Abstract: A cryogenic air separation system wherein nitrogen vapor from a higher pressure column and oxygen liquid from a lower pressure column each pass down through a once-through main condenser in heat exchange relation and some but not all of the oxygen liquid is vaporized such that the oxygen liquid and vapor exit the condenser in a liquid to vapor mass flowrate ratio within the range of from 0.05 to 0.5 whereby the need for a recirculation pump to ensure avoidance of oxygen boiling to dryness is eliminated.

Abstract: A superconducting cable cooling system, wherein coolant continually provides cooling to superconducting cable, comprising a plurality of nodes within a superconducting cable network and a plurality of legs of superconducting cable which interconnect each of the nodes of the superconducting cable network.

Abstract: Method of preparing and introducing fuel into the combustors of a gas turbine in which a hydrocarbon containing feed, oxygen and steam are introduced into a catalytic partial oxidation reactor to produce a product stream. The hydrocarbon containing feed contains no less than about 15 percent by volume on a dry basis of hydrocarbons with at least two carbon atoms and/or at least about 3 percent by volume of olefins. The reactant mixture formed of the hydrocarbon containing feed, oxygen and steam has an oxygen to carbon ratio of between about 0.08 and about 0.25 and a water to carbon ratio of between about 0.05 to about 0.5. The hydrocarbon containing feed is introduced into the reactor alone or with a steam at a temperature no greater than 600° C. and the product stream is produced at a temperature of between about 600° C. and 860° C. and contains less than about 0.5 percent of olefins and less than 10 percent of hydrocarbons with two or more carbon atoms on a dry basis.

Abstract: A method of forming one or more ceramic layers on the substrate in which one layer containing ceramic particles is laminated onto the surface of the substrate that is completely formed. The layer that is applied to the substrate contains voids between the ceramic particles. The particles are sintered into a coherent mass, thereby to form the ceramic layer or layers by heating the layer while simultaneously applying pressure to the layer in a direction normal to the surface of the substrate until the sintering is complete. The layer is heated to a temperature that is below the pressureless sintering temperature of the particles and the temperature is sufficient to allow the movement of the particles upon application of the pressure to force the particles into physical contact with one another and such that the voids are substantially removed.

Abstract: A method of heating a fluid utilizing a process heater having one or more first combustion zones and one or more second combustion zones. The combustion of a fuel is divided between the first and second combustion zones. The oxygen is provided for combustion within the first combustion zone by one or more oxygen transport membranes that contribute between about 50 and 99 percent of the stoichiometric amount of oxygen required for complete combustion of the fuel passing through the process heater. A supplemental or secondary oxidant is introduced into second combustion zone to complete combustion of the fuel and thereby produce a flue gas stream containing between about 1 and 3 percent oxygen to ensure complete combustion of the fuel. In this manner, the surface area of the oxygen transport membranes may be reduced below the surface area that otherwise would be required if 100 percent of the oxygen were contributed by the oxygen transport membranes.

Abstract: A method of producing a green form for use in manufacturing a composite, ceramic ion transport membrane is provided in which first and second ceramic powder mixtures are used to produce first and second layers of the green form. The first and second ceramic powder mixtures have ceramic particles and a pore former. After formation of each of the first and second layers or after formation of the second layer, heat is applied to burn out the binder and form pores. This heating is completed prior to application of a dense layer to prevent production of defects within the dense layer. The dense layer contains an ion transport material. Defects are also prevented by grading particle size from the first layer to the dense layer. This allows the second intermediate layer to fill in larger pores of the first layer and to present a smooth surface to the dense layer. Additionally, the second ceramic powder mixture contains in part material used in forming the dense layer for thermal expansion compatibility purposes.

Abstract: A hydrogen storage system and method having a main hydrogen storage site that contains a sufficient amount of hydrogen for a fuel cell employing a polymer membrane to generate power in accordance with a predetermined electrical power requirement. A main storage site is provided to store and supply hydrogen to meet the electrical power requirement for the fuel cell. An auxiliary hydrogen storage site contains a sufficient amount of hydrogen to allow the fuel cell to operate on a scheduled basis that is required to maintain the polymer membrane hydrated. A manifold connects the main and auxiliary hydrogen storage sites and has an outlet to deliver hydrogen to the fuel cell. The manifold allows the auxiliary hydrogen storage site to be renewed independently of the main storage site and has a flow control network to allow the fuel cell to draw hydrogen from the auxiliary hydrogen storage site for maintenance purposes without utilization of the hydrogen from the main hydrogen storage site.

Abstract: A method for improving the insulation characteristics of a cryogenic piping system wherein an insulation volume defined by a jacket coaxial to an inner pipe is evacuated to a moderate vacuum and then filled with a condensable gas in one or more evacuation and filling cycles, and then, after evacuation to a moderate vacuum, the condensable gas is condensed to effect a high vacuum within the insulation volume.

