Abstract: A process for reducing or eliminating Caro's acid mist, created when producing a hot mixture containing Caro's acid by reaction of sulfuric acid and hydrogen peroxide, is carried out by quenching the hot Caro's acid mixture with water to both cool and dilute the Caro's acid.

Abstract: A process is provided for preparing an aryl diphosphate ester containing less than 5% by weight of triarylphosphate. The process reacts a solution of a dihydroxy aromatic compound and an excess of phosphorus oxychloride in a nonaqueous solvent having a boiling point greater than 110.degree. C. The excess phosphorus oxychloride and part of the solvent are distilled from the solution at atmospheric pressure and the intermediate, a diphosphotetrachloridate solution, is reacted with a monohydric aryl compound. After extracting with an aqueous, alkaline solution the product is recovered by distilling off the remaining solvent.

Abstract: The invention is a novel composition of alkylated phenyl phosphate esters comprising by weight 1% to 20% trialkylphenyl phosphate, 10% to 50% dialkylphenyl monophenyl phosphate, 15% to 60% monoalkylphenyl diphenyl phosphate and less than 2% triphenyl phosphate and a process for preparing the composition comprising passing the composition at least once through a thin film evaporator at a temperature of about 200.degree. C. to about 250.degree. C. at a pressure sufficiently less than 5 kPa to evaporate about 5% to about 30% of the composition.

Abstract: A method is provided for forming a tacky surface area on a styrenic resin, such as a polystyrene label. A thin film is applied of an alkyl, aryl or alkaryl ester of a phosphorus oxyacid providing a tacky area suitable for bonding to another surface. A composition particularly useful for bonding polystyrene labels to bottles is a solid alkyl, aryl or alkaryl ester of a phosphorus oxyacid and a cosolvent selected from terpenoids and aromatic compounds having a flash point of at least 35.degree. C. and a boiling point between 100.degree. C. and 260.degree. C.

Abstract: A method is provided for applying a polystyrene label to a surface of a polystyrenic article. The process comprises applying a thin film of a terpenoid compound to the polystyrene, the terpenoid compound having a boiling point between 150.degree. C. and 260.degree. C.

Abstract: The invention is a process for purifying a solid, storage-stable tris(bromophenyl)phosphate ester dissolving a crude tris(bromophenyl)phosphate in an ester at an elevated temperature, and cooling the solution sufficiently to recover a solid phase.

Abstract: The invention is a process for preparing a solid, storage-stable tris(bromophenyl)phosphate ester by the phosphorylation of a bromophenol and recovering the product by cooling a solution of the reaction mixture from a hydrocarbon solvent containing 2 to 20 parts of a C5 to C10 alkane per part of a C6 to C10 arene.

Abstract: A flame retardant grease composition is described for low temperature applications comprising mixed alkoxy and alkylated phenyl triesters of a phosphorus oxyacid as a base fluid and a siliceous microparticulate inorganic thickener. The grease has excellent low, medium and high temperature physical properties, which makes it suitable for service in applications with wide temperature (-40.degree. C. to +150.degree. C.) fluctuations. The benefits of reduced rolling resistance can be realized in significant energy savings and the possibility of constructing longer conveyor lines with existing drive motors.

Abstract: A process is provided for purifying phosphoric acid, such as wet process phosphoric acid by extracting the impure phosphoric acid with a nonaqueous solvent and contacting the nonaqueous solution of phosphoric acid with a strongly basic anion exchange resin and recovering the purified phosphoric acid by stripping the nonaqueous solution with an aqueous solution.

Abstract: A composition is provided of inorganic polyphosphates which will form a clear, stable solution suitable for injection into meat products. The composition comprises sodium tripolyphosphate and a long-chain glassy phosphate in sufficient quantities to provide 92 to 85 parts by weight sodium tripolyphosphate and 8 to 15 parts by weight of long-chain glassy phosphate, said long-chain glassy phosphate having a degree of polymerization of about 20 to 30, an average mole ratio of (Na.sub.2 O+H.sub.2 O)/P.sub.2 O.sub.5 below about 1.067, and preferably possessing terminal groups on the polyphosphate chain having no less than about 75% OH with the remainder being ONa.

