Abstract: An extremely pure oxide containing two or more metals, homogeneous at the atomic level, is prepared by (1) reacting in water, soluble salts of two or more metals with quaternary ammonium carbonate; the metals being those that form water-insoluble carbonates, thereby to precipitate mixed carbonates of the metals; (2) recovering and drying the precipitate; (3) calcining the precipitate to provide an oxide of mixed metals homogeneous at the atomic level and substantially free from extraneous contaminants. The calcined oxide can be shaped and compressed as greenware and sintered to form useful ceramic products.

Abstract: Improved process for making Tl-Ca-Ba-CuO superconductors. A solution of the monocarboxylates (e.g., acetates) of Ca, Ba, and Cu is dried, calcined, mixed with Tl.sub.2 O.sub.3, and the mixture is heated to make a superconductor. The method minimizes introduction of contaminants. Novel compositions result.

Abstract: Improved process for making Tl-Ca-Ba-Cu oxide superconductors. A solution of the nitrated of Ca, Ba, and Cu is reacted with a quaternary ammonium carbonate in a slurry (heel) of Tl.sub.2 O.sub.3. Carbonates of Ca, Ba, and Cu precipitate homogeneously on the Tl.sub.2 O.sub.3 particles. Solids are recovered, dried, and heated to make a superconductor. The method minimizes introdution of contaminants. Novel compositions result.

Abstract: An FCC catalyst is made with a zeolite Beta which contains from about 0.1 to 15 wt % based on the weight of the zeolite Beta of gallium, zinc or mixtures thereof. The catalyst substantially increases the aromatic content of the gasoline compared to just using a catalyst of zeolite Beta. The catalyst can also be made with an inorganic oxide binder for the metal modified zeolite Beta and other catalytically active zeolite components.

Abstract: There has been provided a catalytically active insert assembly for insertion in an exhaust pipe and characterized by a metal support having at least one layer of a catalytically active thin metal foil applied to and secured to the surface or surfaces thereof. The foil may be corrugated or not. The assemblies hereof are inexpensive to manufacture, easy to install, and are effective to reduce pollutants contained in exhaust gas to environmentally acceptable levels.

Abstract: A catalyst suitable for use as a three-way catalyst having low H.sub.2 S emissions for emission control and with substantially no ceria present is made with a refractory oxide particle or powder support having deposited thereon about 0.5-20% by weight of a non-rate earth oxide stabilizer, at least 0.5 to about 5% by weight of an alkali metal oxide as a promoter, and a catalytically-effective amount of one or more platinum group metals. The preferred refractory oxide is alumina and the non-rare earth oxide stabilizer can be an oxide such as ZrO.sub.2, MgO, CaO, SnO, CaO, Y.sub.2 O.sub.3, TiO.sub.2, ZnO, B.sub.2 O.sub.3, P.sub.2 O.sub.5, SnO.sub.2, Bi.sub.2 O.sub.3, or SiO.sub.2 with the preferred oxide being zirconia.

Abstract: There is provided an improved electrically heated accordion folded corrugated thin metal catalytic converter for hydrocarbon or alcohol fueled engine exhaust, particularly internal combustion engine exhaust, having a simplified construction and characterized in that the entire corrugated thin metal monolith, or monoliths, serves as a resistance heater to bring the catalyst up to optimum operating temperature quickly and thereby reduce the escape of pollutants into the atmosphere upon start-up, and which does not depend upon conduction as a mdoe of heat transfer to achieve such temperature.

Abstract: Catalysts for the selective catalytic reduction of NOx by ammonia are made from porous formed supports having a certain fraction of the pores with pore diameters larger than 600 Angstrom units. Thus macropores can be introduced in a formed TiO.sub.2 support by adding burnout materials or some inorganic oxide prior to forming the titania into the formed support. Alternatively, titania is precipitated onto a porous inorganic oxide such as SiO.sub.2, Al.sub.2 O.sub.3, ZrO.sub.2, AlPO.sub.4, Fe.sub.2 O.sub.3 and B.sub.2 O.sub.3 to form the support. Then conventional DeNOx catalytic metals are added. The support can be made by first impregnating the inorganic oxide particles with titania via a soluble precursor, forming titania and then shaping the coated particles into the desired shape such as a monolith. In a second embodiment, the inorganic oxide particles are first formed into the desired shape and then impregnated with the titania forming material.

Abstract: PbO-B.sub.2 O.sub.3 -Ag.sub.2 O glasses having a preferred weight ratio range of 76-88:10-15:2-10 have glass transistion temperatures of less than 300.degree. C. and are especially useful for adhering together ceramic substrates such as for attaching integrated circuits to ceramic substrates. The glasses can be formulated with Ag particulates and organics and applied as pastes to provide conductive adhesives.

Abstract: An extruded and sintered Al.sub.2 O.sub.3 body having high flexural strength is produced by extruding and sintering and extrusion mixture of alpha-Al.sub.2 O.sub.3 powder, an organic dispersing agent, an optional deaeration agent, and a zirconia sol. The zirconia sol is present in a small amount such that upon firing the final ZrO.sub.2 content of the final body is less than 1 weight percent. The sintered alumina body has a uniform distribution of ZrO.sub.2 particles in the size range of 0.1-1.0 microns.

