Patents Represented by Attorney David L Hedden
  • Patent number: 6579908
    Abstract: This invention relates to foam control agents for paints and coatings comprising a (a) a siloxane polyalkyleneoxide copolymer, (b) N,N′-ethylene bisstearamide, and (c) a carrier.
    Type: Grant
    Filed: March 18, 2002
    Date of Patent: June 17, 2003
    Assignee: Ashland Inc.
    Inventors: Thomas J. Penny, Andrew A. Romano
  • Patent number: 6559203
    Abstract: This invention relates to an organic foundry binder containing an alkyl resorcinol, or preferably a readily available mixture of alkyl resorcinols, and derivatives thereof. Preferably, the organic foundry binder is a furan binder. Foundry mixes are prepared by mixing the binder with a foundry aggregate. Foundry shapes (molds and cores) are prepared by shaping the mix and allowing it to cure to form a workable foundry shape. The invention also relates to the preparation of metal castings using the foundry shapes and the metal castings prepared with the foundry shapes.
    Type: Grant
    Filed: February 13, 2002
    Date of Patent: May 6, 2003
    Assignee: Ashland Inc.
    Inventors: David A. Hutchings, Heimo J. Langer, Ken K. Chang, Thomas E. Dando
  • Patent number: 6557348
    Abstract: This invention relates to an on-line process for removing copper deposits from the blades of the rotor of a steam turbine in systems, particularly condensing steam turbines. The process comprises adding an oxime to an appropriate injection point of an electric generating power plant powered by a steam turbine, where the power plant comprises a pre-boiler system, a steam generator, a steam turbine, a condenser and an electric generator.
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: May 6, 2003
    Assignee: Ashland Inc.
    Inventors: Emery N. Lange, Jr., Thomas H. Pike
  • Patent number: 6554051
    Abstract: A method of preparing foundry shapes, e.g. molds and cores, by mixing a foundry aggregate with a foundry binder, shaping the mixture in a pattern, curing the mixture, and removing the mixture from the pattern. The foundry binder is a phenolic urethane binder that utilizes a phenolic resin prepared by reacting a phenol, an aldehyde, bisphenol-A-tar, and a divalent metal catalyst.
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: April 29, 2003
    Inventors: Andreas Werner, Diether Koch
  • Patent number: 6551452
    Abstract: The invention relates to a process for digesting woodchips used in papermaking. The process employs a digester additive, which is a mixture of (a) a polyglycoside, and (b) a polyoxyalkylene glycol. The digester additives are compatible and stable at elevated temperatures in the highly alkaline white liquor used in the digestion of woodchips into pulp. The invention also relates to the digester additive compositions.
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: April 22, 2003
    Assignee: Ashland Inc.
    Inventors: George K. Wai, Abdul Q. Khan
  • Patent number: 6514350
    Abstract: This invention relates to a process for removing rust from metal surfaces. The process uses an aqueous solution of a benzoate.
    Type: Grant
    Filed: September 14, 2001
    Date of Patent: February 4, 2003
    Assignee: Ashland Inc.
    Inventors: Bruce L. Libutti, Joseph Mihelic
  • Patent number: 6510368
    Abstract: A process for monitoring and controlling an aqueous system. At least one performance parameter relating to conditions within the aqueous system is selected. A value of the at least one performance parameter is measured to serve as a baseline value. A capacity of the aqueous system is determined and flow rates of water into and out of the system are measured and monitored. The value of the at least one performance parameter is measured and compared the value to the baseline for the performance parameter. Flow rates of water into and out of the system are factored in. At least one controllable variable within the aqueous system is altered based upon a deviation of the value of the at least one performance parameter from the baseline value.
    Type: Grant
    Filed: April 13, 2000
    Date of Patent: January 21, 2003
    Assignee: Ashland Inc.
    Inventors: Edward S. Beardwood, George Freedman Hays, James George Knudsen
  • Patent number: 6503400
    Abstract: This invention relates to phosphate stabilizing compositions comprising (a) polyaspartic acid, and (b) an anionic carboxylic polymer. The compositions effectively stabilize phosphates by inhibiting the formation of calcium phosphate scale. The invention also relates to a process for inhibiting calcium phosphate scale in water treatment systems.