Abstract: Compacted shapes of phosphatic material, suitable as a charge for a phosphorus furnace, are produced by compacting a mixture of calcined phosphate fines and phosphoric acid. The compacted shapes are conveniently produced on a roll briquetting press.

Abstract: A process is provided for manufacturing tetrasodium pyrophosphate from sodium tripolyphosphate and a sodium salt capable of forming sodium carbonate on calcination. A compound capable of forming sodium carbonate is added to adjust the mol ratio to about 2, the mixture is milled and heated to from 300.degree. C. to 700.degree. C.

Abstract: A process is provided for producing a powdered STPP hexahydrate particularly useful for use as a builder in a heavy duty detergent.

Abstract: The invention is a process to purify a solution of phosphoric acid by removing transition metal impurities such as iron, chromium and vanadium. In the process a solution of phosphoric acid in an organic solvent which is substantially immiscible with water is contacted with an aqueous solution of a salt of an alkali metal of phosphoric acid. The phosphoric acid recovered following the contacting contains a substantially lesser content of transition metal impurities.

Abstract: A working solution for producing hydrogen peroxide (made up of an anthraquinone working compound dissolved in one or more solvents) is regenerated with an alkaline, activated alumina, containing about 3.7 wt. % Na.sub.2 O at temperatures of about 145.degree. C., wherein both the oxidized and hydrogenated work solution are mixed and treated with the said alumina simultaneously on a continuous basis, so that regeneration proceeds continually and degradation products are maintained within controllable limits.

Abstract: Screen undersize sodium tripolyphosphate (STPP) particles are compacted, milled and moisturized by adding a sufficient amount of water thereon to produce a material containing on the average between about 15% and about 35% by weight moisture. The moisturized material is calcined to a temperature within the range of from about 300.degree. to about 600.degree. C., to produce a granular STPP product having a low friability, high absorptivity, and a bulk density within the range of from about 0.65 to about 0.87 g/cc.

Abstract: Excess water, both crystalline and non-crystalline, is removed safely and rapidly from active chlorine compounds by applying electromagnetic energy with frequencies lower than infrared to vaporize the excess water.

Abstract: Method and apparatus for subterranean slurry drilling and mining of granular ore, such as phosphates, with a combined drilling and mining apparatus. The apparatus includes a tool string having a drilling head and mining head that are selectively interchangeable on its upper end for drilling into one or more ore strata to be mined and thereafter to remove ore from the strata as a slurry. The drill string includes a plurality of inner and outer pipe sections connected to a drill bit at its lower end. A drilling/mining liquid is directed through the tool string during both the drilling and mining modes of operation. During drilling, liquid is directed through a foot valve into the rotating bit to wash cuttings to the surface externally of the tool.

Abstract: Subterranean slurry mining with one or more mining nozzles which, during mining, directs a high pressure jet of liquid into a granular ore matrix to reduce the ore to a slurry which is thereafter pumped to the surface by an eductor pump including a high pressure eductor nozzle. The drilling and mining apparatus includes several different types of hydraulic control systems which operates at or below system pressure and allows the apparatus to be changed between the mining and a drilling mode. During drilling, the liquid is directed through an open foot valve and drill bit into the well cavity being drilled to wash the cuttings to the surface at which time the mining and eductor nozzles are closed. During mining the control systems close the foot valve and control the opening of the mining nozzle (or nozzles) and eductor nozzle.

Abstract: High strength peroxymonosulfate is prepared by adding concentrated sulfuric acid to a solution of a soluble peroxydisulfate whereby the heat of solvation of the sulfuric acid hydrolyzes the peroxydisulfate to the peroxymonosulfate; the temperature is controlled to provide a range of about 140.degree. to 160.degree. F. After about 15 to 45 minutes, the solution is cooled rapidly to about room temperature.