Abstract: A novel catalytic cracking composition comprising a solid cracking catalyst and a diluent containing a selected magnesium compound or a selected magnesium compound in combination with one or more heat-stable metal compounds.
Abstract: A process for cracking high metals content feedstocks which comprises contacting said charge stock under catalytic cracking conditions with a novel catalytic cracking composition comprising a solid cracking catalyst and a diluent containing a selected magnesium compound or a selected magnesium compound in combination with one or more heat-stable metal compounds.
Abstract: The present invention is directed to a class of novel 1-benzoyl-3-thiosemicarbazides which are useful as plant growth regulants. The present invention is also directed to methods and formulations for plant growth regulation.
Abstract: Novel quaternary phosphonium tetrathiostannates and quaternary phosphonium hexathiodistannates are prepared by the reaction of a quaternary phosphonium salt with a tetrathiostannate or a hexathiodistannate salt.
Type:
Grant
Filed:
July 12, 1982
Date of Patent:
July 31, 1984
Assignee:
Gulf Research & Development Company
Inventors:
Judith B. Onopchenko, Gary M. Singerman, Raynor T. Sebulsky
Abstract: A novel cement composition for the preparation of a novel aqueous slurry useful in cementing casing in the borehole of a well comprising (1) cement, (2) (a) a hydroxyethylcellulose ether or (2) (b) a mixture of a hydroxyethylcellulose ether and a hydroxypropylcellulose ether, (3) a polysaccharide produced as a result of microbial action and (4) a dispersant.
Abstract: A novel cement composition for the preparation of a novel aqueous slurry useful in cementing casing in the borehole of a well comprising (1) cement, (2) (a) a hydroxyethylcellulose ether having a critical viscosity or (2) (b) a mixture of a hydroxyethylcellulose ether having a critical viscosity and of a hydroxypropylcellulose ether having a critical viscosity and (3) a dispersant.
Abstract: A process for preventing the formation of deleterious coke deposits on the walls of coal liquefaction reactor vessels involves passing hydrogen and a feed slurry comprising feed coal and recycle liquid solvent to a coal liquefaction reaction zone while imparting a critical mixing energy of at least 3500 ergs per cubic centimeter of reaction zone volume per second to the reacting slurry.
Type:
Grant
Filed:
January 26, 1982
Date of Patent:
July 3, 1984
Assignee:
The Pittsburg & Midway Coal Mining Co.
Inventors:
Norman L. Carr, Michael E. Prudich, William E. King, Jr., William G. Moon
Abstract: Spent boron trifluoride catalyst is removed from organic liquids by contacting the liquid with polyvinyl alcohol. For example, boron trifluoride catalyst is removed from 1-olefin oligomer product by passing the liquid oligomer through a bed of granular polyvinyl alcohol. The boron trifluoride is recovered from the polyvinyl alcohol and is recycled for use as a catalyst.
Type:
Grant
Filed:
December 15, 1982
Date of Patent:
June 12, 1984
Assignee:
Gulf Research & Development Company
Inventors:
Roger F. Vogel, Ajay M. Madgavkar, Harold E. Swift
Abstract: Hydrocarbons containing vanadium are converted to lower boiling fractions employing a zeolitic cracking catalyst containing a significant concentration of a calcium-containing additive as a vanadium passivating agent.
Abstract: C.sub.4 compounds including n-butanol and n-butanal are produced by reacting methanol, hydrogen, and carbon monoxide, in the presence of a cobalt catalyst selected from the group consisting of (a) a cobalt carbonyl, (b) a hydrido cobalt carbonyl and (c) a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, an iodine promotor and a thiol defined by the formula:RSHwherein R is selected from the group consisting of saturated or unsaturated, straight or branched chain alkyl radicals having from one to 24 carbon atoms, cycloalkyl radicals having from three to 40 carbon atoms, aryl radicals having from six to 20 carbon atoms, aralkyl and alkaryl radicals having from six to 40 carbon atoms and halogen substituted derivatives thereof. A high degree of selectivity towards the formation of butanol and butanal is provided by using the cobalt entity and the thiol in a molar ratio in the range of about 2:1 to about 10:1, based on elemental cobalt and sulfur.
