Abstract: A continuous process for producing alkali metal alkoxides comprising continuously introducing an aqueous solution of an alkali metal hydroxide into an upper section of a column reactor; continuously vaporizing an alkanol or an alkoxyalkanol of 4 to 18 carbon atoms into a lower section of the reactor at a rate of at least about 2 to 4 moles of alcohol for each mole of alkali metal hydroxide introduced into the reaction zone; reacting the aliphatic alcohol with the alkali metal hydroxide in the reactor; concurrently removing water from the alkali metal hydroxide solution and the alkoxide formation from an upper section of the reactor as an azeotrope formed by excess alcohol and water; continuously condensing and separating the azeotrope into an alcohol phase and a water phase, the water phase being removed from the process and the alcohol phase being returned to the column reactor; and removing a substantially anhydrous reaction product consisting primarily of alkoxide product in excess alcohol from a bottom se

Abstract: A process for converting a thallium (I) compound to a thallium (III) compound comprising contacting an alkaline solution of the thallium (I) compound with gaseous oxygen and in the presence of a peroxygen compound.

Abstract: An electrophoretic support comprising a base plate having on at least one side thereof, a layer of an adherent resin containing ethylenically unsaturated groups capable of undergoing copolymerization with acrylamide. The support provides excellent adhesion for polyacrylamide gels and other electrophoretic media such as agarose.

Abstract: An improved apparatus for dispensing flowable material having a pinch valve, an operating lever, a support plate, and a resilient tube located between the lever and the support plate. Movement of an end portion of the lever operates the pinch valve which serves to sequentially isolate a measured quantity of flowable material delivered from a supply and release such measured quantity of material for discharge from the apparatus.

Abstract: Compositions are provided suitable for the etching of printed circuits from a laminate of copper metal and an etch resistant backing at a low hydrogen peroxide concentration and at a low temperature. The etching composition contains sulfuric acid, hydrogen peroxide as the oxidant, thiosulfate ion to counteract the depressing effect of chloride ion on the etch rate, an unsaturated organic hydroxy compound to stabilize the hydrogen peroxide in the presence of copper, and an aminomethylenephosphonic acid.

Abstract: The invention relates to the dispensing of hydrogen peroxide into a clothes dryer. The aqueous hydrogen peroxide is placed into a container with a microporous, hydrophobic surface which is heated whereby the hydrogen peroxide is vaporized and delivered to the interior of the dryer where it is available to bleach textiles.

Abstract: A process to manufacture trichloroisocyanuric acid of commercially acceptable size and quality from a mother liquor used to produce an alkali metal salt of dichloroisocyanurate by monitoring and, if necessary, adjusting the mol ratio of available alkalinity to chlorine required to convert all of the triazine compounds in the mother liquor to trichloroisocyanuric acid to be between 1.0 and 1.3 with an alkali metal salt of carbonic acid.

Abstract: An anthraquinone autoxidation process has been developed for producing hydrogen peroxide employing N-substituted-2-pyrrolidones as solvents for the anthrahydroquinone formed in the reduction step. These new solvents have improved solubility characteristics over prior solvents. Particular N-substitutents are alkyl and alkaryl groups containing 6 to 12 carbon atoms.

Abstract: A method of preventing sludge deposition in the treatment of geothermal steam condensate with iron catalyzed/hydrogen peroxide by carrying out the treatment in the presence of an inorganic polyphosphate.

Abstract: Automated chemical analytical method and device in which a precise measured quantity of reagent is combined with an assay medium. Prior to such delivery, the reagent, being water-soluble or dispersible, is contained within carrier solid organic binder which is fixed within and constitutes part of the device. Upon addition of an aqueous medium, the carrier binder is dissolved or dispersed, the protected precise measured quantity of reagent is concomitantly released and dissolved.

