Patents Represented by Attorney Delmar H. Larsen
  • Patent number: 4014174
    Abstract: An improved method of consolidating the surface of a borehole in an incompetent formation and simultaneously strengthening the bond between the surface of the borehole and cement placed in the borehole is achieved by forcing an aqueous solution of a multivalent cation salt into the formation, thereafter forcing an alkali metal silicate solution which has a pH less than 12.0 containing at least 12% by weight silica into the formation, and thereafter forcing an aqueous cement slurry containing at least 2% by weight of a water soluble multivalent cation salt to contact the surface of the borehole. A cementitious piling intimately bonded to the formation is prepared by filing the stabilized borehole with an aqueous cement slurry and allowing the cement to harden.
    Type: Grant
    Filed: October 28, 1975
    Date of Patent: March 29, 1977
    Assignee: N L Industries, Inc.
    Inventor: Thomas C. Mondshine
  • Patent number: 3994783
    Abstract: A process for the determination of creatine phosphokinase MB-isoenzyme (CPK-MB) level in serum in which CPK is determined before and after MB-activation with 1,4-dimercapto-2,3-dihydroxy butane or 2-mercaptoethanol, preferably in an assay system using the ATP/ADP conversion. The difference in the two values found is due to the CPK-MB present. The invention is of particular utility in the diagnosis and treatment of myocardial damage.
    Type: Grant
    Filed: September 26, 1975
    Date of Patent: November 30, 1976
    Assignee: Calbiochem
    Inventors: Parinam Srinivasa Rao, James J. Lukes, Hiltrud S. Mueller
  • Patent number: 3992467
    Abstract: Alkylatable aromatic hydrocarbons are alkylated with olefins and alkylhalides under anhydrous alkylating conditions in the presence of a metallic cation exchanged trioctahedral 2:1 layer-lattice smectite-type catalyst in which the metallic cation has a Pauling electronegativity greater than 1.0. In a specific embodiment, 1-dodecene is reacted with benzene by contacting the dodecene and benzene under anhydrous conditions in the liquid phase at the boiling point of the mixture with a catalyst comprising a metallic cation such as Al.sup.3.sup.+, In.sup.3.sup.+ and Cr.sup.3.sup.+ exchanged onto the surface of hectorite clay.
    Type: Grant
    Filed: March 29, 1976
    Date of Patent: November 16, 1976
    Assignee: NL Industries, Inc.
    Inventor: George E. Stridde
  • Patent number: 3979331
    Abstract: Alkylatable aromatic hydrocarbons are alkylated with olefins and alkylhalides under anhydrous alkylating conditions in the presence of certain metallic cation exchanged synthetic hectorite-type catalysts in which the metallic cation has a Pauling electronegativity greater than 1.0 and in which the central octahedral layer contains one or more divalent metals which have an ionic radius not greater than 0.75 A. In a specific embodiment, 1-dodecene is reacted with benzene by contacting the dodecene and benzene under anhydrous alkylating conditions in the liquid phase at the boiling point of the mixture with a catalyst comprising a metallic cation such as Al.sup.3.sup.-, In.sup.3.sup.- and Cr.sup.3.sup.- exchanged onto the surface of a synthetic nickeliferous hectorite.
    Type: Grant
    Filed: December 6, 1974
    Date of Patent: September 7, 1976
    Assignee: NL Industries, Inc.
    Inventor: George E. Stridde
  • Patent number: 3976744
    Abstract: Laminar 2 : 1 layer-lattice aluminosilicate minerals containing intra-lattice multivalent ions such as nickel, copper, cobalt and others. The minerals are particularly useful in catalytic operations. Procedures for preparing the inventive minerals are given.
    Type: Grant
    Filed: September 23, 1974
    Date of Patent: August 24, 1976
    Assignee: NL Industries, Inc.
    Inventor: William T. Granquist
  • Patent number: 3971734
    Abstract: The invention provides compositions and aqueous solutions containing a sulfite compound chosen from alkali metal and ammonium sulfites and bisulfites and at least one water soluble stabilizing compound which is an organic phosphonate containing at least two phosphonic acid groups per molecule. Also provided is a method of reducing the oxidation rate of aqueous sulfite solutions caused by oxygen in the atmosphere and a method of decreasing the corrosiveness to ferrous metals of aqueous systems containing dissolved oxygen and at least one divalent cation derived from iron, cobalt, copper, manganese, and nickel.
    Type: Grant
    Filed: March 3, 1975
    Date of Patent: July 27, 1976
    Assignee: NL Industries, Inc.
    Inventor: Harley E. Bush
  • Patent number: 3965043
    Abstract: Alkylatable aromatic hydrocarbons are alkylated with olefins and alkylhalides under anhydrous alkylating conditions in the presence of a metallic cation exchanged trioctahedral 2:1 layer-lattice smectite-type catalyst in which the metallic cation has a Pauling electronegativity greater than 1.0. In a specific embodiment, 1-dodecene is reacted with benzene by contacting the dodecene and benzene under anhydrous conditions in the liquid phase at the boiling point of the mixture with a catalyst comprising a metallic cation such as Al.sup.3.sup.+, In.sup.3.sup.+ and Cr.sup.3.sup.+ exchanged onto the surface of hectorite clay.
    Type: Grant
    Filed: September 6, 1974
    Date of Patent: June 22, 1976
    Assignee: NL Industries, Inc.
    Inventor: George E. Stridde
  • Patent number: 3963602
    Abstract: Catalysts of wide utility, e.g., for hydrocarbon conversion, are prepared by calcining at 500.degree.C. to 800.degree.C. a septechlorite precursor prepared by hydrothermal synthesis, and which may be characterized as a charge-balanced 1:1 trioctahedral phyllosilicate in which the divalent metal ions may be nickel, magnesium, cobalt, iron, copper, manganese, zinc, or mixtures thereof, and the trivalent metal ions may be aluminum, chromium, iron, or mixtures thereof, in relative proportions as set forth in the specification and claims.
    Type: Grant
    Filed: July 7, 1975
    Date of Patent: June 15, 1976
    Assignee: NL Industries, Inc.
    Inventors: Alan C. Wright, Hsien-Dao Chang
  • Patent number: 3962361
    Abstract: Alkylatable aromatic hydrocarbons are alkylated with olefins and alkylhalides under anhydrous alkylating conditions in the presence of a metallic cation exchanged synthetic saponite-type catalyst in which the central octahedral layer contains one or more divalent cations selected from the group consisting of Mg, Ni, Co, Zn, Mn, Cu, and mixtures thereof, provided that the octahedral layer contains less than 95 mole % Mg, and in which the metallic cation has a Pauling electronegativity greater than 1.0. In a specific embodiment, 1-dodecene is reacted with benzene by contacting the dodecene and benzene under anhydrous conditions in the liquid phase at the boiling point of the mixture with a catalyst comprising a metallic cation such as Al.sup.3.sup.+, In.sup.3.sup.+ and Cr.sup.3.sup.+ exchanged onto the surface of a nickeliferous saponite-type clay.
    Type: Grant
    Filed: December 6, 1974
    Date of Patent: June 8, 1976
    Assignee: NL Industries, Inc.
    Inventor: George E. Stridde
  • Patent number: 3959118
    Abstract: Hydrocarbon cracking is carried out by means of a catalyst which is a novel synthetic smectite composition related to saponite plus accessory hydrous magnesia. The composition is calcined prior to use as a catalyst.
    Type: Grant
    Filed: December 10, 1974
    Date of Patent: May 25, 1976
    Assignee: N L Industries, Inc.
    Inventor: William T. Granquist