    Type: Grant
    Filed: December 15, 2000
    Date of Patent: January 7, 2003
    Assignee: Ashland Inc.
    Inventors: Pavol Kmec, Dwight E. Emerich
  • Patent number: 6503448
    Abstract: The invention relates to a process for retarding the formation of corrosion and/or removing existing corrosion deposits on a metal surface where the metal is in contact with air. The process comprises contacting said metal surface with an oxime in an amount effective to retard the formation of corrosion on the metal surface.
    Type: Grant
    Filed: May 27, 1999
    Date of Patent: January 7, 2003
    Assignee: Ashland Inc.
    Inventors: Charles D. Kuhfeldt, James M. Bryson
  • Patent number: 6479567
    Abstract: This invention relates to furan no-bake foundry binders comprising (a) furfuryl alcohol and/or a reactive furan resin, (b) an activator selected from the group consisting of resorcinol, resorcinol pitch, and bisphenol A tar (c) a bisphenol compound (d) a polyol selected from the group consisting of polyester polyols, polyether polyols, and mixtures thereof, and preferably (e) a silane. The binders are cured in the presence of the furan curing catalyst. The invention also relates to foundry mixes prepared with the binder, foundry shapes prepared with the foundry mix, and metal castings prepared with the foundry shapes.
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: November 12, 2002
    Assignee: Ashland Inc.
    Inventor: Ken K. Chang
  • Patent number: 6464900
    Abstract: This invention relates to corrosion inhibiting compositions for aqueous systems comprising (a) polyaspartic acid or salts therefore, and (b) a water soluble phosphonated oligomer. The compositions are effective corrosion inhibitors, but are also advantageous from an environmental standpoint because they are non-toxic, contain no heavy metals, and have little or no phosphorus. They also have significant calcium/hardness tolerance, are chlorine/bromine stable, and are effective corrosion inhibitors.
    Type: Grant
    Filed: August 1, 2000
    Date of Patent: October 15, 2002
    Assignee: Ashland Inc.
    Inventors: Pavol Kmec, Dwight E. Emerich
  • Patent number: 6458320
    Abstract: This invention relates to a galvanized metal, typically steel, corrosion inhibitor concentrate comprising (a) an amine salt of a fatty acid or an amine salt of a derivative of a fatty acid, (b) preferably a salt of a non polymeric aromatic acid, and (c) preferably a nonionic or anionic surfactant, and water. The invention also relates to a process for inhibiting corrosion and/or stripping of galvanized steel subjected to acidic conditions, e.g. an amine citrate or citric acid cleaning solution.
    Type: Grant
    Filed: April 5, 1999
    Date of Patent: October 1, 2002
    Assignee: Ashland Inc.
    Inventors: Bruce L. Libutti, Joseph Mihelic
  • Patent number: 6441060
    Abstract: The subject invention relates to a foundry binder system which cures in the presence of a volatile amine curing catalyst comprising (a) an epoxy resin, (b) an acrylated organic polyisocyanate, (c) a reactive unsaturated acrylic monomer, acrylic polymer, or mixtures thereof, and (d) an oxidizing agent comprising a hydroperoxide. The foundry binders are used for making foundry mixes. The foundry mixes are used to make foundry shapes which are used to make metal castings.
    Type: Grant
    Filed: September 14, 2000
    Date of Patent: August 27, 2002
    Assignee: Ashland Inc.
    Inventors: Don Greg Hendershot, Edward Gerard Toplikar, Laurence G. Dammann, Vincent J. Pascarella
  • Patent number: 6429236
    Abstract: The subject invention relates to a foundry binder system that cures in the presence of a volatile amine curing catalyst. The binder system comprises a Part I component comprising (1) a phenolic resin component, and (2) a free radical initiator, and a Part II component comprising (1) a polyisocyanate, and (2) a multifunctional acrylate. The foundry binders are used for making foundry mixes. The foundry mixes are used to make foundry shapes that are used to make metal castings.
