Abstract: This invention relates to thermoplastic formulations which comprise: (1) at least 50 weight percent, based upon the total weight of the formulation, unreinforced nylon selected from nylon 6,6 nylon 6 or mixtures thereof, and (2) a sufficient amount of decabromodiphenyl ethane to provide a melt index, as measured by ASTM D 1238-79, 265.degree. C./1200 grams, which is higher than the like-measured melt index of such nylon alone.This invention also relates to thermoplastic formulations which comprise: (1) at least 50 weight percent, based upon the total weight of the formulation, reinforced nylon selected from glass reinforced nylon 6,6, glass reinforced nylon 6 or mixtures thereof, and (2) a sufficient amount of decabromodiphenyl ethane to provide a melt index, as measured by ASTM D 1238.LAMBDA., 275.degree. C./550 grams, which is higher than the like-measured melt index of such reinforced nylon alone.

Abstract: This invention relates to a process for enhancing the properties of alkylene(C.sub.1 -C.sub.6)-bis-(tetrabromophthalimide) or bis-(tetrabromophthalimide) produced by the bromination, respectively, of alkylene(C.sub.1 -C.sub.6)-bis-(phthalimide) or bis-(phthalimide) with a brominating agent in the presence of oleum, the process comprising curing the alkylene(C.sub.1 -C.sub.6)bis-(tetrabromophthalimide) or bis-(tetrabromophthalimide) at a temperature above about 150.degree. C. and below the melting point of the tetrabromophthalimide being cured for a period of from about 36 hours to about 5 hours. This enhanced product and its use in molding and extrusion compositions and in molded and extruded articles is also disclosed.

Abstract: This invention relates to the process for preparing partially brominated non-condensed ring polyaromatic product. The process comprises forming a reaction mass by adding a substantially stoichiometric amount of Br.sub.2 to a mixture comprising a non-condensed ring polyaromatic, a solvent selected from a group consisting of methylene dibromide, methylene dichloride and mixtures thereof, and a catalyst selected from the group consisting of zirconium halide, iron, ferric chloride and mixtures thereof, the reaction mass being maintained at a temperature within the range of from about 10.degree. to about 50.degree. C. during at least substantially all of the addition; refluxing the reaction mass after the addition is completed or at least nearly completed; and recovering from the reaction mass the partially brominated non-condensed ring polyaromatic product.

Abstract: This invention relates to novel mixtures of brominated diphenyl ethanes, such mixtures containing a predominant amount of hexabromodiphenyl ethane and having an average bromine number, based upon GC area percent, of from about 6.7 to about 7.3. ABS based formulations containing such mixtures and articles made from such formulations are also a part of this invention.

Abstract: This invention relates to a process for producing a product which is predominant in decabromodiphenyl alkane.

Abstract: Vinyl-olefins are converted to vinylidene olefin dimers at a selectivity of at least 85 mole percent by reacting a mixture of dry vinyl-olefin containing 0.001-0.04 moles of trialkyl aluminum per mole of initial vinyl-olefin at a temperature in the range of about 100.degree.-140.degree. C. for a time sufficient to convert at least 80 mole percent of the initial vinyl-olefin to a different material.

Abstract: A process is disclosed for producing diphenylalkanes, which process comprises the formation of a reaction mass comprising a (1) solvent, (2) iron, (3) copper, Cu(I) salt or a mixture thereof, and (4) phenylalkylhalide, and maintaining this reaction mass at a temperature of at least 40.degree. C. until diphenylalkane is formed.

Abstract: A process of selectively preparing p-bromo-o-alkylanilines (e.g. 4-bromo-2-methylaniline) by reacting o-alkylanilines (e.g., 2-methylaniline) with unadsorbed bromine in a solvent selected from the group consisting of an inert di- tri- or tetrahaloaliphatic hydrocarbon (e.g., dichloromethane and dibromomethane), an alkyl nitrile (e.g., acetonitrile) and mixtures thereof.

Abstract: This invention relates to a trailer for transporting solid, loose materials. The trailer features an elongated frame which is attached to a towing vehicle and which carries a bin for containing the solid material. A discharge means is associated with the bin to effect discharge of the material therefrom. The material is conveyed after discharged by a conveying means along a path which extends from the discharge means, over at least a portion of the towing vehicle, and to a dumping point forward of the towing vehicle. This path lies substantially in the vertical plane of the long axis of the trailer.

Abstract: This invention relates to an apparatus and process for detecting gas permeability in a main rupture disc which is in gaseous communication with a vessel. The process comprises: fitting a chamber over and in gas-tight association with the outside surface of the main rupture disc; selecting a burst presure for the main rupture disc and a set pressure; obtaining a gaseous pressure within the chamber which is greater than the normal operating pressure within the vessel, and equal to the difference between the set pressure and the burst pressure of the main rupture disc; and monitoring the chamber pressure for a decrease thereof. The apparatus comprises, generally, a chamber, a means for obtaining a gaseous pressure within the chamber, and a means for monitoring a change in pressure in the chamber.