Abstract: A converter for treating gases to remove pollutants or particulate matter having layers of normally nesting corrugated thin metal foil, with or without a catalyst supported thereon, and characterized by spaced strands of wire or nonvitreous inorganic ceramic thread interposed between the layers to maintain them in spaced relation for the passage of gas, e.g., exhaust gas from an engine or plant, therethrough. The principal advantages are the relatively high particulate trap efficiency, the relatively low back pressure, and the low cost of manufacture.

Abstract: Catalysts for the selective catalytic reduction of NOx by ammonia are made from porous formed supports having a certain fraction of the pores with pore diameters larger than 600 Angstrom units. Thus macropores can be introduced in a formed TiO.sub.2 support by adding burnout materials or some inorganic oxide prior to forming the titania into the formed support. Alternatively, titania is precipitated onto a porous inorganic oxide such as SiO.sub.2, Al.sub.2 O.sub.3, ZrO.sub.2, AlPO.sub.4, Fe.sub.2 O.sub.3 and B.sub.2 O.sub.3 to form the support. Then conventional DeNOx catalytic metals are added. The support can be made by first impregnating the inorganic oxide particles with titania via a soluble precursor, forming titania and then shaping the coated particles into the desired shape such as a monolith. In a second embodiment, the inorganic oxide particles are first formed into the desired shape and then impregnated with the titania forming material.

Abstract: A ceramic composite valve for an internal combustion engine or the like is disclosed. The valve includes (a) an elongated valve stem shaped for insertion in the valve guide of an engine and comprising a ceramic sleeving which is packed with an axially aligned unidirectional cluster of ceramic reinforcing fibers; and (b) a ceramic bell shaped for mating with the valve seat of an engine and containing discontinuous ceramic fibers; one end of said sleeving being molded into the bell to form a valve-shaped structure; and said valve shaped structure being impregnated and rigidized with a matrix of carbon, other ceramic material, or both carbon and other ceramic material, and coated with a hard ceramic coating which is resistant to oxidation and wear. Also disclosed are various preform valves, and a method of making ceramic valves and preform valves.

Abstract: There is provided a novel core member for use in a catalytic converter characterized by a corrugated nonnesting thin metal foil having a given length and a given width, which strip is overfolded to provide portions of about equal length. Along the fold line is attached a wire or rod, as, for example, by welding. The wire containing ends are gathered and secured to form a central core. This core may by spirally wound to fit within a peripheral housing, and the free ends of the core members secured to the housing, as by welding. This assembly may be used in a catalytic converter and may be equipped to be electrically heated from a battery using the resistance of the corrugated thin metal strip portions to effect heating thereof.

Abstract: Dense ceramic sheets suitable for electronic substrates are prepared by hot pressing ceramic green sheets containing ceramic powder and organic binders which leave no undesirable residue upon pyrolysis in the absence of oxygen. Boron nitride sheets made of boron nitride powder in a similar binder are placed on each side of the ceramic green sheet to form a composite. After hot pressing the composite so as to remove the binder and densify the ceramic, the BN layers are removed.

Abstract: There is provided a relatively large unitized monolithic catalyst panel especially adapted for use in the exhaust lines or conduits of stationary power plants to remove pollutants from the exhaust, especially those using hydrocarbon fuels as a source of power. The panels are characterized by top, bottom and side frame plates in rectangular relation, front and rear stiffener bars extending between the top and bottom plates, separator plates at intervals and in parallel relation extending between the side frame plates to define a grid, and corrugated thin metal foil layers disposed within and filling the spaces within the frame, which foil has a catalytically active surface formed thereon. These devices are useful in removing such pollutants as NO.sub.X from exhaust gas streams.

Abstract: A catalyst, which is capable of controlling not only HC, CO and NO.sub.x, but also H.sub.2 S emission from the tail pipe of catalytic converter automobiles, is made of platinum-group metals promoted by rare earth oxides and containing a metal ferrite. The ferrite is present in an H.sub.2 S gettering amount and in an amount up to about 20 weight % of the catalyst. The catalyst comprises an alumina support and is applied as a washcoat to a substrate, such as a honeycomb monolith made from ceramic or metal.

Abstract: A catalyst support is made with a bidisperse micropore size distribution. One region has small micropores with an average pore diameter of less than 100 Angstrom units. The other region has large micropores with an average pore diameter which is between 100 and 600 Angstrom units. By adding catalytic metals for desulfurization and demetallation, a hydrotreating catalyst is made which is able to treat heavy feeds containing large metal bearing molecules. In a preferred embodiment the desulfurization metals are placed in the small micropores and the demetallation metals are placed in the larger micropores.

Abstract: PbO-B.sub.2 O.sub.3 -Ag.sub.2 O glasses having a preferred weight ratio range of 76-88:10-15:2-10 have glass transition temperatures of less than 300.degree. C. and are especially useful for adhering together ceramic substrates such as for attaching integrated circuits to ceramic substrates. The glasses can be formulated with Ag particulates and organics and applied as pastes to provide conductive adhesives.

Abstract: Porous ceramic greenware comprising finely divided ceramic filler, finely divided metal, and polyolefin controls shrinkage in fired shape. In a preferred embodiment the metal and ceramic filler are bound together with the clean burning polyolefin and a plasticizer. After molding the mixture into the final shape, the plasticizer is removed to introduce porosity into the shaped article. Next the article is heated to decompose the polyolefin which can exit as a gas through the pore openings. Finally, the article is fired to a high temperature to oxidize the metal to metal oxide which becomes sintered with the ceramic filler particles to form a sintered porous article where the oxidized metal bonds the filler particles together in the desired shape.