Abstract: A gravel pack is formed using a mixture of a solid deformable material and conventional gravel pack gravel. In the event of reservoir compaction, such a gravel pack will reduce the transmission of forces from the subterranean formation to the wellbore completion hardware, thereby significantly extending the life of a well. Deformable materials selected for mixing with conventional gravel may be elastically flexible, plastically deformable, or crushable solid materials or particles.

Abstract: The well intervention system of the invention is a novel subsea deployed wire line, “stiff wire” (conventional wire-line located inside reeled tubing or embedded in the tubing wall), coil tubing, or reeled pipe unit landed on the existing subsea wellhead assembly or tree, wherein the unit includes as an additional novel component a “carousel” tool caddy. The carousel is utilized to allow the remote change-out of multiple tool strings that are included in the carousel prior to deployment, thereby eliminating the need for a “riser” conduit to the surface or the need to trip tools through the riser column for tool replacement. The subject invention also includes an improved method for conducting a well intervention activity, wherein the method includes the step of selecting a tool for the well intervention activity from a carousel tool caddy located in close proximity to the well.

Abstract: A method of installing tubular conduits (e.g. casing, liners, sand screens) into a highly deviated borehole. A lower plug is attached at one end of a portion of a tubular conduit. This end is inserted into a borehole. After insertion of the length of conduit intended to be buoyancy-aided into the borehole, an inflatable plug insert is attached at the upper end. The inflatable plug has a built-in valve designed to enable fluid communication between the buoyancy-aided tubular section and the insertion string. A pump is attached to the built-in valve and the fluid within the section intended to be buoyancy-aided is removed, after which the built-in valve is closed. The buoyancy provided by the evacuated section enables insertion of the tubular conduit into boreholes greatly deviated from the vertical, reducing running drag and the risk of the tubular becoming differentially stuck.

Abstract: The well intervention system is a subsea deployed wire line, “stiff wire” (conventional wire-line located inside reeled tubing or embedded in the tubing wall), coil tubing, or reeled pipe unit landed on the existing subsea wellhead assembly or tree, wherein the unit includes as an additional novel component a “carousel” tool caddy. The carousel is utilized to allow the remote change-out of multiple tool strings that are included in the carousel prior to deployment, thereby eliminating the need for a “riser” conduit to the surface or the need to trip tools through the riser column for tool replacement. A method for conducting a well intervention activity, wherein the method includes the step of selecting a tool for the well intervention activity from a carousel tool caddy located in close proximity to the well. The invention system may also be employed in a similar manner to conduct repair or surveillance operations for pipelines or flowlines having flow control manifolds.

Abstract: A cathodic protection system for offshore structures includes an elongated electrode carrier, such as a pipe, with a plurality of sacrificial anodes attached, that is placed on the ocean floor and electrically connected to the structures to be protected. The system is particularly useful for retrofitting cathodic protection systems for offshore structures that have exceeded their expected life.

Abstract: A method for inhibiting the formation of gas hydrates in a petroleum fluid having hydrate-forming constituents is claimed. More specifically, the method can be used to treat a petroleum fluid, such as natural gas conveyed in a pipe, to inhibit the formation of a hydrate flow restriction in the pipe. The hydrate inhibitors used for practicing the method comprise substantially water soluble homopolymers and copolymers of N-acyldehydroalanine derivatives which are esters or amides of N-acyldehydroalanine.

Abstract: A method for inhibiting the formation of gas hydrates in a petroleum fluid having hydrate-forming constituents is claimed. More specifically, the method can be used to treat a petroleum fluid, such as natural gas conveyed in a pipe, to inhibit the formation of a hydrate flow restriction in the pipe. The hydrate inhibitors used for practicing the method comprise substantially water soluble homopolymers and copolymers of surfactant monomers, wherein the surfactant monomer unit may be represented by the formula: where R1 and R2 independently are hydrogen or a methyl group, M is a metal cation, n is a number sufficient to produce a number average molecular weight between 1000 and 6,000,000, and o is a number from 1 to 5.

Abstract: A system for enhancing steam distribution in a thermal stimulation phase, and for reducing the production of particulate matter with hydrocarbon fluids in a production phase, has a base pipe with a limited number of spaced-apart holes. The spaced-apart holes are sized and located so that steam is uniformly distributed in the reservoir. A collar is disposed around each hole to deflect the steam into an annulus between the base pipe and a wire-wrap screen section to avoid erosion and deterioration of the wire-wrap screen, which is required in the production phase. Mobilized hydrocarbon fluids flow to the wire-wrap screen section, which acts to filter particulate matter so that the production of particulate matter with hydrocarbon fluid is limited. The open area in the base pipe is significantly reduced, as compared with conventional methods, so that at the design injection rates, the pressure drop through the spaced-apart holes is larger than the pressure drop along the base pipe.

Abstract: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is claimed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitors used for practicing the method comprise substantially water soluble polymers having N-vinyl amide or N-allyl amide units. Specific examples of such copolymers include, N-vinyl-N-methylacetamide (VIMA) copolymerized with acryloylpyrrolidine (APYD) or acryloylpiperidine (APID), and more preferably, VIMA copolymerized with N-substituted methacrylamides, such as N-isopropylmethacrylamide (iPMAM) and methacryloylpyrrolidine (MAPYD) to produce inhibitors for practicing the claimed method.

