Abstract: Air is introduced through an inlet into a higher pressure rectification column. A stream of oxygen-enriched liquid is withdrawn through an outlet from the higher pressure rectification column. A part of this stream is introduced into a low pressure rectification column through an inlet. The stream is separated in the column low pressure rectification into oxygen and nitrogen. In addition, an argon-enriched vapor stream is withdrawn from the low pressure rectification column through an outlet, and is at least partially condensed in a reboiler-condenser which reboils oxygen separated in an argon column. One part of the resulting at least partially condensed argon-enriched oxygen stream is reduced in pressure by passage through a valve and is introduced through an inlet into an intermediate mass exchange region of the argon column in which it is separated into argon and oxygen.

Abstract: A cryogenic refrigeration method for use in connection with a cryogenic temperature swing adsorption process. The cryogenic temperature swing adsorption process has a discontinuous production cycle during which production of a purified vapor stream ceases or is reduced through use of purified vapor to purge a regenerating adsorption bed. Additionally, the purified vapor stream in part of the production cycle is superheated through use of the purified vapor stream to cool the regenerating adsorption bed. A heat exchange stream is liquefied against the vaporization of at least part of an impure liquid stream to produce an impure vapor stream to be purified by the adsorption process. Process liquid is continually produced from the liquefaction of the process stream. The process liquid is used to in turn liquefy the purified vapor stream at varying flow rates that are sufficient to liquefy the purified vapor stream throughout the production cycle.

Abstract: An adsorption process in which high and low pressure feed streams are introduced into a plurality of beds to produce product streams by adsorbing one or more preferentially adsorbed components within the beds. Each bed is subjected to a low pressure feed stage to produce a low pressure product stream followed by a high or higher pressure feeding stages to produce one or more high pressure product streams. Thereafter the beds are regenerated through depressurization and purge stages. The cycle is conducted out of phase so that one of the beds is producing the high pressure product stream while another bed is producing a low pressure product stream.

Abstract: An apparatus for storing a multi-component cryogenic liquid in which headspace vapor in a storage tank is condensed in an external condensation tank through indirect heat exchange with liquid being vented from the storage tank. The resulting condensate can then be re-introduced into the storage tank through a pressure building circuit applied to the external condensation tank. In such manner, the pressure within the storage tank is regulated and the composition of the liquid stored within the storage tank is held with some degree of consistency. The use of an external condensation tank allows prior art cryogenic storage tanks and dewars to be retrofitted to store a multi-component cryogenic liquids.

Abstract: An air separation method in which a pre-purification unit is provided with three or more beds which are subjected to a pressure swing adsorption process. Each of the beds is subjected to feed, pressurization, purge and repressurization stages. The purge stages are conducted with a waste stream from the air separation unit and the duration of the purge stage is equal to the total time of the cycle divided by the number of beds.

Abstract: A burner block for mounting a burner within a furnace containing a melt to be heated by the burner. The burner block comprises a body having a passageway terminating in a divergent opening. The passageway is configured to receive the burner so that the burner is recessed within the divergent opening and a flame produced by the burner is directed out of the divergent opening and over the melt. The divergent opening has a lower section angled in a downward direction and the lower section has a reversed step to produce a primary recirculation zone beneath the flame, thereby to draw the flame in a downward direction toward the melt. The reversed step is positioned within the divergent opening so that when the burner is in use, a secondary recirculation zone forms between the opening and the melt and further draws the flame in the downward direction toward the melt.

Abstract: A stream of air is compressed in compressor and has water vapor and carbon dioxide removed therefrom in purification unit. A part of the resulting purified air is cooled by passage through heat exchanger and is employed to heat an intermediate reboiler in a lower pressure rectification column. The air flow from the reboiler passes into a higher pressure rectification column which supplies a stream of oxygen-enriched liquid air for separation in the lower pressure rectification column. Liquid nitrogen reflux for the higher pressure column is provided by taking nitrogen vapor from this column through an outlet and condensing it in another intermediate reboiler located above the reboiler in the lower pressure rectification column. The condensed nitrogen is returned to the top of the column.

