Patents Represented by Attorney Elwood Haynes
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Patent number: 8167977Abstract: A method of purifying a gaseous mixture rich in hydrogen and in carbon monoxide, commonly termed an H2/CO mixture or syngas, by adsorption prior to treating it cryogenically with a view to producing a CO-rich fraction, and/or one or more H2/CO mixtures of determined content, such as a mixture of 50 mol % H2/50 mol % CO and generally a hydrogen-rich fraction is provided.Type: GrantFiled: January 10, 2008Date of Patent: May 1, 2012Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Christian Monereau, Guillaume Rodrigues, Ingrid Bellec, François Demoisy
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Patent number: 7632453Abstract: The invention relates to a gas quenching method of the type that makes use of (i) a quenching cell (V1) which is intended to receive objects to be quenched with a quenching gas and (ii) a buffer capacity (V2) which is designed to contain the quenching gas.Type: GrantFiled: August 10, 2004Date of Patent: December 15, 2009Assignee: L'Air Liquide-Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Florent Chaffotte, Nicolas Blanchard, Olivier Delobel, Linda Lefevre
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Patent number: 7617701Abstract: In a process for producing a mixture containing at least 10% carbon monoxide (73) by cryogenic separation of a feed gas containing at least carbon monoxide, hydrogen and methane, the feed gas (1) is separated to produce a first gas enriched in hydrogen (71), the feed gas is scrubbed in a methane wash column (7), a carbon monoxide enriched stream (13) from the bottom of the methane wash column is separated (19) to produce a stream further enriched in carbon monoxide (23), the stream further enriched in carbon monoxide is separated to form a carbon monoxide rich stream (31,49) and a liquid methane stream (27), at least part (72) of the carbon monoxide rich stream is mixed with the first gas enriched in hydrogen to form the mixture containing at least 10% carbon monoxide as a product stream.Type: GrantFiled: April 7, 2004Date of Patent: November 17, 2009Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean Billy, Natacha Haik-Beraud, Jean Gallarda, Franck Wegrzyn
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Patent number: 7588742Abstract: The invention relates to a method for purifying a gas flow containing hydrogen (H2) and carbon monoxide (CO), in addition to at least one nitrogen oxide (NOx), as impurities. According to said method, the gaseous flow is brought into contact with at least one catalyst containing copper and/or palladium, at a temperature between 100 DEG C. and 200 DEG C., in such a way as to eliminate at least part of the nitrogen oxide.Type: GrantFiled: June 10, 2004Date of Patent: September 15, 2009Assignee: L'Air Liquide, Societe Anonyme a Directorie et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Natacha Haik-Beraud, Serge Moreau, François Jantet, Audrey Moulin
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Patent number: 7565806Abstract: According to the inventive method, incoming air enters (via 16) the separation unit (14); at least one fraction of said incoming air is supplied from the gas turbine (2), and at least one gas flow (via 20,24), which is enriched with nitrogen, is extracted from the separation unit (16); heat exchange occurs in a first exchanger (56) between the fraction of incoming air from the gas turbine (2) and a liquid fraction (58) to be heated in order to obtain a first heated liquid fraction (58); said heated liquid fraction (58) is added to a liquid mixture fraction (48) in order to obtain a liquid fraction to be cooled (60); heat exchange occurs between said liquid fraction which is to be cooled and the nitrogen-enriched gas flow in a second exchanger (50).Type: GrantFiled: July 21, 2004Date of Patent: July 28, 2009Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Bernard Saulnier
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Patent number: 7546748Abstract: This disclosure discusses the problems associated with the design, layout, and construction of units and equipment in air separation units. The invention of this disclosure provides a process and apparatus using multiple discrete subcoolers. The nitrogen stream exiting the cryogenic distillation columns cools streams in the subcoolers. By having at least two subcoolers, the size of the nitrogen vent (nitrogen waste or product stream) can be reduced. This saves fabrication costs and improves reliability by reducing thermal stresses in the piping and equipment. Subcoolers cool rich liquid, lean liquid, liquid oxygen, and/or liquid air streams coming from the main heat exchanger or a system of separation columns. The disclosure also discusses integration of the subcoolers with the main heat exchangers.Type: GrantFiled: March 30, 2006Date of Patent: June 16, 2009Assignee: Air Liquide Process & Construction, Inc.Inventor: Frederic Judas
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Patent number: 7543733Abstract: The invention relates to a method of protecting equipment intended to operate at high temperature in the presence of a fluid containing at least one hydrocarbon and/or carbon monoxide against corrosion by metal dusting, method in which pieces of the equipment are made from an alloy containing nickel, iron, chromium and/or aluminum, and in which said pieces of the equipment are protected from said corrosion by a protective coating. This method is characterized in that said equipment pieces protected in this way are connected to each other by means of joining pieces, said joining pieces being protected beforehand by a protective coating over at least part of their surface intended to be brought into contact with said fluid at high temperature, and in that each of the connections intended to be subjected to said corrosion is produced by external welding of the ends of the joining piece with said pieces of equipment.Type: GrantFiled: June 25, 2003Date of Patent: June 9, 2009Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Sophie Wastiaux, Michel Poteau
