Patents Represented by Attorney, Agent or Law Firm Douglas W Miller
  • Patent number: 6955065
    Abstract: A first, optional second, optional third air conditioning systems employing air condensers and/or water condensers, coupled to a water source are disclosed. The water source includes a water to air heat exchanger, which is not coupled to nor provides cooling to either a habitable interior space or an attic.
    Type: Grant
    Filed: June 13, 2003
    Date of Patent: October 18, 2005
    Inventors: Darrell Thomas Taylor, Jeffrey Edward Cantrell
  • Patent number: 6527015
    Abstract: Pipes or pipelines insulated on their surface or surfaces are described. The pipes or pipelines may be for submerged service, below the surface of water. The insulation chosen may be an epoxy substantially free of phenolics and one or more of glass or ceramics. The coating may be an abrasion resistant coating. Such pipes or pipelines are generally intended for the transport of fluids, which can include natural gas, natural gas liquids, crude oil, refined products, chemicals, combinations thereof, and the like.
    Type: Grant
    Filed: December 7, 2001
    Date of Patent: March 4, 2003
    Inventor: F. Glenn Lively
  • Patent number: 6444774
    Abstract: This invention relates generally to fibers and fabrics prepared using crystalline propylene polymer compositions comprising both propylene homopolymer and propylene copolymer. The propylene polymer compositions are prepared using at least one metallocene catalyst system in a polymerization process that involves the initial homopolymerization of propylene followed by the copolymerization of propylene with a small amount of comonomer. Fibers prepared with these propylene polymers are significantly more elastic and fabrics prepared with these polymers have a significantly broader bonding window which allows for more easy processing compared to fibers and fabrics prepared from known propylene polymers.
    Type: Grant
    Filed: September 29, 1998
    Date of Patent: September 3, 2002
    Assignee: ExxonMobil Chemical Patents, Inc.
    Inventors: G. Allan Stahl, Galen C. Richeson
  • Patent number: 6397895
    Abstract: Pipes or pipelines insulated and optionally coated on their interior surface or surfaces are described. Pipes or pipelines insulated and optionally coated on their exterior surface or surfaces are also contemplated, The pipes or pipelines may be for submerged service, below the surface of water. The insulation chosen may be an epoxy substantially free of phenolics and one or more of glass or ceramics. The coating may be an abrasion resistant coating. Such pipes or pipelines are generally intended for the transport of fluids, which can include natural gas, natural gas liquids, crude oil, refined products, chemicals, combinations thereof, and the like.
    Type: Grant
    Filed: June 28, 2000
    Date of Patent: June 4, 2002
    Inventor: F. Glenn Lively
  • Patent number: 6391817
    Abstract: A method for controlling fouling in a prepolymerization reactor is disclosed and comprises combining a supported metallocene catalyst system, an alpha olefin monomer feed, and added hydrogen under suitable prepolymerization reaction conditions. This method is also useful for the control of agglomeration during a prepolymerization reaction.
    Type: Grant
    Filed: March 10, 1995
    Date of Patent: May 21, 2002
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Jeffrey L. Brinen
  • Patent number: 6235664
    Abstract: The present invention relates to polypropylene copolymer alloys which are especially suited for soft fiber and fabric applications. These alloys comprise an ethylene-propylene random copolymer having an ethylene content of from about 1.0 to 5.0% by weight, in an amount of from about 40 to 90% by weight of the alloy; and an ethylene-propylene bipolymer having an ethylene content of from about 10 to 30% by weight, in an amount of from about 10 to 60% by weight of the alloy. The present invention further relates to fiber and fabric articles made from such alloys.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: May 22, 2001
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: George Byron Georgellis, Chia Yung Cheng, William Moa-Tseng Chien
  • Patent number: 6228902
    Abstract: Emulsion delivery systems for applying anti-stick additives to polymer particles, provide free-flowing particles of polymers or polymer blends, that without the anti-stick additives tend to agglomerate. The agglomeration presents storage and handling difficulties. The anti-stick additives are selected from the group consisting of primary amides, secondary amides, ethylene bisamides, waxes, talc and silica.
    Type: Grant
    Filed: July 22, 1997
    Date of Patent: May 8, 2001
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Barry Gene Brueggeman, Peter Joseph Ferenz, Joel Edward Schmieg
  • Patent number: 6225432
    Abstract: Branched polypropylene compositions which have improved melt strength and good processability are provided. The branched polypropylene compositions of the present invention have a polydispersity of less than 4.0 and a melt point greater than 90° C. Further, the weight average branching index g of the polypropylene compositions is less than 0.95. Additionally, a novel process is provided for efficiently producing a branched polypropylene composition comprising: a) contacting propylene monomers in a reactor with an inert hydrocarbon solvent or diluent and a catalyst composition comprising one or more single site catalyst compounds capable of producing stereospecific polypropylene at a temperature from about 40° C. to about 120° C., wherein the ratio in the reactor of the propylene monomers to the inert hydrocarbon solvent or diluent is less than 9.