Abstract: A cryogenic rectification system employing a phase separator, which may include one or more trays, in conjunction with a double column air separation plant, wherein some shelf liquid is subcooled and phase separated to produce crude neon vapor, and the remaining liquid is used to reflux the lower pressure column of the double column plant.

Abstract: A cryogenic biological preservation unit having a removable lid and an integrated cryocooler positioned apart from, or within a fixed portion of, the lid and which provides refrigeration to the upper portion of the interior of the unit which also contains a pool of liquid cryogen and at least one biological sample preferably positioned above the pool of liquid cryogen.

Abstract: A method of controlling a distillation column having control valves to control both reflux and the vapor rate within the column. In accordance with the present invention, a temperature sensed in a top section of the column is magnified and utilized within the model predictive controller so that control is more aggressive as temperatures increase beyond a threshold temperature. Additionally, in the distillation column, or in fact in any other system in which two or more manipulated variables control two or more common controlled variables, special modeling techniques are utilized to make controller tuning easier to accomplish. In such modeling techniques, each manipulated variable is assumed to be able to have an effect on a controlled variable by a single step response model and other step response models are utilized so that the other manipulated variable(s) that also would have an effect on the same controlled variable are taken into account by the controller as feed forward variables.

Abstract: A cryogenic air separation plant and method of operation wherein, after an interruption in operation, liquid from the sump of a lower pressure column and liquid from the sump of a higher pressure column is passed to a condenser, preferably an argon column top condenser, prior to the restarting of the plant.

Abstract: Method of measuring the weight of bulk liquid material within a container of a tractor-trailer combination in which air bag pressure of a pneumatic suspension system is sensed and correlated with the weight of the bulk liquid material within the container. In accordance with the method, the tractor engine is turned off and supplemental pressurized air is introduced into a pneumatic circuit feeding compressed air to the air bags and while not applying the brakes of the trailer.

Abstract: A method of separating oxygen from an oxygen containing feed and reacting the oxygen with a reactive substance and an oxygen ion transport membrane element utilized for such purposes. The oxygen ion transport membrane element has a self-supporting dense layer and a surface porous feature in contact with and supported by the dense layer. The porous surface feature may be a layer, a layer having discontinuities or a series of repeating geometrical forms. The dense layer and the porous surface feature are capable of conducting oxygen ions and electrons. The porous surface feature at least in part forms the anode side of the oxygen ion transport membrane element at which the reactive substance reacts with the separated oxygen and has a thickness less than that of the dense layer and a greater surface area than that of a surface of the dense layer adjoining the porous layer. Pores within the porous surface feature have a pore aspect ratio of pore size to pore length of between about 0.1 and about 5.

Abstract: A superconducting magnet system wherein a cryocooler provides refrigeration to a cryogenic shield for the superconducting magnet and a heat pipe extends from the cryogenic shield to a cryogen vessel for the provision of supplementary refrigeration.

Abstract: An autothermal reactor and method for producing synthesis gas in which a heated oxygen containing stream is expanded into a mixing chamber to entrain a hydrocarbon containing stream to form a reactant stream without reaction of the oxygen and hydrocarbon contents of the streams. The reactant stream is reacted in a series of sequential catalytic reaction zones to react the hydrocarbon and oxygen contained in the reactant stream to form the synthesis gas. The sequential catalytic reaction zones are configured such that an initial partial oxidation reaction occurs that is followed by endothermic reforming reactions having ever decreasing temperatures. The sequential catalytic reaction zones in which the endothermic reforming reactions occur contain a precious metal catalyst supported on ceramic supports that have successively greater surface areas to compensate for the temperature decrease while remaining stable and without a transform in state.

Abstract: A method for operating a cryocooler which provides opportunity for timely intervention prior to failure thus enhancing the reliability of the provision of the refrigeration wherein temperature trending of at least one cryocooler component or the refrigeration load is monitored and used to calculate a service time.

Abstract: Method for controlling the production of one or more liquid products produced by one or more plants, that can be an air separation plant, that has a liquid storage capacity and that consumes electrical power. Linguistic values related to current liquid inventory, a rate of change of liquid inventory, projected demand requirements and projected unit power costs are inputted into a expert system controller having one or more rule sets that apply such input linguistic values to produce output linguistic values that are converted back to an output numerical value of a forecasted differential production rate to be applied during a forecast period. The output numerical value of differential production is added to the current production rate of the plants to obtain a new production rate which is applied during the forecast period.

Abstract: A cryocooler system having at least one flow straightener which has a system of grooves on its perforated surface for enhancing gas flow uniformity through the system wherein pulsing gas which does not initially pass through the flow straightener through a perforation flows along the surface of the flow straightener within a groove prior to passing through a perforation and is effectively redistributed across the surface of the flow straightener and thus the cross section of the regenerator or thermal buffer tube.

Abstract: A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo5Si3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.