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Patent number: 7527249Abstract: The invention relates to a fluid distributor for a material and heat exchange column, comprising a series of adjacent parallel vertical walls (11) which define alternate gas and liquid volumes, whereby some of the vertical walls are separated by horizontal bottom walls, provided with a line of holes and at least one section of each vertical wall is provided with a line of openings (12, 12A), formed in the upper part of the vertical wall and whereby first openings (12) have a first length towards the horizontal wall and second openings (12A) have a second length towards the horizontal wall, the second length being greater than the first.Type: GrantFiled: October 14, 2004Date of Patent: May 5, 2009Assignee: L'Air Liquide, Societe Anonyme a Directoire et Consell de Surveillance pout l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Richard Dubettier-Grenier, Philippe Grigoletto
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Patent number: 7502667Abstract: Production plants for treating gas mixtures and methods of their operation. The plant's treatment unit is operated in periods when the cost of electricity is either above a first level or below a second level. At some point when the cost is below the second level, part of the fluid is stored in a storage tank. This stored liquid is supplied to the customer when the cost is above the first level. When the cost is below the second level, a fluid with predefined properties is produced by the treatment unit. When the cost is above the first level, the power consumption of the treatment unit is reduced and a less ideal fluid is produced.Type: GrantFiled: June 24, 2003Date of Patent: March 10, 2009Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Alain Guillard, Patrick Le Bot
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Patent number: 7497092Abstract: Process and apparatus for optimization of integrated air separation systems. In an integrated process for the compression, cooling, and purification of air, an adiabatic compressor compresses an air stream to produce a compressed air stream. The compressed air stream is used to warm a first pressurized stream at a first pressure and a second pressurized stream at a second pressure. The produced streams include a first warmed pressurized stream, a second warmed pressurized stream, and a cooled compressed air stream. The first warmed pressurized stream is gaseous and is expanded in a turbine. At least part of the work produced by the turbine is used to power the adiabatic compressor. The cooled compressed air stream is further cooled by a cooling unit by heat exchange with water, and then purified in a purifying unit using a TSA process.Type: GrantFiled: October 19, 2005Date of Patent: March 3, 2009Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Patrick Le Bot
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Patent number: 7490484Abstract: Integrated air separation units with a petrochemical process. This invention provides an integrated process and gas treatment process wherein at least one first pressurized gas derived from a first process at a first site is expanded. Using the work generated by the expansion of at least one pressurized gas, a first gas compressor at the first site is driven, operates, and removes compressed gas from the first gas compressor. At least part of the compressed gas from the first gas compressor is sent to a gas treatment unit located at a remote second site. At least part of the compressed gas sent from the first site to the second site is treated in the gas treatment unit. At least one fluid from the gas treatment unit is removed and at least part of the fluid removed from the gas treatment unit is sent to the first site.Type: GrantFiled: June 23, 2005Date of Patent: February 17, 2009Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Alain Guillard, Patrick Le Bot, Bernard Saulnier
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Patent number: 7467527Abstract: The invention provides an installation for the production of hydrogen and/or carbon monoxide and/or a mixture of hydrogen and carbon monoxide, by separating a mixture to be processed (1) which contains at least carbon monoxide and hydrogen. Said installation comprises a production apparatus (9), for producing a feed mixture (3), a separating unit (BF), means for supplying the feed mixture to the separating unit, means for collecting hydrogen and/or carbon monoxide and/or a mixture of both products (7, 8), derived from the separating unit, means for drawing off at least one recycling gas (6) from the separating unit, means for returning said recycling gas upstream of the separating unit, for separating said gas simultaneously with the feed mixture from the production apparatus and means for modifying the rate and composition of said feed mixture, by modifying the operation of the production apparatus, according to the rate and composition of said at least one recycling gas.Type: GrantFiled: October 14, 2004Date of Patent: December 23, 2008Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Alain Briglia
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Patent number: 7464568Abstract: Methods and apparatus for air separation by cryogenic distillation in a double or triple air separation column. The column in the system with the highest operating pressure is said to be operating at medium pressure. All the air to be distilled is pressurized to a high pressure, which is about 5 bar greater than the medium pressure. The air is purified at this high pressure, and a portion of the purified air is cooled in a heat exchange line, while another portion is expanded in a turbine. Part of the cooled air is drawn from the exchange line with a cold booster, which is mechanically coupled to at least one turbine. An energy dissipation device is also provided which is coupled to the turbine not coupled to the cold booster. The energy dissipation device is either another booster, an oil break system, or an electrical generator.Type: GrantFiled: March 24, 2004Date of Patent: December 16, 2008Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Patrick Le Bot, Olivier De Cayeux