    Type: Grant
    Filed: August 17, 1999
    Date of Patent: May 1, 2001
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Weiqing Weng, Eric J. Markel, Armenag H. Dekmezian, Palanisamy Arjunan
  • Patent number: 6124428
    Abstract: Melt processed linear polyethylenes which may optionally contain an elastomer, are shown to exhibit improved processability through the addition of certain surfactants. Among the melt processing parameters improved are reduced head pressure, reduced torque, reduced motor load, reduced or eliminated melt fracture, or combinations of these parameters. The surfactants can be chosen from a non-aromatic alkyl sulfonate or sulfate salt wherein a cation of the salt is selected from the group consisting of Na, K, Li, and other alkali cations and quaternary ammonium cations, said surfactant being essentially free of halogens.
    Type: Grant
    Filed: August 6, 1997
    Date of Patent: September 26, 2000
    Assignee: Exxon Chemical Patents, Inc
    Inventors: Joel Edward Schmieg, Thomas Craig Erderly, Dennis George Peiffer, James Joseph Chludzinski
  • Patent number: 6111039
    Abstract: The present invention provides a catalyst system that exhibits unexpected control of desired properties in polyolefin products. The catalyst system includes a titanium-supported catalyst in combination with a mixture of tetraethoxysilane (TEOS) and dicyclopentyldimethoxy-silane (DCPMS). This catalyst system has been found to be effective in making polypropylene and polypropylene copolymers having relatively high melt flow rates and moderately broad molecular weight distribution.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: August 29, 2000
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Nemesio Delgado Miro, George Byron Georgellis, Homer Swei
  • Patent number: 6107454
    Abstract: Melt processed linear polyethylenes are shown to exhibit improved processability through the addition of certain surfactants. Among the melt processing parameters improved are reduced head pressure, reduced torque, reduced motor load, reduced or eliminated melt fracture, or combinations of these parameters. The surfactants can be chosen from a non-aromatic alkyl sulfonate or sulfate salt wherein a cation of the salt is selected from the group consisting of Na, K, Li, and other alkali cations and a quaternary ammonium cations, said surfactant being essentially free of halogens.
    Type: Grant
    Filed: August 6, 1997
    Date of Patent: August 22, 2000
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Joel Edward Schmieg, Thomas Craig Erderly, Dennis George Peiffer, James Joseph Chludzinski
  • Patent number: 6087459
    Abstract: A method of forming a polymer that simultaneously provides an improved level of impact resistance and processability in which an .alpha.-olefin monomer is subjected to polymerization in the presence of a Ziegler-Natta catalyst system and a blend of electron donors including dicyclopentyldimethoxysilane (DCPMS) and propyltriethoxysilane (PTES). The polymer so formed will have a relationship between a first melt flow rate of a homopolymer formed by polymerizing an .alpha.-olefin monomer in the presence of a Ziegler-Natta catalyst system and a first electron donor (MFR (a)), and a second melt flow rate of a homopolymer formed polymerizing an .alpha.-olefin monomer in the presence of the Ziegler-Natta catalyst system and a second electron donor (MFR (b)), is defined by the equation:1.2.ltoreq.log [MFR(b)/MFR(a)].ltoreq.1.
    Type: Grant
    Filed: May 14, 1998
    Date of Patent: July 11, 2000
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Nemesio D. Miro, Masatoshi Ohkura
  • Patent number: 5994482
    Abstract: The present invention relates to polypropylene alloys which are especially suited for soft fiber and fabric applications. An embodiment of these alloys comprise an ethylene-propylene random copolymer having an ethylene content of from about 1.0 to 5.0% by weight, in an amount of from about 40 to 90% by weight of the alloy; and an ethylene-propylene bipolymer having an ethylene content of from about 10 to 30% by weight, in an amount of from about 10 to 60% by weight of the alloy. The present invention further relates to a hybrid process for making these alloys.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: November 30, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: George Byron Georgellis, Chia Yung Cheng, William Moa-Tseng Chien
  • Patent number: 5981643
    Abstract: Copolymers of ethylene and a cyclic olefin, preferably a fused ring cyclic olefin (FRCO), optionally containing an alpha-olefin and/or a non-conjugated diene, display increasing glass transition temperatures (T.sub.g) as the amount of FRCO in the copolymer increases. This increase brings these polymers quickly above a T.sub.g acceptable as elastomers. Addition of specially selected process oils, based on cohesive energy densities of both the copolymer and the process oil, is shown to lower T.sub.g to a range acceptable for elastomers e.g. below about -30.degree. C. The copolymer/process oil combination can then be used in elastomer compounding operations and behave in typical elastomer fashion.
