Abstract: Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIII metal having an atomic number of at least 44, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; and at least one aliphatic polyether such as a polyethylene glycol dimethyl ether or a crown ether. The catalyst system also preferably contains a compound of another metal, preferably lead.
Type:
Grant
Filed:
May 26, 2000
Date of Patent:
February 12, 2002
Assignee:
General Electric Company
Inventors:
Eric James Pressman, Grigorii Lev Soloveichik, Kirill Vladimirovich Shalyaev, Bruce Fletcher Johnson