Type:
Grant
Filed:
March 1, 1982
Date of Patent:
May 8, 1984
Assignee:
Gulf Research & Development Company
Inventors:
Wayne R. Pretzer, Thaddeus P. Kobylinski, John E. Bozik
Abstract: Paraffin wax is continuously extruded through an extrusion die into a sag-free ribbon of good surface characteristics by extruding the wax at a temperature within the range of about 2.degree. C. below and about 10.degree. C. above the solid state transition temperature of the wax.
Abstract: A catalyst particularly suitable for selectively producing aldehydes, particularly acetaldehyde, which comprises (1) cobalt, (2) iodine and (3) a ligand containing atoms from Group VB of the Periodic Table separated by a sterically constrained carbon-carbon bonding.
Abstract: Olefin oligomers suitable as lubricants are prepared with a catalyst comprising boron trifluoride and a mixture of an alcohol, a polyol and a ketone. 1-Decene is oligomerized to a liquid product having a high trimer to tetramer ratio using boron trifluoride and a mixture of n-butanol, ethylene glycol and methylethyl ketone.
Abstract: There is provided a solid, particulate, catalytic complex suitable for the stereospecific polymerization of olefins prepared by reducing TiCl.sub.4, contacting the resultant reduced solid with a complexing agent to obtain a treated solid and contacting the treated solid with TiCl.sub.4 in the presence of silica which has been treated with an alkylaluminum halide. When such a catalyst complex is combined with a suitable activator to polymerize olefins, a high degree of stereospecificity is attained, the activity of the catalyst complex is reduced for polymerization control and the efficiency of the titanium employed is enhanced.
Abstract: Boron trifluoride is removed from coordination compounds contaminating organic liquids by contacting the contaminated liquid with silica. For example, boron trifluoride is removed from a boron trifluoride-n-butanol coordination compound contaminating a 1-olefin oligomer product by passing the contaminated liquid oligomer through a bed of silica.
Type:
Grant
Filed:
July 8, 1982
Date of Patent:
February 21, 1984
Assignee:
Gulf Research & Development Company
Inventors:
Roger F. Vogel, Ajay M. Madgavkar, Harold E. Swift
Abstract: Uranium peroxide is precipitated from an acidified carbonate strip solution by the addition of hydrogen peroxide and a sufficient quantity of the alkaline carbonate strip solution to maintain the pH at an acid level which is suitable for the precipitation of uranium peroxide.
Abstract: An alpha-olefin is oligomerized in the presence of a three-component catalyst comprising a particulate solid adsorbent, boron trifluoride and elemental oxygen. The process also activates the catalyst. For example, 1-decene is oligomerized to a product predominating in the trimer and tetramer using boron trifluoride, elemental oxygen and silica as the solid adsorbent.
Abstract: New N-carbamylindolines which are useful in combating unwanted vegetation by both pre-emergent and post-emergent application are compounds having the structural formula ##STR1## in which R and R.sup.3 are hydrogen or methyl, R.sup.1 is hydrogen or N,N-dimethylsulfamyl, N,N-diethylsulfamyl, N-methoxy-N-methyl-sulfamyl, bromo or chloro, X is hydrogen or fluoro and R.sup.2 is hydrogen or dimethylsulfamyl, with the provision that at least one and no more than two substituents represented by R.sup.1, R.sup.2, and R.sup.3 and X are present.
Abstract: Highly aromatic hydrocarbon feedstocks are converted to jet fuel or diesel fuel using a sulfided, halogen promoted Group VIB - Group VIII metal on an alumina-containing support. The preferred catalyst is a presulfided, fluorine-promoted nickel-tungsten on silica-alumina catalyst wherein the nickel is present in amounts of between 18 and 22 weight percent based on the total catalyst weight.
Abstract: Polymer precursor materials are vaporized without polymerization or are removed from a raw naphtha fraction by passing the raw naphtha to a vaporization zone (24) and vaporizing the naphtha in the presence of a wash oil while stripping with hot hydrogen to prevent polymer deposits in the equipment.
Type:
Grant
Filed:
January 25, 1982
Date of Patent:
December 27, 1983
Assignee:
The Pittsburg & Midway Coal Mining Co.
Inventors:
Dennis C. Kowalczyk, Bruce A. Bricklemyer, Joseph J. Svoboda