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Patent number: 7464012Abstract: Process simulators, including a novel process simulator that utilizes simplified mathematical correlations to predict the performance of equipment or subsystems in a process unit. The process simulator comprises a process correlation that is a mathematical response model for a discrete process system in a process unit. The process correlation is developed by obtaining operating data over a range of operating conditions of the process unit and regressing the operating data to form the mathematical response model. The process simulator calculates a number of output parameters using a number of input parameters. The process simulator outputs the output parameters so they can be used by operating personnel to evaluate the current operations of the process plant and make operating decisions.Type: GrantFiled: November 14, 2005Date of Patent: December 9, 2008Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean Gallarda, Franck Wegrzyn, Antoine Hernandez, Frederic Bonne, Jan Cobbaut
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Patent number: 7462218Abstract: A process and a device for melting aluminum where solid aluminum is melted in a furnace to form aluminum melt pool. The temperature and carbon monoxide (CO) concentration of the flue gas generated in the melting process is detected and examined for variations. Using this variation information, it is determined if aluminum oxides have formed on the surface of the aluminum melt pool and if they have, the melting process is regulated accordingly.Type: GrantFiled: November 7, 2002Date of Patent: December 9, 2008Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Jean Ducrocq
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Patent number: 7452393Abstract: An installation and process for producing hydrogen, which includes a purification unit for purifying a hydrogen-rich synthesis gas and for producing hydrogen and a waste gas, along with the additional equipment required in order to continue operation in the event of a purification unit shutdown.Type: GrantFiled: November 20, 2002Date of Patent: November 18, 2008Assignee: L'Air Liquide, Societe Anonyme A Directorie et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Yves Engler, Edie Michalik, Jan Cobbaut, Olivier Gonfalone, Dirck Simons
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Patent number: 7444834Abstract: The invention relates to a method for the provision of gas under pressure, by vaporisation of a cryogenic liquid from at least two cryogenic separation devices (A, B, C, D). Each device comprises a heat exchanger (1) and a system of columns (2, 3). In a first mode of operation, a cryogenic liquid is withdrawn from the columns in each cryogenic separation device, at least a part of which is pressurised (7, 8) to give a pressurised cryogenic liquid (9) and at least a part of the cryogenic liquid under pressure is vaporised in the heat exchanger (1) to give a part of gas under pressure (10). A cryogenic liquid is sent (6) from the cryogenic separation device to a common store (12) and at least one liquid (28A, 28B, 28C, 28D) coming from the store is vaporised in the exchange line (1) in at least one of the cryogenic separation devices.Type: GrantFiled: March 12, 2004Date of Patent: November 4, 2008Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Emmanuel Garnier, Frédéric Staine
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Patent number: 7445040Abstract: A heat exchange fin spacer. The fin may be sandwiched between two plates in a brazed-plate heat exchanger. The fin is based upon a corrugated product having wave legs which, when mounted, define flow channels for a gas to be condensed. The fin has at least one condensed liquid drainage channel on the wave legs and deviation elements that drain the liquid towards at least one lateral edge of the wave legs. The deviation elements are provided with at least one leading edge and/or at least one inclined trailing edge. The invention is suitable for use in the main heat exchanger of an air separation unit.Type: GrantFiled: January 10, 2003Date of Patent: November 4, 2008Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Claire Szulman, Etienne Werlen, Fabienne Chatel
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Patent number: 7401577Abstract: An oxygen enriched boiler having a burner subassembly and a steam subassembly is disclosed. The burner subassembly has a fuel inlet, an oxidant inlet, a combustion chamber, a flue gas composition detector and a flue gas outlet. The fuel inlet provides fuel to the combustion chamber, the oxidant inlet provides an oxygen-enriched inlet stream to the combustion chamber, the combustion chamber burns the fuel and the flue gas composition detector measures at least one characteristic of the flue gas. The steam subassembly has a supply water inlet, a heat exchange zone, a water drum, a steam quality actuator and a steam outlet.Type: GrantFiled: February 13, 2004Date of Patent: July 22, 2008Assignee: American Air Liquide, Inc.Inventors: Victor Saucedo, Ovidiu Marin
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Patent number: 7396392Abstract: An apparatus and method of use for treating at least one fluid, in a container that holds at least one mass of a particulate material between two perforated walls. Near the upper part of the mass, at least one deflector extends from the first wall towards the second wall. Fluid flows through the walls horizontally, and the deflector is positioned at an angle to this horizontal fluid flow direction. With this particular apparatus configuration, an area close to the second wall and opposite the adjacent end of the deflector is formed, which is generally free of particulate matter; thus, resulting in a more efficient treatment process.Type: GrantFiled: February 17, 2003Date of Patent: July 8, 2008Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Yves Lehman, Benoît Davidian, Philippe Fert