Patents Represented by Attorney Edwin M. Szala
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Patent number: 5464564Abstract: Power surge resistor pastes comprising palladium/silver, glass and dopant(s) are described for use in the manufacture of power surge resistor devices employed for power surge protection applications. The resultant surge resistors are characterized in their ability to dissipate repeated voltage surges equal in voltage and duration to surges created by lightning with less than 0.05% change in sheet resistance.Type: GrantFiled: May 17, 1994Date of Patent: November 7, 1995Assignee: National Starch and Chemical Investment Holding CorporationInventor: Orville W. Brown
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Patent number: 5455299Abstract: Aqueous liquid for primers are prepared from a copolymer consisting essentially of the following components (A), (B) and (C) in aqueous medium where (A) is a cationic monomer represented by the following general formula (1) ##STR1## wherein Y is organic or inorganic monovalent anion; m is an integer 0 to 3 and n is an integer 1 to 3;(B) is an alkoxysilane monomer represented as the following general formula (2) ##STR2## (C) is an ethylenic unsaturated monomer, and wherein a structural unit derived from the (A) component accounts for not less than 5% of the copolymer, a structural unit derived from the (B) component accounts for not less than 0.5% by weight of the copolymer and a structural unit derived from the (C) component accounts for not more than 94.5% by weight of the copolymer.Type: GrantFiled: February 17, 1994Date of Patent: October 3, 1995Assignee: National Starch and Chemical Investment Holding CorporationInventor: Masao Maegawa
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Patent number: 5411789Abstract: A composition is disclosed which forms a bend sensor when coated on a flexible substrate. A bend sensor prepared from the composition is also disclosed. The composition contains a brittle binder which cracks under a stress, electrically conductive elements and a graphite additive which stabilizes the degree of cracking. The composition forms a bend sensor which upon a change in degree of flexing produces an electrical signal in the form of a change in resistance in circuits which include the sensor.Type: GrantFiled: February 26, 1992Date of Patent: May 2, 1995Assignee: National Starch and Chemical Investment Holding CorporationInventor: Keith J. Margolin
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Patent number: 5399617Abstract: Copolymerizable amphoteric surfactants of the structural formula ##STR1## in which R.sub.1 =C.sub.1 -C.sub.2 alkyl, R.sub.2 =C.sub.1 -C.sub.2 alkyl, X.sup.- =SO.sub.3.sup.- or COO.sup.-, a=2-3, and b=1-6, are polymerized into copolymer latexes for use in paint formulations, in an amount of 1-3 parts per hundred parts by weight of monomers used to form the copolymer, to impart superior wet adhesion and freeze-thaw stability to the latex paints. The copolymer latexes contain no more than one part by weight carboxylic acid functionality per hundred part monomers. The monomers with which the amphoteric surfactants are copolymerized are selected from alkyl esters of acrylic and methacrylic acid, acrylic and methacrylic acid, styrene and mixtures thereof.Type: GrantFiled: March 7, 1994Date of Patent: March 21, 1995Assignee: National Starch and Chemical Investment Holding CorporationInventors: Rajeev Farwaha, William Currie
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Patent number: 5345212Abstract: Power surge resistor containing palladium/silver, glass and dopant(s) are described for use in the manufacture of power surge resistor devices employed for power surge protection applications. The resultant surge resistors are characterized in their ability to dissipate repeated voltage surges equal in voltage and duration to surges created by lightning with less than 0.05% change in sheet resistance.Type: GrantFiled: July 7, 1993Date of Patent: September 6, 1994Assignee: National Starch and Chemical Investment Holding CorporationInventor: Orville W. Brown
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Patent number: 5308907Abstract: Electrical power cables and sealants used in their manufacture are described. The pumpable sealants are manufactured with a smoke suppressant composition comprising a combination of alumina trihydrate ATH and magnesium hydroxide.Type: GrantFiled: October 6, 1992Date of Patent: May 3, 1994Assignee: National Starch and Chemical Investment Holding CorporationInventors: Leonard Leibowitz, Robert A. Nosal