    Type: Grant
    Filed: May 23, 2000
    Date of Patent: August 6, 2002
    Assignee: Ashland Inc.
    Inventors: Gary M. Carlson, Robert B. Fechter, Edward G. Toplikar, D. Greg Hendershot
  • Patent number: 6426379
    Abstract: This invention relates to a defoamer composition comprising (a) hydrophobic silica; (b) a linear polysiloxane having end-blocked polyoxypropylene groups; (c) a polysiloxane having a pendant polyoxypropylene group; (d) a nonionic surfactant; and preferably (e) an inert diluent. The defoamer compositions are used in paints and coatings.
    Type: Grant
    Filed: June 22, 2000
    Date of Patent: July 30, 2002
    Assignee: Ashland Inc.
    Inventors: Rosanna P. Rudy, Andrew A. Romano
  • Patent number: 6426374
    Abstract: This invention relates to foundry binder compositions that contain a divalent sulfur compound, and/or foundry mixes where the aggregate contains a divalent sulfur compound. The foundry binders and foundry mixes are used to make foundry shapes, e.g. molds and cores. The presence of sulfur in the foundry shape facilitates the removal of foundry shapes (particularly internal cores) from the metal casting which is made by pouring molten metal into a casting assembly in which the foundry shapes are arranged. The invention also relates to a method of preparing foundry shapes, the shapes prepared, a method of making a metal casting, and metal castings by this process.
    Type: Grant
    Filed: July 28, 2000
    Date of Patent: July 30, 2002
    Assignee: Ashland Inc.
    Inventor: Michael J. Skoglund
  • Patent number: 6403028
    Abstract: This invention relates to an all-organic corrosion inhibiting composition comprising (a) 6,6,6-(1,3,5-triazine-2,4,6-triyltriimino) tris hexanoic acid; and (b) a water-soluble phosphonated oligomer salt. The invention also relates to a process for inhibiting corrosion in a closed recirculating cooling water system.
    Type: Grant
    Filed: October 18, 1999
    Date of Patent: June 11, 2002
    Assignee: Ashland Inc.
    Inventors: Steven J. Colby, Dwight E. Emerich, Edward S. Beardwood
  • Patent number: 6391942
    Abstract: This invention relates to furan no-bake foundry binders comprising (a) a reactive furan resin, (b) furfuryl alcohol, and (c) a catalyst component comprising a catalytically effective amount of a Lewis acid furan catalyst. The invention also relates to foundry mixes prepared with the binder, foundry shapes prepared with the foundry mix, and metal castings prepared with the foundry shapes.
    Type: Grant
    Filed: April 27, 2000
    Date of Patent: May 21, 2002
    Assignee: Ashland Inc.
    Inventors: Ken K. Chang, David A. Hutchings
  • Patent number: 6387983
    Abstract: This invention relates to foundry mixes and their use in preparing foundry shapes (molds and cores) and in casting metals. The foundry mixes comprise a foundry aggregate and an organic foundry binder that contains an organic polyisocyanate and an aliphatic mercaptan. The binder systems react to form thiocarbamate polymers when mixed with sand. Preferably, a tertiary amine curing catalyst is used to promote the reaction of the organic polyisocyanate and aliphatic mercaptan.
    Type: Grant
    Filed: May 23, 2000
    Date of Patent: May 14, 2002
    Assignee: Ashland Inc.
    Inventor: Michael J. Skoglund
  • Patent number: 6360808
    Abstract: The invention relates to exothermic sleeve compositions comprising (a) an oxidizable metal where the oxidizable metal comprises aluminum dross, and (b) an oxidizing agent capable of generating an exothermic reaction. The invention also relates to sleeve mixes prepared with the sleeve compositions, the use of the sleeve composition to prepare sleeves, the sleeves prepared with the sleeve compositions and the use of the sleeves to prepare metal castings.
    Type: Grant
    Filed: June 19, 2000
    Date of Patent: March 26, 2002
    Assignee: Ashland Inc.
    Inventors: Helena Twardowska, Ronald C. Aufderheide