    Type: Grant
    Filed: October 9, 1997
    Date of Patent: November 9, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Sudhin Datta, Bruce A. Harrington
  • Patent number: 5952427
    Abstract: Elastomeric polymers including ethylene, alpha-olefin and vinyl norbornene are shown to have improved extrusion characteristics, improved electrical properties, improved cure characteristics compared to ethylene, alpha-olefin, non-conjugated diene elastomeric polymers containing non-conjugated dienes other than vinyl norbornene. The elastomeric polymers containing vinyl norbornene generally have a branching index below 0.5. Such elastomeric polymers are combined with up to 30 parts of metallocene catalyzed ethylene, alpha-olefin copolymers to improve physical properties.
    Type: Grant
    Filed: June 5, 1997
    Date of Patent: September 14, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Periagaram Srinivasan Ravishankar, Charles Douglas Burrage
  • Patent number: 5929174
    Abstract: The invention concerns a polymer derived from ethylene and at least 5 wt % of acrylic acid neutralised by a divalent cation (D) and a monovalent cation (M) at a mol ratio D/(D+M) of from 0.3 to 0.8 with at least 23 mol % of the acrylic acid derived acid groups neutralised by the divalent cation so as to provide a melt index uplift of at least 250%.
    Type: Grant
    Filed: March 20, 1997
    Date of Patent: July 27, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Dirk Jozef Celeste Permentier, Tengku Mahamut
  • Patent number: 5837787
    Abstract: Rubbery, amorphous cyclic olefin/.alpha.-olefin copolymers in a molar ratio from 5/95 to 30/70. The copolymers are rubbery and have the general properties of thermoplastic elastomers, e.g. good elastic recovery, toughness, and high elasticity, and have a relatively low glass transition temperature (Tg) to avoid brittleness and hardness under normal use temperature. The copolymers also have a high molecular weight, a narrow molecular weight distribution and a uniform, random comonomer distribution to impart a rubbery loss modulus plateau over the temperature range from Tg to above 100.degree. C., and are optionally lightly crosslinked or plasticized to further extend their useful temperature range.
    Type: Grant
    Filed: January 19, 1993
    Date of Patent: November 17, 1998
    Assignee: Exxon Chemical Patents, Inc.
    Inventor: Bruce Allan Harrington
  • Patent number: 5807946
    Abstract: Motor vehicle brake parts based on an ethylene, alpha-olefin, vinyl norbornene elastomeric polymer are manufactured with more efficiency due to brake part compounds having lower viscosity, faster and fuller cures than ethylene, alpha-olefins, diene monomer compounds, where the diene monomer is other than vinyl norbornene. Additionally, the brake parts based on the ethylene, alpha-olefin, vinyl norbornene elastomeric polymer have improved resistance to elevated temperature properties, and good heat aging characteristics, compared to for instance ethylene, alpha-olefin, non-conjugated diene elastomers (where the diene is other than vinyl norbornene) or styrene butadiene rubbers.
    Type: Grant
    Filed: June 14, 1995
    Date of Patent: September 15, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Eric Paul Jourdain, Periagaram S. Ravishankar
  • Patent number: 5798420
    Abstract: This invention relates to block polymers containing both crystalline and elastomeric blocks, the block copolymer having an A block and a B block. The A block is a polyethylene or an ethylene polymer optionally containing an alpha-olefin and optionally a non-conjugated diene, and is generally crystalline. The B block is an ethylene, .alpha.-olefin copolymer. Also disclosed is a process for manufacture of the block copolymers and methods for coupling the block copolymers. Coupled block copolymers are useful as thermoplastic elastomers exhibiting physical properties approaching those of crosslinked EP or EPDM elastomers, but showing thermal processability after coupling. The block copolymers of the present invention may also be used as a lubricant or fuel additive, as a plastics blend component, and as a component in hot melt adhesives.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: August 25, 1998
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Charles Cozewith, Gary William Ver Strate, Roger K. West, Gaetano A. Capone
  • Patent number: 5766713
    Abstract: Elastomeric vehicle hoses based on ethylene, alpha-olefin, vinyl norbornene elastomeric polymers will exhibit improved cure state and improved long term heat aging. Long term heat aging is an important consideration, as vehicle lives get longer and under the hood temperatures get higher. Also, such elastomeric based hoses will have improved compression set under a wide range of service temperatures. Such excellent compression set values lead to improved sealability over a wide temperature range. Additionally, these elastomeric polymers exhibit lower compound viscosity leading generally to improved processability.
    Type: Grant
    Filed: June 14, 1995
    Date of Patent: June 16, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Periagaram S. Ravishankar, Jean-Roch Schauder