Abstract: Allylic esters of tetrachlorophthalic acid are formed using allylic alcohol both as a reactant and a solvent. In the first step, the alcohol and a base are reacted with tetrachlorophthalic anhydride to form the half-ester sodium salt. In the second step, the sodium salt is reacted with allylic halide to form the diester which crystallizes from solution. The excess solvent may be treated to recover the raw materials or recycled.

Abstract: Apparatus for liberating particulate material from a compressed bale and feeding the liberated material at a controlled rate to a processing station comprises a screw conveyor and means for compacting the particulate material against the conveyor screw.

Abstract: Epoxy resins are rendered fire retardant by the addition thereto of a 3-hydroxyalkylphosphine oxide. Other halogen containing flame retardants may or may not be present in the composition. Mixtures containing a brominated epoxide and/or a halogenated phosphine oxide provide a high level of flame retardance at low levels of the additive. The epoxy resins may be heat cured in the presence of an acid anhydride or amine to form a polymer having the phosphine oxide incorporated in the polymer molecule.

Abstract: Stabilizer formulations have been developed for commercial hydrogen peroxide stored in stainless steel containers. These stabilizers, which include benzene phosphonous acid, 2,2'-dithiobenzoic acid, 1-allyl-thiourea, and thiocarbanilide are effective in the presence of typical decomposition catalysts when used in conjunction with typical organic phosphonic stabilizer systems, even when the commercial organic phosphonic stabilizers are present in less than the usually recommended quantities.

Abstract: A polyphenylene ether resin composition comprising:(i) from about 30 to about 90 weight percent of a graft copolymer free from polyphenylene ether homopolymers prepared by polymerizing 20 to 200 parts by weight of styrene-type compound at a temperature in the range from 130.degree. C. to 200.degree. C. in the presence of 100 parts by weight of polyphenylene ether and 0.1 to 15 parts by weight of a radical initiator and(ii) 10 to 70 weight percent of a styrene-type compound polymer having a number average molecular weight in the range from 50,000 to 200,000; is rendered fire retardant by the addition of an effective amount of a phosphine oxide having the formula ##STR1## wherein R.sub.1 may be the same or different radicals selected from the group consisting of hydrogen and the methyl radical, R.sub.2 is an alkyl radical of 4 to 8 carbon atoms and n is either zero or one.

Abstract: Epoxy resins are rendered fire retardant by the addition thereto of a 3-hydroxyalkylphosphine oxide. Other halogen containing flame retardants may or may not be present in the composition. Mixtures containing a brominated epoxide and/or a halogenated phosphine oxide provide a high level of flame retardance at low levels of the additive. The epoxy resins may be heat cured in the presence of an acid anhydride or amine to form a polymer having the phosphine oxide incorporated in the polymer molecule.

Abstract: Polyurethane compositions are rendered fire retardant by substitution for some of the polyol normally present in the reaction mixture, an effective amount of a 3-hydroxypropyl phosphine oxide such as sec-butyl bis(3-hydroxypropyl) phosphine oxide.

Abstract: Glass filled thermoplastic polyamide polymers such as nylon 6/6 are rendered fire retardant by the addition of an effective amount of a tris-(3-hydroxyalkyl) phosphine oxide such as tris-(3-methyl-3-hydroxypropyl) phosphine oxide.

Abstract: A mechanism for use in a strapping apparatus including a pair of like rolls which have meshing gears as flanges and which are rotated by a drive means through a clutch system to both feed and tension strap without stopping or reversing the drive means. Strap is laced about and nipped by the rolls and, as the rolls rotate at the same speed and the roll flanges travel with the strap, abrasion along the strap sides and edges is avoided.

Abstract: 4Na.sub.2 SO.sub.4.2H.sub.2 O.sub.2.NaCl, having improved alkaline stability, is produced by crystallizing it in the presence of a stabilizing quantity of a soluble, organic polyphosphonate which is taken up in the crystalline structure of the compound.The stabilized product is useful as a peroxygen bleaching agent in alkaline bleach systems.