Abstract: A process for the preparation of 2-carboalkoxy-1-indanones of Formula I from 1-indanones of Formula II using a dialkyl carbonate and an alkali metal alkoxide is provided. This process is superior to the prior art in that it avoids pyrophoric reagents such as sodium hydride, and proceeds in high chemical yield and product quality. The invention provides a novel process to an important intermediate in the preparation of arthropodicidal carboxanilides of commercial interest. ##STR1## wherein: R.sup.1, R.sup.2 and M are defined in the specification.
Type:
Grant
Filed:
April 28, 1997
Date of Patent:
January 6, 1998
Assignee:
E. I. du Pont de Nemours and Company
Inventors:
Donald Joseph Dumas, William Christopher Hollinsed