: 5914310Abstract: According to the invention, an improved class of amphoteric surfactant having improved surfactant properties characterized as mild and environmentally safe has been provided comprising compounds of the formula: ##STR1## The amphoteric surfactant of the subject invention have at least two hydrophobic moieties and at least two hydrophilic groups per molecule and are useful as emulsifiers, detergents, dispersants and solubilizing agents.Type: GrantFiled: July 30, 1997Date of Patent: June 22, 1999Assignee: Rhodia Inc.Inventors: Ji Li, Manilal Dahanayake, Robert Lee Reierson, David James Tracy
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Patent number: 5906972Abstract: Novel liquid detergent compositions are provided which contain a high purity amphoteric surfactant, one or more anionic surfactants and a nonionic foam boosting compound.Type: GrantFiled: June 11, 1996Date of Patent: May 25, 1999Assignee: Rhodia Inc.Inventors: Gladys Saliba Gabriel, Ronald B. Bell, Mark Einziger
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Patent number: 5880222Abstract: Latexes are thickened by compounds of the formula:R.sup.1 -(O-A).sub.a -B.sup.1 -R.sup.2 -(B.sup.2 -R.sup.3).sub.d -(B.sup.3 -(A'-O).sub.b-f -(A'-B.sup.4).sub.f -R.sup.4 -(B.sup.5 -R.sup.5).sub.e).sub.n -B.sup.6 -(A"O).sub.c -R.sup.6wherein:R.sup.1 and R.sup.6 are monovalent hydrophobic groups independently selected from the group consisting of an aliphatic group, a substituted aliphatic group, an aromatic group, and a substituted aromatic group;R.sup.2 and R.sup.4 are independently selected from the group consisting of aliphatic, substituted aliphatic, aromatic, or substituted aromatic radicals, each radical being divalent or trivalent;R.sup.3 and R.sup.5 are independently selected from hydrogen, lower alkyl and lower aralkyl;B.sup.1, B.sup.2, B.sup.3, B.sup.4, B.sup.5, and B.sup.6 are linking groups independently selected from the group consisting of an oxygen atom (to form the ether linkage --O--), a carboxylate group (to form an ester linkage R.sup.2 --C(O)--O-- and/or R.sup.Type: GrantFiled: September 19, 1997Date of Patent: March 9, 1999Assignee: Henkel CorporationInventors: Michael S. Wiggins, Reuben H. Grinstein
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Patent number: 5877141Abstract: Glycolic acid or its salts is effective in stabilizing enzymes in liquid laundry detergent compositions.Type: GrantFiled: February 3, 1997Date of Patent: March 2, 1999Assignee: Rhodia Inc.Inventors: Gladys Saliba Gabriel, Ronald B. Bell