Abstract: Disclosed are low temperature, moisture curable coating compositions, related coated substrates, and methods for coating a substrate. The coating compositions include an ungelled, secondary amine-containing Michael addition reaction product of reactants including a compound comprising more than one site of ethylenic unsaturation, and an aminofunctional silane.

Abstract: A resin containing a liquid pigment dispersion is disclosed. The dispersion comprises a pigment dispersed in a blend of two or more active hydrogen-containing materials that together have a freezing point that is room temperature or below. The pigment remains dispersed in the blend, even if the dispersion is subjected to freezing and thawing. A curative blend comprising at least two active hydrogen-containing materials, which is liquid at room temperature, is also disclosed. The dispersions and curative blends of the present invention can be solvent-free. Resins and prepolymers comprising the curative blends of the invention, either pigmented or unpigmented, are also disclosed.

Abstract: Coating compositions are disclosed that include corrosion resisting particles such that the coating composition can exhibit corrosion resistance properties. Also disclosed are substrates at least partially coated with a coating deposited from such a composition and multi-component composite coatings, wherein at least one coating later is deposited from such a coating composition. Methods and apparatus for making ultrafine solid particles are also disclosed.

Abstract: Coating compositions are disclosed that include corrosion resisting particles such that the coating composition can exhibit corrosion resistance properties. Also disclosed are substrates at least partially coated with a coating deposited from such a composition and multi-component composite coatings, wherein at least one coating later is deposited from such a coating composition. Methods and apparatus for making ultrafine solid particles are also disclosed.

Abstract: Disclosed are pigment dispersions and coating compositions that include such pigment dispersions. The pigment dispersions include: (a) a pigment; (b) an acid functional, hydroxyl functional and secondary amine functional acrylic polymer having a weight average molecular weight of at least 11,000; and (c) a liquid carrier comprising an organic solvent.

Abstract: Disclosed are antimicrobial coating compositions. These coating compositions comprise (a) a film-forming resin; (b) a porous solid comprising pores having anti-microbial metal ions disposed therein; and (c) an onium compound.

Abstract: Disclosed are low temperature curable coating compositions, related coated substrates, methods for depositing a coating on a substrate and methods for refinishing the surface of an article, such as an automobile. The coating compositions include: (1) an aminofunctional silicon compound; (2) a polyether; and (3) a compound comprising functional groups reactive with the amino functionality of the aminofunctional silicon compound.

Abstract: Disclosed are powder coating compositions suitable for producing a decorative and durable coating having a homogeneous hue, articles comprising a decorative and durable coating having a homogeneous hue deposited thereon, methods for preparing a decorative and durable coating having a homogeneous hue, kits capable of producing a decorative and durable coating having a homogeneous hue, and methods for color matching using powder coating compositions.

Abstract: Disclosed are low temperature, moisture curable coating compositions, related coated substrates, and methods for coating a substrate. The coating compositions include an ungelled, secondary amine-containing Michael addition reaction product of reactants including a compound comprising more than one site of ethylenic unsaturation, and an aminofunctional silane.

Abstract: Disclosed are coating compositions that include a continuous phase that includes water and a dispersed phase that includes a microgel having a mean particle size of greater than 50 nanometers. The microgel is formed from reactants selected so as to provide a copolymer having a certain calculated Tg and includes a cycloaliphatic (meth)acrylate.

Abstract: Fluorinated polyurethanes and methods of making the same are provided. The fluorinated polyurethanes are useful for making polyurethane coating compositions for use in aerospace and other applications. The method includes a “split process” by which a hydroxypolyalkylenoxy derivative of a perfluoropolyoxyalkane is separately reacted with isocyanate to produce an isocyanate-terminated compound. The isocyanate-terminated compound is then reacted with an emulsifier to produce an acid- and hydroxyl-functional compound. The acid- and hydroxyl-functional compound is then reacted with isocyanate to form an acid-functional, isocyanate-terminated compound. The acid-functional, isocyanate-terminated compound is then reacted with at least one polyol to produce a higher molecular weight, acid- and hydroxyl-functional compound. Finally, the acid functional groups of the high molecular weight, acid- and hydroxyl-functional compound are neutralized to form a fluoro-urethane salt which is dispersed in water.

Abstract: One-part moisture curable sealant compositions and methods of making the same are provided. The composition includes a silane-terminated polythioether component and a catalyst. The silane-terminated polythioether component and catalyst are isolated from moisture to prevent curing. The composition is stable against curing at ambient temperature and under conditions substantially free of moisture. When the composition is applied to a substrate and exposed to moisture, the composition cures to form a sealant. A method of making a sealant composition includes reacting a mercapto-terminated polythioether with a compound having a silane group to form a silane-terminated polythioether. The silane-terminated polythioether is then combined with a catalyst and isolated from moisture to prevent curing. Lastly, the composition is applied to a substrate and exposed to moisture which allows the composition to cure to form a sealant.

Abstract: Compositions, such as aerospace sealant, coating, and/or potting compositions are disclosed. The compositions include a polythioether and, in at least some cases, can be sprayable and fuel resistant even when substantially free of volatile organic compounds.

Abstract: Disclosed are waterborne, radiation-curable coating compositions. These coating compositions include a water-dispersible polymer and a hydrophobic multi-functional ethylenically unsaturated compound. The compositions are characterized by being viscosity stable at elevated temperatures and alkaline conditions.

Abstract: Disclosed herein are dual cure coating compositions that include a melamine group-containing polyethylenically unsaturated compound and a polysiloxane. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.

Abstract: Methods for generating metallic particles in situ in a polymer are disclosed. A method includes (a) contacting the polymer with a solution comprising (i) a solvent, (ii) a metal salt, and (iii) a free radical generator; (b) removing the polymer from the solution; and (c) exposing the polymer to actinic radiation. Polymer composites and polymer nanocomposites comprising inorganic particulates comprising metallic particles generated in the polymer are also disclosed.

Abstract: A pigment dispersant is disclosed comprising a tri-block copolymer having a first block comprising a glycidyl(meth)acrylate reacted with a napthoic acid, a second block comprising (meth)acrylic acid alkyl esters, and a third block comprising (meth)acrylic acid alkyl esters, wherein said third block is different from said second block. The dispersant is suited for use in a nanoparticulate dispersion comprising pigment particles having an average primary particle size of less than 100 nm.

Abstract: A liquid pigment dispersion is disclosed. The dispersion comprises a pigment dispersed in a blend of two or more active hydrogen-containing materials that together have a freezing point that is room temperature or below. The pigment remains dispersed in the blend, even if the dispersion is subjected to freezing and thawing. A curative blend comprising at least two active hydrogen-containing materials, which is liquid at room temperature, is also disclosed. The dispersions and curative blends of the present invention can be solvent-free. Resins and prepolymers comprising the curative blends of the invention, either pigmented or unpigmented, are also disclosed.

Abstract: Disclosed are methods for treating and coating a ferrous metal substrate, such as cold rolled steel, hot rolled steel, and electrogalvanized steel. These methods include contacting the ferrous metal substrate with an aqueous pretreatment composition comprising: (a) a Group IIIB and/or IVB metal compound; (b) phosphate ions; and (c) water.

Abstract: Disclosed are coating compositions based on non-aqueous dispersions of solid fluoropolymer particles in an organic solution of acrylic polymers. The coating compositions include: (1) a fluorocarbon polymer; (2) an organic solvent; and (3) an adjuvant polymer.