Abstract: An apparatus and method for dispersing a gas in a liquid and for increasing gas pressure of a gas from a supply pressure to a delivery pressure. A first pump pumps the liquid to produce a pressurized liquid stream. The gas is injected into the pressurized liquid stream through for instance, a piping tee. The gas injection produces a pressure drop within the gas and as a result, the first pump pumps the liquid stream so that it has a static pressure no greater than the injection pressure. A second pump pumps the resultant pressurized gas-liquid stream so that an outlet liquid stream is produced with the liquid having a greater head than that of the pressurized liquid stream and the gas having the increased delivery pressure.

Abstract: Air is compressed in a compressor, purified in a purification unit, cooled by passage through a main heat exchanger and separated in a double rectification column comprising a higher pressure rectification column and a lower pressure rectification column. A stream of argon-enriched oxygen vapour is withdrawn from the lower pressure rectification column through an outlet and an argon product is separated from it in an argon rectification column provided with an argon condenser. Argon is condensed in the condenser by indirect heat exchange with a second stream of air at a pressure between the operating pressures of the columns. The second air stream is partially condensed and passed into a phase separator. A stream of liquid phase is withdrawn from the phase separator, is passed through a throttling valve and the condenser, in sequence. Further cooling for the condenser is thus provided.

Abstract: A method for the treatment of a stream of exhaust gases including phosphine in which the stream is heated to a sufficiently high temperature to decompose the phosphine to phosphorus vapor and the stream is then passed into a reactor containing calcium oxide heated to above about 100.degree. C. An oxygen containing stream is also passed into the reactor.

Abstract: Air is compressed in compressors, cooled in a main heat exchanger, and separated into oxygen and nitrogen products in a double rectification column comprising a higher pressure rectification column and a lower pressure rectification column. A liquid oxygen product is withdrawn from the lower pressure column via a conduit. A liquid nitrogen product is also formed. An argon-enriched oxygen vapour stream is withdrawn from the lower pressure column through an outlet and has argon separated from it in an argon column. In order to help meet the requirements of the higher pressure column for reflux, a nitrogen vapour stream is withdrawn from the top of the lower pressure column, is warmed by passage through the heat exchanger, is recompressed in a compressor, and is liquefied by passage back through the heat exchanger from its warm end to its cold end and passage through a valve. A high liquid make and a high argon recovery can both be achieved.

Abstract: A process and system for removing condensable vapors contained within the gas stream in accordance with the process and system, condensable vapors contained within the gas stream are condensed within one or more condensers through indirect heat exchange of the gas stream with a refrigerant stream. This produces a refrigerated gas stream and a heated refrigerant gas stream. Further heat is exchanged from at least part of the heated refrigerant stream to the refrigerated gas stream and in economizing heat exchanger to form a cooled refrigerant stream from the heated refrigerant stream. The refrigeration stream is produced by combining a cryogenic stream with the at least part of the cooled refrigerant stream in a mixing chamber of an ejector or analogous equipment.

Abstract: A method and apparatus for producing a ultra-high purity oxygen product in which a nitrogen generator is operated to produce nitrogen and an oxygen rich fraction as column bottoms. Part of the oxygen rich fraction can be further processed at column pressure within rectification column to produce a tower overhead lean in hydrocarbons such as methane, acetylene, propane and propylene. After liquefaction in a head condenser of the rectification column, part of the condensate is further processed in a stripping column to produce an ultra-high purity liquid oxygen column bottoms which can be extracted as product.

Abstract: A liquid-vapor contact device having a plate-like body provided with a central section formed of expanded metal construction. The expanded metal construction provides slit-like openings for the vapor to ascend through the plate-like body and mix with liquid traversing the plate-like body. Tongue-like flow deflectors associated with the openings impart momentum to the vapor in a flow direction taken from inlet and outlet segments of the plate-like body. A plurality of elongated members overlie the central segment of the plate-like body. The plurality of the elongated members define channels running from the inlet and outlet segments which are preferably outwardly curved to ensure complete liquid distribution across the plate-like body. In addition, flow impedance members in the form of cut and bent tabs impede the flow of liquid across the plate-like body while flinging liquid against side surfaces of the elongated members to produce a falling film and therefore a secondary mechanism for liquid-vapor contact.

