Patents Represented by Attorney Delmar H. Larsen
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Patent number: 4014174Abstract: An improved method of consolidating the surface of a borehole in an incompetent formation and simultaneously strengthening the bond between the surface of the borehole and cement placed in the borehole is achieved by forcing an aqueous solution of a multivalent cation salt into the formation, thereafter forcing an alkali metal silicate solution which has a pH less than 12.0 containing at least 12% by weight silica into the formation, and thereafter forcing an aqueous cement slurry containing at least 2% by weight of a water soluble multivalent cation salt to contact the surface of the borehole. A cementitious piling intimately bonded to the formation is prepared by filing the stabilized borehole with an aqueous cement slurry and allowing the cement to harden.Type: GrantFiled: October 28, 1975Date of Patent: March 29, 1977Assignee: N L Industries, Inc.Inventor: Thomas C. Mondshine
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Patent number: 3994783Abstract: A process for the determination of creatine phosphokinase MB-isoenzyme (CPK-MB) level in serum in which CPK is determined before and after MB-activation with 1,4-dimercapto-2,3-dihydroxy butane or 2-mercaptoethanol, preferably in an assay system using the ATP/ADP conversion. The difference in the two values found is due to the CPK-MB present. The invention is of particular utility in the diagnosis and treatment of myocardial damage.Type: GrantFiled: September 26, 1975Date of Patent: November 30, 1976Assignee: CalbiochemInventors: Parinam Srinivasa Rao, James J. Lukes, Hiltrud S. Mueller
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Patent number: 3992467Abstract: Alkylatable aromatic hydrocarbons are alkylated with olefins and alkylhalides under anhydrous alkylating conditions in the presence of a metallic cation exchanged trioctahedral 2:1 layer-lattice smectite-type catalyst in which the metallic cation has a Pauling electronegativity greater than 1.0. In a specific embodiment, 1-dodecene is reacted with benzene by contacting the dodecene and benzene under anhydrous conditions in the liquid phase at the boiling point of the mixture with a catalyst comprising a metallic cation such as Al.sup.3.sup.+, In.sup.3.sup.+ and Cr.sup.3.sup.+ exchanged onto the surface of hectorite clay.Type: GrantFiled: March 29, 1976Date of Patent: November 16, 1976Assignee: NL Industries, Inc.Inventor: George E. Stridde
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Patent number: 3979331Abstract: Alkylatable aromatic hydrocarbons are alkylated with olefins and alkylhalides under anhydrous alkylating conditions in the presence of certain metallic cation exchanged synthetic hectorite-type catalysts in which the metallic cation has a Pauling electronegativity greater than 1.0 and in which the central octahedral layer contains one or more divalent metals which have an ionic radius not greater than 0.75 A. In a specific embodiment, 1-dodecene is reacted with benzene by contacting the dodecene and benzene under anhydrous alkylating conditions in the liquid phase at the boiling point of the mixture with a catalyst comprising a metallic cation such as Al.sup.3.sup.-, In.sup.3.sup.- and Cr.sup.3.sup.- exchanged onto the surface of a synthetic nickeliferous hectorite.Type: GrantFiled: December 6, 1974Date of Patent: September 7, 1976Assignee: NL Industries, Inc.Inventor: George E. Stridde
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Patent number: 3976744Abstract: Laminar 2 : 1 layer-lattice aluminosilicate minerals containing intra-lattice multivalent ions such as nickel, copper, cobalt and others. The minerals are particularly useful in catalytic operations. Procedures for preparing the inventive minerals are given.Type: GrantFiled: September 23, 1974Date of Patent: August 24, 1976Assignee: NL Industries, Inc.Inventor: William T. Granquist
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Patent number: 3971734Abstract: The invention provides compositions and aqueous solutions containing a sulfite compound chosen from alkali metal and ammonium sulfites and bisulfites and at least one water soluble stabilizing compound which is an organic phosphonate containing at least two phosphonic acid groups per molecule. Also provided is a method of reducing the oxidation rate of aqueous sulfite solutions caused by oxygen in the atmosphere and a method of decreasing the corrosiveness to ferrous metals of aqueous systems containing dissolved oxygen and at least one divalent cation derived from iron, cobalt, copper, manganese, and nickel.Type: GrantFiled: March 3, 1975Date of Patent: July 27, 1976Assignee: NL Industries, Inc.Inventor: Harley E. Bush
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Patent number: 3965043Abstract: Alkylatable aromatic hydrocarbons are alkylated with olefins and alkylhalides under anhydrous alkylating conditions in the presence of a metallic cation exchanged trioctahedral 2:1 layer-lattice smectite-type catalyst in which the metallic cation has a Pauling electronegativity greater than 1.0. In a specific embodiment, 1-dodecene is reacted with benzene by contacting the dodecene and benzene under anhydrous conditions in the liquid phase at the boiling point of the mixture with a catalyst comprising a metallic cation such as Al.sup.3.sup.+, In.sup.3.sup.+ and Cr.sup.3.sup.+ exchanged onto the surface of hectorite clay.Type: GrantFiled: September 6, 1974Date of Patent: June 22, 1976Assignee: NL Industries, Inc.Inventor: George E. Stridde
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Patent number: 3963602Abstract: Catalysts of wide utility, e.g., for hydrocarbon conversion, are prepared by calcining at 500.degree.C. to 800.degree.C. a septechlorite precursor prepared by hydrothermal synthesis, and which may be characterized as a charge-balanced 1:1 trioctahedral phyllosilicate in which the divalent metal ions may be nickel, magnesium, cobalt, iron, copper, manganese, zinc, or mixtures thereof, and the trivalent metal ions may be aluminum, chromium, iron, or mixtures thereof, in relative proportions as set forth in the specification and claims.Type: GrantFiled: July 7, 1975Date of Patent: June 15, 1976Assignee: NL Industries, Inc.Inventors: Alan C. Wright, Hsien-Dao Chang
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Patent number: 3962361Abstract: Alkylatable aromatic hydrocarbons are alkylated with olefins and alkylhalides under anhydrous alkylating conditions in the presence of a metallic cation exchanged synthetic saponite-type catalyst in which the central octahedral layer contains one or more divalent cations selected from the group consisting of Mg, Ni, Co, Zn, Mn, Cu, and mixtures thereof, provided that the octahedral layer contains less than 95 mole % Mg, and in which the metallic cation has a Pauling electronegativity greater than 1.0. In a specific embodiment, 1-dodecene is reacted with benzene by contacting the dodecene and benzene under anhydrous conditions in the liquid phase at the boiling point of the mixture with a catalyst comprising a metallic cation such as Al.sup.3.sup.+, In.sup.3.sup.+ and Cr.sup.3.sup.+ exchanged onto the surface of a nickeliferous saponite-type clay.Type: GrantFiled: December 6, 1974Date of Patent: June 8, 1976Assignee: NL Industries, Inc.Inventor: George E. Stridde
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Patent number: 3959118Abstract: Hydrocarbon cracking is carried out by means of a catalyst which is a novel synthetic smectite composition related to saponite plus accessory hydrous magnesia. The composition is calcined prior to use as a catalyst.Type: GrantFiled: December 10, 1974Date of Patent: May 25, 1976Assignee: N L Industries, Inc.Inventor: William T. Granquist