Abstract: Tertiary phosphines are prepared by reacting a phosphine (PH3 or a primary or secondary phosphine) with a cyclic alpha,beta-unsaturated carbonyl compound having no more than one C?C double bond conjugated with a carbonyl group. The inventive tertiary phosphines can have R groups that are the same or different. The inventive tertiary phosphines may be used as ligands for metal catalysts or as starting materials for preparing phosphonium salts or ylids.

Abstract: A solvent extraction composition is comprised of one or more orthohydroxyarylaldoximes and one or more othohydroxyarylketoximes, and one or more equilibrium modifiers in an amount providing a degree of modification of the orthohydroxyarylaldoximes from about 0.2 to 0.

Abstract: Froth flotation processes, useful for beneficiating base metal mineral values from metal sulfide ore, utilize a collector comprising an N-butoxycarbonyl-O-alkylthionocarbamate selected from the group consisting of N-butoxycarbonyl-O-methylthionocarbamate, N-butoxycarbonyl-O-ethylthionocarbamate, N-butoxycarbonyl-O-propylthiononocarbamate, N-butoxycarbonyl-O-butylthionocarbamate, N-butoxycarbonyl-O-pentylthionocarbamate, and N-butoxycarbonyl-O-hexylthionocarbamate.

Abstract: Froth flotation processes, useful for beneficiating base metal mineral values from metal sulfide ore, utilize a collector comprising N-butoxycarbonyl-O-butylthionocarbamate.

Abstract: Froth flotation processes, useful for beneficiating base metal mineral values from metal sulfide ore, utilize a collector comprising an N-butoxycarbonyl-O-alkylthionocarbamate selected from the group consisting of N-butoxycarbonyl-O-methylthionocarbamate, N-butoxycarbonyl-O-ethylthionocarbamate, N-butoxycarbonyl-O-propylthiononocarbamate, N-butoxycarbonyl-O-butylthionocarbamate, N-butoxycarbonyl-O-pentylthionocarbamate, and N-butoxycarbonyl-O-hexylthionocarbamate.

Abstract: Materials and a process are provided whereby polymers with the pendant group or end group containing —Si(OR″)3 (where R″ is H, an alkyl group, Na, K, or NH4) are used to control aluminosilicate scaling in a Bayer process. When materials of the present invention are added to the Bayer liquor before the heat exchangers, they reduce and even completely prevent formation of aluminosilicate scale on heat exchanger walls. The present materials are effective at treatment concentrations that make them economically practical.

Abstract: The present invention relates to novel red-shifted UV absorbers comprising 1,3,5-triazine structures containing a 2-naphthol-derived substituent. The present invention also relates to a method for stabilizing a material by incorporating into such material, e.g., organic material, the novel red-shifted triazine compounds in an amount effective to stabilize the material against the effects of actinic radiation.

Abstract: Froth flotation processes, useful for beneficiating base metal mineral values from metal sulfide ore, utilize a collector comprising N-butoxycarbonyl-O-butylthionocarbamate.

Abstract: A partially impregnated preform employs a fiber layer partially impregnated with a resin to form a fiber reinforced resin composite. The fiber layer of the partially impregnated preform is formed of a plurality of parallel oriented tows, each tow formed of a plurality of unidirectional reinforcement fibers. The resin is partially impregnated on one or both faces of the fiber layer. A resin composition for partially impregnating a fiber layer of a preform is also provided. A stack of partially impregnated preforms utilizes a plurality of partially impregnated preforms. The stack of partially impregnated preforms may be cross-ply reinforced by cross-ply stitching the stack of partially impregnated preforms together prior to curing to form a fiber reinforced resin composite upon curing.

Abstract: A ferromagnetic powder comprising ferromagnetic particles coated with a material that does not degrade at temperatures above 150° C and permits adjacent particles to strongly bind together after compaction such that parts made from the ferromagnetic powder have a transverse rupture strength of about 8,000 to about 20,000 pounds/square inch before sintering. The coating includes from 2 to 4 parts of an oxide and one part of a chromate, molybdate, oxalate, phosphate, or tungstate. The coating may be substantially free of organic materials. The invention also includes a method of making the ferromagnetic powder, a method of making soft magnetic parts from the ferromagnetic powder, and soft magnetic parts made from the ferromagnetic powder.

Abstract: A ferromagnetic powder comprising ferromagnetic particles coated with a material that does not degrade at temperatures above 150° C. and permits adjacent particles to strongly bind together after compaction such that parts made from the ferromagnetic powder have a transverse rupture strength of about 8,000 to about 20,000 pounds/square inch before sintering, The coating includes from 2 to 4 parts of an oxide and one part of a chromate, molybdate, oxalate, phosphate, or tungstate. The coating may be substantially free of organic materials. The invention also includes a method of making the ferromagnetic powder, a method of making soft magnetic parts from the ferromagnetic powder, and soft magnetic parts made from the ferromagnetic powder.

