Abstract: Disclosed is an improved method of making chlorine and alkali metal hydroxide, e.g., sodium hydroxide, in an electrolytic cell of the type wherein a liquid permeable diaphragm separates the anolyte from the catholyte, said method comprising adding to the anolyte, while the cell is operating, a hydrated aluminum silicate containing clay mineral, followed by lowering the pH of the anolyte by the addition of an inorganic acid and maintaining the anolyte at said lowered pH for a time sufficient to restore the cell to a predetermined current efficiency.
Type:
Grant
Filed:
February 25, 1992
Date of Patent:
October 22, 1996
Assignee:
PPG Industries, Inc.
Inventors:
Donald W. DuBois, Bernard A. Maloney, Stanley R. Pickens
Abstract: A refractory composition, particularly for application as a dry vibratable refractory for forming the wearable, disposable monolithic lining coating the permanent lining of a tundish or ladle used in molten metal casting processes is disclosed. The composition contains a refractory aggregate, a first bonding agent actuatable at temperatures in the range of from about 300.degree. F. to about 1000.degree. F. to cause the formation of interparticle bonds between aggregate particles, at least one second bonding agent actuatable at temperatures in the range of from about 1000.degree. F. to about 2500.degree. F. to cause further formation of interparticle bonds between aggregate particles, and, optionally, clay. The use of both first and second bonding agents enables installation of the refractory in hot practice, in which vessel preheat temperatures of up to about 2500.degree. F. are utilized.
Type:
Grant
Filed:
May 4, 1992
Date of Patent:
February 8, 1994
Assignee:
Minteq International Inc.
Inventors:
John Damiano, Julie A. Dody (nee Hebron), Wilfred A. Martinez
Abstract: Disclosed is a soil release composition for application to or finishing on polyester textile that is heat set at a temperature of 375.degree. F. (191.degree. C.) or higher, said composition comprising a non fiber forming polyester-polyether copolymer and an antioxidantly effective amount of the butylated reaction product of dicyclopentadiene with p-cresol.
Abstract: This invention relates to high solids content aqueous calcium stearate dispersions useful as lubricating agents in paper and paperboard coating compositions.
Abstract: A liquid permeable diaphragm for use in an electrolytic chlor-alkali cell, the diaphragm being made of fibrous material and having particulate zirconia deposited in the interstices of the fibrous matrix, prior to installing the diaphragm in the cell. Also described is a zirconia impregnated fibrous diaphragm having a zirconia topcoating applied to the anode face thereof.
Abstract: A liquid permeable diaphragm for use in an electrolytic chlor-akali cell, the diaphragm being made of fibrous material and having deposited thereon and cementitiously bonded to the anode face thereof at least one topcoating of inorganic, particulate, refractory material. The interstices of the fibrous matrix of the diaphragm may also have particulate zirconia deposited therein.
Abstract: Disclosed are compositions comprising the reaction product of maleic anhydride and at least one alkenylsuccinic anhydride. These compositions when hydrolyzed and neutralized are useful in not only imparting corrosion resistance to ferrous metal surfaces in contact with aqueous systems but also retard or prevent precipitation of alkaline earth salts of organic acids from the aqueous system.
Type:
Grant
Filed:
December 13, 1991
Date of Patent:
January 5, 1993
Assignee:
PPG Industries, Inc.
Inventors:
Hyung H. Kang, David B. Markobrad, Eugene A. Weipert
Abstract: Disclosed is a process for preparing surface modified silica sorption agent suitable for purifying contaminated aqueous liquid, the sorption agent comprising amorphous, precipitated, silica having surface deposited thereon an organic quaternary ammonium compound.
Type:
Grant
Filed:
May 9, 1991
Date of Patent:
August 11, 1992
Assignee:
PPG Industries, Inc.
Inventors:
Frederick F. Guzik, Suresh B. Damle, William W. Carlin
Abstract: Disclosed is a binder insolubilizer for use in binder-containing paper coating compositions, the insolubilizer consisting essentially of an aqueous formulation containing at least about 15 weight percent of titratable glyoxal and at least one polyhydroxy compound.
Abstract: The present invention relates to a method of removing ink from secondary fiber by contacting a pulp of said secondary fiber with an aqueous medium in the presence of a polymeric material having a glass transition temperature in the range of from about 20.degree. C. to about 70.degree. C. and a substituted polyethylene oxide to agglomerate the ink into discrete masses and separating the agglomerated ink from the pulp-containing aqueous medium.
Abstract: Disclosed is a process for preparing aminofunctional silicone fluids substantially free of alkoxy groups by equilibrating a partially hydrolyzed aminofunctional dialkoxy or trialkoxy silane with a trialkylsiloxy terminated poly(dialkylsiloxane) followed by equilibration with a silanol terminated poly(dialkylsiloxane).