Abstract: The present invention provides a shelf for a freeze dryer which includes a pair of first and second flat plates spaced apart from one another, and a plurality of ribs located between the first and second plates and spaced from one another so as to define flow channels for circulating a diathermic fluid. The ribs are preferably formed of hollow tubes that are brazed to the first and second plates and the hollow tubes and plates are stress relieved so that the first plate presents a flat surface at which heat is transferred from articles to be freeze dried and the diathermic fluid. A freeze dryer shelf constructed in such manner has less thermal mass than prior art design which have solid ribs and plates welded to the ribs with a thickness sufficient to prevent the formation of surface deformations that would interrupt the flat surface of the first plate.

Abstract: In a rotatable magnetron, a seal cartridge having vacuum seals integrated therein provides a seal between a seal housing of the magnetron support assembly and a spindle carried therein. The seal cartridge is axially movable with respect to the magnetron support assembly which enables its efficient removal and replacement therefrom. As such removal and replacement of the cartridge automatically accomplishes the removal and replacement of the integral vacuum seals, no handling or reassembly of the vacuum seals is required. The seal cartridge of the present invention provides a protected seal design which improves seal integrity in rotatable magnetrons.

Abstract: An oxy-fuel burner system for alternately or simultaneously burning gaseous and liquid fuels. A gaseous fuel jet emanating from an oxy-fuel burner is either undershot by an oxygen lance or is sandwiched between oxidant jets produced by two subsidiary oxidant jets which are preferably formed of oxygen. An actuable second fuel nozzle is provided for producing a second fuel jet composed of the liquid fuel which is angled toward the oxidant jet at an angle of less than 20.degree.. When the liquid fuel to be used, the gaseous fuel is turned off and the liquid fuel is turned on and vice-versa or both can operate simultaneously where the oxidant supplies oxygen to both fuel streams.

Abstract: An air separation method and apparatus in which a stream of air is compressed in a compressor and purified in a unit. One stream of the resulting air is cooled in a heat exchanger and is separated in an arrangement of rectification columns comprising a higher pressure rectification column, a lower pressure rectification column, and a further rectification column for separating argon from an argon-enriched oxygen stream withdrawn from the lower pressure rectification column and the stream of resulting air is introduced into the higher pressure rectification column through an inlet. A second cooled, compressed, purified air stream is expanded in an expansion turbine and is introduced into the lower pressure rectification column. A third cooled, compressed, purified air stream is expanded in a second expansion turbine and is introduced into the higher pressure rectification column.

Abstract: An air separation method and apparatus for producing nitrogen is provided in which oxygen enriched liquid, produced as a column bottoms of a distillation column, is partially vaporized and phase separated. The vapor phase is expanded to provide refrigeration while the liquid phase, after pressure reduction, is introduced into the head condenser to condense reflux to the column. Alternatively, part of the oxygen enriched liquid can be fully vaporized and then expanded to provide refrigeration. In such case, another part of the oxygen enriched liquid can be used to condense reflux to the column. Part of the air to be separated is liquefied against the oxygen enriched liquid to be vaporized and then introduced into a lower portion of the column to maintain production and purity levels that would have been obtained had all the oxygen enriched liquid stream been used in condensing reflux to the column.

Abstract: A method of rectifying a multicomponent mixture by pressure swing adsorption to separate primary and secondary components of the mixture. Two groups of adsorbent beds are used in the method and adsorbent beds of the two groups are employed in a paired relationship and subjected to feed, co-current depressurization, evacuation, and countercurrent repressurization stages. In the feed stages, pairs of the adsorbent beds are pressurized with the mixture to adsorb the primary component in a first group of the adsorbent beds and in an entry section of a second group of the adsorbent beds. Also during the feed stage, the secondary component is adsorbed in the second group of adsorbent beds in remaining sections thereof. During co-current depressurization, any of the secondary component adsorbed in the first group of adsorbent beds and part of the primary component is driven to the second group of adsorbent beds.