Abstract: An apparatus and method are provided for coating particles in a rotating container. A cathode forms an electrically conductive inner surface of a side wall of the container. An anode is positioned relative to the cathode so as to permit both the cathode and the anode to be immersed together in an electrically conductive fluid. A motor is connected to the container and arranged to cause the container to rotate so as to generate a centrifugal force. Particles are placed in the container, the container is filled with the electrically conductive fluid, and electrical current is caused to pass from the cathode to the anode through the electrically conductive fluid while the container is rotated. The particles rest against the electrically conductive inner surface of the side wall of the container while the electrical current passes from the cathode to the anode, so as to result in deposition of a coating material from the electrically conductive fluid onto the particles.

Abstract: A method for coating particulate substrate materials is provided which comprises (a) combining particles and an electrolyte in an imperforate container; (b) vibrating the container to generate a fluidized bed of particles in the electrolyte; and (c) electrochemically depositing a coating on the particles from reactants in the electrolyte. An apparatus for coating particles is also provided which comprises an imperforate container for receiving particles to be coated and an electrolyte and a device for generating a fluidized bed in the container, the device being operatively associated with the container.

Abstract: The invention is directed to a method of forming parts having complex geometries made by coating ferrous based powders with a metallurgical coating, pressing the powder to make the parts, and using a low temperature heating step to diffuse the coating into the ferrous based powders.

Abstract: A ferromagnetic powder comprising ferromagnetic particles coated with a material that does not degrade at temperatures above 150° C. and permits adjacent particles to strongly bind together after compaction such that parts made from the ferromagnetic powder have a transverse rupture strength of about 8,000 to about 20,000 pounds/square inch before sintering. The coating includes from 2 to 4 parts of an oxide and one part of a chromate, molybdate, oxalate, phosphate, or tungstate. The coating may be substantially free of organic materials. The invention also includes a method of making the ferromagnetic powder, a method of making soft magnetic parts from the ferromagnetic powder, and soft magnetic parts made from the ferromagnetic powder.

Abstract: A powder feed system for delivering a quantity of particulate material to a die cavity of a powder press is provided. The powder press has a table-like platen surface which is flush with and surrounds a die in which the die cavity sits, an upper punch appending from an upper ram and a lower punch. The powder feed delivery system includes a receptacle for receiving and delivering particulate material to the cavity. The receptacle has an ingress through which particulate material is received under pressure and an egress for registering with the interior of the cavity and through which particulate material is delivered under pressure from a feed conduit to the cavity. The feed conduit is attached at a first end to the receptacle ingress. At least one pressure generator is attached to a top end of a pressure vessel attached at a second end to the feed conduit.

Abstract: A plurality of particles include a first material. A coating including a second material is formed on surfaces of the particles, until a selected ratio of the volume of the coating relative to the volume of the particles is achieved. A plurality of particles, including the coated particles, are consolidated in a manner such that the particles are caused to be joined to each other, to form an article. The ratio of the volume of the coating relative to the volume of the particles is selected in a manner such that the article is engineered to have a selected volume fraction representing the volume of the second material in the article relative to the volume of the first material in the article. The first material, the second material, and the volume fraction are selected in a manner such that the article is engineered to exhibit a selected intrinsic property.

Abstract: A ferromagnetic powder comprising ferromagnetic particles coated with a material that does not degrade at temperatures above 150.degree. C. and permits adjacent particles to strongly bind together after compaction such that parts made from the ferromagnetic powder have a transverse rupture strength of about 8,000 to about 20,000 pounds/square inch before sintering. The coating includes from 2 to 4 parts of an oxide and one part of a chromate, molybdate, oxalate, phosphate, or tungstate. The coating may be substantially free of organic materials. The invention also includes a method of making the ferromagnetic powder, a method of making soft magnetic parts from the ferromagnetic powder, and soft magnetic parts made from the ferromagnetic powder.

Abstract: A process for consolidating powder, particulates, foils or sheets of metal coated composites, elemental metallic or metallic alloy or intermetallic compounds into net shapes having increased green strength at or near ambient temperature comprises treating the material with an aqueous activation solution. The aqueous activation solution is selected from dilute acids, reducing agents, molten salt electrolytes and mixtures thereof. Pressure is used to consolidate the treated powders, particulates, foils or sheets into a net shape at or near ambient temperature.

Abstract: Steel powder for use in case hardenable steels is provided. The steel powder is made from a plurality of pre-alloyed iron-molybdenum particles. Each of the particles has from about 1.5 to about 3.5 percent by weight of molybdenum and have a diameter of from about 20 to about 200 microns. The powders further have from about 0.001% by weight to about 0.5% by weight of a coating. The coating is made up of from about 40% to about 85% by weight of one or more of FeO, Fe.sub.3 O.sub.4, Fe.sub.2 O.sub.3, (Fe.sub.2 O.sub.3.H.sub.2 O) and combinations thereof; and from about 15% to about 60% by weight of one or more of FePO.sub.4, Fe.sub.3 (PO.sub.4).sub.2, FeHPO.sub.4, Fe.sub.3 (PO.sub.4).sub.2.2H.sub.2 O, Fe.sub.2 (PO.sub.4).sub.3.8H.sub.2 O, FeCrO.sub.4, FeMoO.sub.4, FeC.sub.2 O.sub.4, and FeWO.sub.4.Also provided is a steel powder composition for use in manufacturing sinter hardenable structural parts. The powder is made from a plurality of pre-alloyed steel particles of from about 0.5 to about 3.