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Patent number: 5258477Abstract: Various novel acetal- and aldehyde-containing monomers are prepared. They can be polymerized and copolymerized by conventional polymerization techniques. The polymers contain repeating units derived from one or more ethylenically or allylically unsaturated monomers containing an acetal group or aldehyde group and optionally one or more repeating units derived from ethylenically or allylically unsaturated monomers other than the acetal-containing or aldehyde-containing monomer such as ethylene, vinyl acetate, ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, hydroxyethyl acrylate, hydroxypropyl acrylate, methyl methacrylate or acrylic acid. Aqueous emulsions of polymers containing the acetal-containing monomers and a hydroxy-containing monomer are useful as binders for nonwoven fabrics.Type: GrantFiled: October 16, 1990Date of Patent: November 2, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: John J. Tsai, Patrick G. Jobe, Robert L. Billmers, Rama S. Chandran, Paul R. Mudge, Michael T. Sarkis
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Patent number: 5252663Abstract: Formaldehyde free crosslinking emulsion polymers are prepared by the addition of N-(2,2-dialkoxy-1-hydroxy)ethyl acrylamide to a vinyl ester based polymer. The resultant emulsions can be used as binders for nonwovens or fiberfill or as woodworking adhesives.Type: GrantFiled: May 22, 1991Date of Patent: October 12, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: Rama S. Chandran, Carmine P. Iovine, Paul R. Mudge, John C. Leighton, Malcolm F. Hallam, Pravin K. Kukkala
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Patent number: 5250659Abstract: Polyester resins, comprising the polymerized residues of dibasic acids and diols, dibasic anhydrides and diols, and the lower alkyl esters of dibasic acids and diols, are soluble up to 40% by weight of solids in 1,3-dioxacyclopentane, and blends of 1,3-dioxacyclopentane with other relatively nontoxic solvents.Type: GrantFiled: May 8, 1992Date of Patent: October 5, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: Linwood E. Bradford, Patricia Flannagan, Ronald J. Caimi
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Patent number: 5250227Abstract: A composition is disclosed which forms a bend sensor when coated on a flexible substrate. A bend sensor prepared from the composition is also disclosed. The composition contains a brittle binder which cracks under a stress, electrically conductive elements and a graphite additive which stabilizes the degree of cracking. The composition forms a bend sensor which upon a change in degree of flexing produces an electrical signal in the form of a change in resistance in circuits which include the sensor.Type: GrantFiled: May 3, 1990Date of Patent: October 5, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventor: Keith J. Margolin
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Patent number: 5247066Abstract: A crosslinking additive for imparting water resistance to starch-based alkaline corrugating adhesive compositions is prepared by reacting acetone and formaldehyde under aqueous alkaline conditions at 20.degree.-80.degree. C. in a molar ratio of from 2 to 5 moles of formaldehyde per mole of acetone. The condensate is thereafter treated with from 1.0 to 2.0 moles of hydrogen peroxide per mole of unreacted formaldehyde which oxidizes the residual formaldehyde to formic acid. The treated crosslinking additive will contain less than 0.4% unreacted formaldehyde and may be added directly to a starch-based corrugating adhesive.Type: GrantFiled: August 29, 1991Date of Patent: September 21, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: Jules E. Schoenberg, Michael Foran
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Patent number: 5240982Abstract: Amphoteric surfactants and copolymerizable amphoteric surfactants for use in latex paints are presented. These surfactants, which contain positively charged nitrogen, are incorporated into the paint formulations at low levels and impart superior wet adhesion and freeze-thaw stability.Type: GrantFiled: August 19, 1991Date of Patent: August 31, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: Rajeev Farwaha, William Currie
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Patent number: 5239008Abstract: A process for the emulsion polymerization of graft copolymers comprising the steps of: a) obtaining an unsaturated polymer containing terminal or pendant polymerizable functionalities; b) dissolving the resultant unsaturated polymer in an ethylenically unsaturated monomer in the presence of a surfactant in water to form an aqueous phase; c) microfluidizing the aqueous phase of (b) to a size of less than 0.5 u; and d) subsequently graft polymerizing a monomer with the unsaturated polymer in the microfluidized aqueous phase using free radical polymerization techniques; such that the graft polymerization reaction occurs within each micelle thereby resulting in uniform particles of the predetermined particle size.Type: GrantFiled: June 28, 1991Date of Patent: August 24, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: Paul R. Mudge, Sirisoma Wanigatunga
