Abstract: A thermal barrier coating (TBC 26) and method for forming the TBC (26) on a component (10) characterized by a stabilized microstructure that resists grain growth, sintering and pore coarsening or coalescence during high temperature excursions. The TBC (26) contains elemental carbon and/or a carbon-containing gas that increase the amount of porosity (32) initially within the TBC (26) and form additional fine closed porosity (32) within the TBC (26) during subsequent exposures to high temperatures. A first method involves incorporating elemental carbon precipitates by evaporation into the TBC microstructure. A second method is to directly incorporate an insoluble gas, such as a carbon-containing gas, into an as-deposited TBC (26) and then partially sinter the TBC (26) to entrap the gas and produce fine stable porosity within the TBC (26).

Abstract: A coating system and method for reducing the tendency for hydrocarbon fluids, such as fuels and oils, to form carbonaceous deposits that adhere to the walls of a containment article. Of particular concern are carbonaceous deposits that form at temperatures below about 650° F. (about 345° C.). The coating system combines an outermost layer of platinum with a ceramic barrier layer. The coating system has been shown to significantly reduce the formation of carbonaceous deposits at temperatures between about 220° F. and 650° F. (about 105° C. to about 345° C.), as well as reduce the adhesion of such deposits. The platinum outermost layer also serves as a radiation shield to reduce heat transfer from the containment article to the hydrocarbon fluid. The outermost layer is preferably deposited as an extremely thin film by chemical vapor deposition. The barrier layer is deposited to a thickness sufficient to prevent interdiffusion of the platinum outermost layer with the containment wall.

Abstract: A thin film that forms an interface between metal surfaces and polymeric inserts of aircraft engine fan blades. The thin film is formed from a chemical comprised of carbon black, at least one evaporable solvent, a combination of phenolic-like resins dissolved in the solvent and the balance filler and inert ingredients. The thin film, upon drying of the evaporable solvent, forms a phenolic that bonds with the metallic portion of the fan blade. After the polymeric material is applied to recesses in the fan blade and cured, a chemical bond is formed between the thin film and the elastomeric inserts. The bonded structure has improved FWT peak stresses and improved fracture toughness.

Abstract: A method for producing apertures in hot section components of gas turbine engines made from ceramic matrix composites that have at least one oxidizable component. The method involves forming the apertures using a laser beam controlled by parameters that ablate the ceramic matrix composite in the path of the beam, while simultaneously heating the matrix material, SiC or SiN, to a sufficient temperature to oxidize it to form a silica. Sufficient heat is supplied by the beam to melt the silica to cause it to flow. The melted silica is quickly solidified as recast silica along the walls of the newly created aperture before it has an opportunity to flow and form undesirable geometries. The wall of the aperture is formed of recast silica that is a smooth surface and that forms an oxidation barrier to inhibit any further oxidation of the underlying composite as it is exposed to the high temperatures and oxidative, corrosive atmosphere of an operating gas turbine.

Abstract: A coating for use on a superalloy substrate comprising a diffusion barrier as an intermediate layer overlying the substrate and underlying a protective coating having a high aluminum content. The diffusion barrier layer is characterized by having low solubility for aluminum from either the substrate or the protective coating. Further, the diffusion barrier layer has low interdiffusivity for elements from the substrate and the coating, a minimal impact on the mechanical properties of the article which is coated, a minimal thermal expansion mismatch with both the substrate and the high aluminum content protective coating, and can be applied readily using existing coating application techniques. The diffusion barrier is preferably a single phase alloy or intermetallic compound.

Abstract: A gas turbine component has a platform, a shank extending downwardly from the platform, and an airfoil extending upwardly from the platform. The gas turbine component is coated by first applying a first chromide layer overlying the base metal of at least a portion of the shank and interdiffused therewith, and second applying a second coating on at least a portion of the airfoil. The second coating optionally includes a second chromide layer contacting the base metal of the airfoil and interdiffused therewith, and includes an aluminide protective layer overlying the second chromide layer. The first chromide layer on the shank and the second chromide layer on the airfoil may be within the same chromium composition range (for example, from about 20 to about 30 weight percent chromium) and thickness range (for example, from about 0.001 to about 0.002 inch), and deposited at the same time.

Abstract: A method is provided for physical vapor deposition of ceramic thermal barrier coatings and articles made therefrom Impurity levels in conventional yttria stabilized zirconia source materials have caused undesired spitting (eruptions) due to a combined effect of various impurities thereby requiring relatively low evaporation rates to control the level of spitting during the process. The present method provides a high purity source material having a purity index sufficiently low to result in reduced spitting in the vapor deposition process and to permit in evaporation rates. Reducing the density of the source material has also been found to reduce spitting. The method permits higher processing rates and/or reduced levels of spitting.

Abstract: A method is provided for physical vapor deposition of ceramic thermal barrier coatings and articles made therefrom. Impurity levels in conventional yttria stabilized zirconia source materials have caused undesired spitting (eruptions) due to a combined effect of various impurities thereby requiring relatively low evaporation rates to control the level of spitting during the process. The present method provides a high purity source material having a purity index sufficiently low to result in reduced spitting in the vapor deposition process and to permit increased evaporation rates. Reducing the density of the source material has also been found to reduce spitting. The method permits higher processing rates and/or reduced levels of spitting.

Abstract: A process for preparing a material includes preparing a preform having carbon particles and a carrier material. A first end of a wick, made of a material that is wetted by liquid silicon, is contacted to the preform. The wick and the preform are heated to a temperature greater than the melting point of silicon, so that silicon flows along the wick to the preform. The silicon reacts with the carbon particles to form silicon carbide. At least a portion of the reaction of carbon and silicon is performed in an atmosphere containing a source of nitrogen and substantially free of oxygen, so that free silicon reacts to form silicon nitride.