Abstract: This invention relates to a process for treating a first product which contains monobromopentaerythritol, dibromoneopentyl glycol and tribromoneopentyl alcohol to yield a second product having a dibromoneopentyl glycol content, on a weight percent basis, greater than that of the first product. The process features forming a stirrable mass from the first product and a solvent system in which, at a temperature within the range of from about 0.degree. C. to about 40.degree. C., the monobromopentaerythritol and the tribromoneopentyl alcohol are more soluble than the dibromoneopentyl glycol and in which at least 85% of the dibromoneopentyl glycol in the mass is insoluble; maintaining the reaction mass within the aforementioned temperature range to realize an insoluble portion and a solvent and solute portion; and separating the insoluble portion and the solvent and solute portion without substantial precipitation of the solute from the solvent and solute portion.

Abstract: This invention relates to a process for preparing a white flame retardant product which principally contains a bisimide. The process comprises: providing an essentially water-free solution containing tetrabromophthalic anhydride and a solvent in a reaction vessel; forming a reaction mass by adding a diamine or a diamine salt to the solution at an addition rate such that, at the addition temperature, water formed during the addition is removed from the reaction mass substantially as it is formed; terminating the addition of the diamine when the molar ratio of the tetrabromophthalic anhydride initially present in the solution to the diamine or diamine salt added is at least about 2.00:1; maintaining the reaction mass at a temperature of at least 125.degree. C. for at least 0.5 hr after the addition; and recovering from the reaction mass the flame retardant product.

Abstract: Tetrabromobisphenol-A is made in high purity by adding a methanol-bromine solution to a methanol-bisphenol-A solution with vigorous agitation. Use of the bromine-methanol solution reduces the amount of by-products compared to the use of liquid bromine feed to a methanol-bisphenol-A solution. The process is readily adapted to large scale equipment by circulating the reaction mixture from the reaction vessel through an external closed loop which includes an impingement mixer. The bromine-methanol feed is pumped at the proper rate and ratio into the impingement mixture whereby it impinges with the circulating reaction mixture. The resultant bromination mixture is then returned to the reaction vessel.

Abstract: This invention relates to a method for preparing a white or at least near-white product which is predominant in alkylene(C.sub.1 -C.sub.5)-bis-(tetrabromophthalimide). This method comprises: forming a solution which contains, as a solvent, (i) SO.sub.3 or fuming sulfuric acid, and (ii) a haloalkane of the formula RX.sub.n, wherein R is an alkyl group containing up to two carbon atoms, X is a halogen selected independently from Br and Cl, and n is 2 or 3 when R is an alkyl containing 1 carbon atom and is 1, 2 or 3 when R is an alkyl group containing 2 carbon atoms, and, as a solute, the yellow alkylene(C.sub.1 -C.sub.5)-bis-tetrabromophthalimide predominant product obtained from the reaction of tetrabromophthalic anhydride and diaminoalkane is the presence of water and alkanoic acid; and adding water to said solution to precipitate therefrom the white or at least near-white product.

Abstract: An upper sash of a frame window or door assembly which is provided with projections extending below the lower rail of the upper sash, wherein the projections engage and cooperate with a notch found on the flange of the jamb of the frame assembly in a manner so as to support and restrict movement of the upper sash.

Abstract: A modification for window or door assemblies having interlocks on the sash rails where insulating material is placed between the interlock of a lower rail to an upper sash and the interlock of an upper rail to a lower sash so as to act as a thermal barrier against heat conduction through the upper sash which is exposed to exterior climate of the building in which the window or door assembly is being used.

Abstract: This invention relates to a thermoplastic formulation having a first part comprising, (i) nylon 6,6 nylon 6 or a mixture thereof and (ii) a halogenated polyphenylene ether flame retardant, and a second part, in admixture with the first part, comprising a Diels-Alder adduct having the formulaA--R--(A).sub.nwherein n is 0, 1 or 2 and A is a polyhalogenated cycloalkylene or cycloalkyl group and R is as defined herein.

Abstract: A flame retardant polypropylene based formulation which contains polypropylene and a flame retardant amount of decabromodiphenyl oxide and a halogenated bisimide.

Abstract: This invention relates to a knotting device which comprises a handle portion which carries an elongated member and an elongated needle member. The elongated member and the elongated needle member are associated with one another by a linking member so that they can move from a first position to a second position. The elongated needle member is used to initially engage the knot and obtain an initial tightening thereof. The elongated member is used to finally tighten the knot after the elongated needle member has been removed from the knot as the elongated member moves to the second position.

Abstract: The process comprises: (a) initiating a feed of molten diphenyl oxide to a substantially anhydrous mixture of methylene dibromide solvent, elemental bromine (Br.sub.2) and an aluminum trihalide catalyst at a temperature between about 10.degree. and about 30.degree. C.; (b) heating the reaction mixture to about 50.degree.-60.degree. C., and while maintaining the temperature at about 50.degree.-60.degree. C., continuing the feed of molten diphenyl oxide until the total amount fed is equivalent to (i) about 0.064 to about 0.077 mole per mole of elemental bromine (Br.sub.2) employed in the reaction, and (ii) about 0.2 to about 10 parts by weight per part by weight of methylene dibromide employed in the reaction; (c) steam distilling the methylene dibromide solvent and the residual bromine from the reaction mixture; (d) recovering decabromodiphenyl oxide from the distilland; and (e) drying the methylene dibromide and bromine distillate to render them suitable for reuse in the process.