Abstract: Disclosed are compositions useful as surface coatings for nonwoven substrates which compositions are reaction products of a melamine formaldehyde compound, long chain saturated alcohols and long chain saturated or unsaturated polyethoxylated alcohols. The invention compositions when used to surface size paper impart oil, water and polar solvent resistance thereto. The compositions may be used alone or as substantial replacements for anionic or non-ionic fluorocarbon based surface sizes that are typically used to impart oil resistance to paper.
Type:
Grant
Filed:
November 14, 1988
Date of Patent:
October 22, 1991
Assignee:
PPG Industries, Inc.
Inventors:
William W. Carlin, Sai H. Hui, John D. Mansell
Abstract: Disclosed are cationic aqueous emulsions containing (a) sizing composition comprising the reaction product of melamine formaldehyde compound, long chain saturated alcohol and long chain saturated or unsaturated polyethoxylated alcohol; and (b) cationic surfactant. The emulsions when used to surface size paper impart improved oil, water and polar solvent resistance thereto. The emulsions may be used alone or as substantial replacements for anionic or non-ionic fluorocarbon based emulsions that are typically used to impart oil resistance to paper.
Abstract: This invention relates to a method of making thermoplastic polymeric fibrils by passing an aqueous suspension of powdered thermoplastic polymeric material at high pressure through a two-stage valve assembly of the type conventionally used in liquid homogenization.
Type:
Grant
Filed:
March 7, 1990
Date of Patent:
July 9, 1991
Assignee:
PPG Industries, Inc.
Inventors:
Stanley R. Pickens, Donald W. DuBois, Hou-Ching M. Yang
Abstract: Disclosed is a method for selectively separating 2-nitrosophenol from an isomeric mixture containing 2-nitrosophenol and 4-nitrosophenol by contacting the mixture with an organic solvent so as to preferentially dissolve the 2-nitrosophenol from the mixture.
Abstract: This invention relates to urea-free high solids content aqueous calcium stearate dispersions useful as lubricating agents in paper and paperboard coating compositions.
Abstract: The combined sensor with a thermostatted heating device (7, 23) for the simultaneous and continuous transcutaneous measurement of oxygen (O.sub.2) and of carbon dioxide (CO.sub.2) in the blood contains a measuring device (1) for the partial pressure of CO.sub.2 (pCO.sub.2), in which there is pure optical/spectrometric operation or which operates on the principle of pH measurement in a electrolyte (8), and which is separated from the measuring site on the skin by a membrane (13) which is permeable to both CO.sub.2 and light, and contains another measuring device (24, 25, 26) for the spectrometric measurement of the blood oxygen saturation (sO.sub.2). The advantage over a known pO.sub.2 /pCO.sub.2 combined sensor is that the combined sensor according to the invention can be operated at a low operating temperature of, for example, 42.degree. C.
Abstract: An electrolyte permeable asbestos diaphragm is prepared by depositing asbestos and a particulate thermoplastic polymeric material from an aqueous slurry including alkali metal hydroxide onto a porous substrate, and heating the deposited asbestos, particulate thermoplastic polymeric material, and alkali metal hydroxide for a period of time, e.g., at least 2 hours, and at temperatures sufficient to react the asbestos and alkali metal hydroxide but temperatures insufficient to melt or sinter the particulate thermoplastic polymeric material, whereby the particulate thermoplastic polymeric material functions to provide permeability for the diaphragm.
Abstract: An electrolyte permeable diaphragm consisting essentially of asbestos is prepared by depositing asbestos and a porosity control agent selected from the group of cellulosic-type materials, e.g., starch, cellulose or rayon, infusible thermoset polymer materials, e.g., phenol-formaldehyde resin, urea-formaldehyde resin or melamine-formaldehyde resin, and inorganic materials, e.g., fiberglass, graphite, titania, silica, talc, vermiculite or potassium-containing mica from an aqueous slurry including alkali metal hydroxide onto a porous substrate, the porosity control agent being substantially stable and insoluble in the aqueous alkali metal hydroxide-containing slurry, followed by heating the deposited asbestos, porosity control agent and alkali metal hydroxide at temperatures between about 110.degree. C. and 280.degree. C. for a period of time sufficient to react the asbestos and alkali metal hydroxide whereby the porosity control agent provides the permeability for the diaphragm.
Abstract: The combined sensor with a thermostatted heating device (7, 23) for the simultaneous and continuous transcutaneous measurement of oxygen (O.sub.2) and of carbon dioxide (CO.sub.2) in the blood contains a measuring device (1) for the partial pressure of CO.sub.2 (pCO.sub.2), in which there is pure optical/spectrometric operation or which operates on the principle of pH measurement in an electrolyte (8), and which is separated from the measuring site on the skin by a membrane (13) which is permeable to both CO.sub.2 and light, and contains another measuring device (24, 25, 26) for the spectrometric measurement of the blood oxygen saturation (sO.sub.2). The advantage over a known pO.sub.2 /pCO.sub.2 combined sensor is that the combined sensor according to the invention can be operated at a low operating temperature of, for example, 42.degree. C.