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Patent number: 5236977Abstract: Corrugating adhesive compositions comprising soluble high amylose starch as the carrier starch may be prepared as a one-piece, dry mixture that can be dispersed in water at 25.degree. to 55.degree. C. and applied to paperboard without further preparation steps. The corrugating adhesives may be prepared without alkali, and used at any pH.Type: GrantFiled: September 20, 1991Date of Patent: August 17, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: James Eden, James Kasica, Craig Leake, Norman Lacourse, Paul Altieri
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Patent number: 5237083Abstract: An aqueous glass fiber sizing composition acetate file former and an effective amount of a lubricant additive having the formula: ##STR1## where R is an alkyl or alkenyl group of 6 to 20 carbons, A is a divalent organic--S--or--NH--group, R.sup.1 is an alkyl group of 1 to 4 carbons, m is or 1 and n is 0 to 10 with the proviso that when n is O, m is also O.Type: GrantFiled: March 5, 1992Date of Patent: August 17, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: Gary T. Martino, Michael J. Hasuly, John J. Tsai
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Patent number: 5227481Abstract: Cationic polysaccharide derivatives are prepared by reacting a polysaccharide with a polycationic reagent having one polysaccharide reactive group and at least two cationic groups. Suitable reagents include polycationic alkyl, aryl, alkaryl, cycloaliphatic, or heterocyclic amines, some of which are novel compositions. The polycationic polysaccharide derivatives prepared from these reagents are useful in the manufacture of paper.Type: GrantFiled: April 9, 1991Date of Patent: July 13, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: John J. Tsai, Peter T. Trzasko, Michael T. Philbin, Robert L. Billmers, Martin M. Tessler, Joseph A. Van Gompel, Morton W. Rutenberg
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Patent number: 5219924Abstract: An improved process for the production of paper coating binders wherein ethylene, vinyl ester and optional comonomers are polymerized using batch emulsion polymerization techniques and wherein the improvement comprises subjecting the emulsion to microfluidization to produce a particle size of less than about 0.5 microns prior to the emulsion polymerization step.Type: GrantFiled: June 28, 1991Date of Patent: June 15, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventor: Yen-Jer Shih
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Patent number: 5217798Abstract: Nonwoven assemblies bonded with water dispersible or sensitive hot melt adhesives comprising 50-100 parts of a graft copolymer of about 40-85% of at least one vinyl monomer and about 15-60% of at least one water soluble polyalkylene oxide polymer, and about 0-50 parts by weight of tackifying resin. The compositions may also be employed as water sensitive binders in the manufacture of the nonwoven. Vinyl acetate is the preferred vinyl monomer whereas ethylene oxide homo- or copolymers are the preferred polyalkylene oxide. The use of tackifying resin is optional and may be undesirable for many of the applications.Type: GrantFiled: May 7, 1991Date of Patent: June 8, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: Francis Brady, Gary Raykovitz, Paul Puletti, Thomas Kauffman, Jules Schoenberg
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Patent number: 5213866Abstract: Carpet and textile coating compositions are formulated to include fiber or flock pieces so as to improve the tuft pull strength and dimensional stability of the carpet or textile. The coating compositions comprise 10 to 70%, by weight, of a latex binder and 30 to 90%, by weight, of at least one filler, wherein the filler comprises about 0.001 to 100%, by weight, of fiber or flock pieces. Any natural or synthetic fiber may be used in the coating compositions of this invention.Type: GrantFiled: October 21, 1992Date of Patent: May 25, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: Ronald L. Swope, Cheri L. McConnell, Larry S. Fulton
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Patent number: 5204399Abstract: This is a thermally conductive adhesive having excellent die shear strength, in film form, and having a weight average molecular weight of about 100,000 to 150,000, prepared from a mixture of a dietherdianhydride, a meta-substituted benzenediamine, a polysiloanediamine, and a thermally conductive filler, that is suitable as a die attach adhesive: it bonds rapidly without the need for curing or baking off-line; does not produce excess stress on the die; requires no refrigeration; provides uniform bond line thickness between the die and paddle; can be used at temperatures that do not oxidize copper lead frames or produce excessive thermal stress; can be reworked; and can exert adequate adhesion during the processes of wire bonding and molding.Type: GrantFiled: August 9, 1991Date of Patent: April 20, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventor: Robert Edelman