Abstract: Novel maleimide copolymers have at least two monomeric units, a maleimide unit and a vinyl unit having a pendant group, the pendant group having two to twenty-one carbon atoms, at least one nitrogen atom and at least one oxygen atom. The copolymer has an average molecular weight between about 1,000 and about 6,000,000. Preferred maleimide copolymers include acrylamide/maleimide copolymers, N-vinyl amide/maleimide copolymers, vinyl lactam/maleimide copolymers, alkenyl cyclic imino ether/maleimide copolymers, and acryloylamide/maleimide copolymers. The substantially water soluble maleimide copolymers are useful for inhibiting the formation of clathrate hydrates in a fluid having hydrate-forming constituents by reducing the rate of nucleation, growth, and/or agglomeration of gas hydrate crystals in a petroleum fluid stream, thereby inhibiting the formation of a hydrate blockage in the pipe conveying the petroleum fluid stream.

Abstract: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is disclosed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitor used for practicing the method is selected from the family of substantially water soluble copolymers formed from N-methyl-N-vinylacetamide (VIMA) and one of three comonomers, vinylpyrrolidone (VP), vinylpiperidone (VPip), or vinylcaprolactam (VCap). VIMA/VCap is the preferred copolymer. These copolymers may be used alone or in combination with each other or other hydrate inhibitors. Preferably, a solvent, such as water, brine, alcohol, or mixtures thereof, is used to produce an inhibitor solution or mixture to facilitate treatment of the petroleum fluid stream.

Abstract: The present invention relates to a continuous process for the polymerization of olefin(s) utilizing a metallocene catalyst or catalyst system in a continuous slurry or gas phase polymerization process for polymerizing monomer(s). The invention is more particularly drawn to a gas phase polymerization process for polymerizing one or more olefin(s), alone or in combination, in the presence of a metallocene catalyst system in a fluidized bed reactor, preferably operating in a condensed mode.

Abstract: This invention relates to a process for transitioning between incompatible polymerization catalyst systems. Particularly, the invention relates to a process for transitioning from an olefin polymerization reaction utilizing a traditional Ziegler-Natta catalyst system to a metallocene-olefin polymerization reaction.

Abstract: This invention relates to a process for transitioning between incompatible polymerization catalyst systems. Particularly, the invention relates to a process for transitioning from an olefin polymerization reaction utilizing a traditional Ziegler-Natta catalyst system to a metallocene-olefin polymerization reaction.

Abstract: Novel maleimide copolymers have at least two monomeric units, a maleimide unit and a vinyl unit having a pendant group, the pendant group having two to twenty-one carbon atoms, at least one nitrogen atom and at least one oxygen atom. The copolymer has an average molecular weight between about 1,000 and about 6,000,000. Preferred maleimide copolymers include acrylamide/maleimide copolymers, N-vinyl amide/maleimide copolymers, vinyl lactam/maleimide copolymers, alkenyl cyclic imino ether/maleimide copolymers, and acryloylamide/maleimide copolymers. The substantially water soluble maleimide copolymers are useful for inhibiting the formation of clathrate hydrates in a fluid having hydrate-forming constituents by reducing the rate of nucleation, growth, and/or agglomeration of gas hydrate crystals in a petroleum fluid stream, thereby inhibiting the formation of a hydrate blockage in the pipe conveying the petroleum fluid stream.

Abstract: This invention relates to a process for transitioning between polymerization catalyst systems which are incompatible with each other. Particularly, the invention relates to a process for transitioning from an olefin polymerization reaction utilizing a traditional Ziegler-Natta catalyst system to a metallocene-olefin polymerization reaction.

Abstract: This invention includes a process for preparing a solid state polymerized poly(ethylene naphthalate)or PEN polymer comprising: (1) preparing a molten PEN polymer with an intrinsic viscosity of from about 0.25 dl/g to about 0.55 dl/g, (2) dispersing an inert gas into the molten PEN polymer to form a foamed PEN polymer with a void fraction of from about 0.10 to about 0.50, (3) forming the foamed PEN polymer into granules, (4) devolatilizing the granular PEN polymer at a temperature of from about 80.degree. C. to about 140.degree. C., (5) crystallizing the devolatilized PEN polymer at a temperature of from about 150.degree. C. to about 260.degree. C., and (6) solid state polymerizing the crystallized PEN polymer at a temperature of from about 235.degree. C. to about 265.degree. C. to form a solid state polymerized PEN product.

Abstract: This invention is a composition and a kit to prepare the composition and articles made from the composition, which composition comprises polyethylene terephthalate, a nucleating agent having a defined Nucleation Index and optionally a polyolefin and a heat stabilizer. A particularly effective nucleating agent is polytetrafluoroethylene.

Abstract: Polyester prepolymer granules with open-ended cavities provide greatly improved solid state polymerization rates by improving reaction by-product diffusion characteristics.

Abstract: A method of making a polyethylene terephthalate/polyolefin blend for sheeting and thermoformed articles which has improved color stability and can be recycled many times. A heat stabilizer is melt blended only with the polyolefin prior to its incorporation into the polyethylene terephthalate. The PET and polyolefin are then blended and extruded into sheeting and subsequently thermoformed into articles useful as microwave oven trays.