Patents Represented by Attorney Francis M. Fazio
  • Patent number: 4188477
    Abstract: Derivatives of esterdiol alkoxylates obtained by reaction thereof with an isocyanate, as well as the anhydride capped products thereof. Formulations containing the above are also claimed.
    Type: Grant
    Filed: January 4, 1979
    Date of Patent: February 12, 1980
    Assignee: Union Carbide Corporation
    Inventors: Oliver W. Smith, Joseph V. Koleske, Robert J. Knopf
  • Patent number: 4171423
    Abstract: Derivatives of esterdiol alkoxylates obtained by reaction thereof with an anhydride, isocyanate or epoxide, as well as the anhydride capped products of the derivatives of the two latter. Formulations containing the above are also claimed.
    Type: Grant
    Filed: September 29, 1977
    Date of Patent: October 16, 1979
    Assignee: Union Carbide Corporation
    Inventors: Oliver W. Smith, Joseph V. Koleske, Robert J. Knopf
  • Patent number: 4165266
    Abstract: Compositions comprising poly (vinyl alkyl ether), a liquid monoacrylate monomer and photoinitiator cure upon exposure to radiation to form pressure sensitive adhesives having an excellent balance of peel strength, shear time, and quick stick.
    Type: Grant
    Filed: March 30, 1977
    Date of Patent: August 21, 1979
    Assignee: Union Carbide Corporation
    Inventors: Kenneth C. Stueben, Raymond G. Azrak, Michael F. Patrylow
  • Patent number: 4165345
    Abstract: High solids coating compositions comprising a polycaprolactone derivative and a mixture of a methylolated melamine and a low molecular weight polyol; and, optionally, solvent and catalyst. The polycaprolactone derivative used in the coating compositions is the reaction product of a polycaprolactone polyol, a polyisocyanate and an anhydride of a polycarboxylic acid; the polycaprolactone polyol has an average of at least two hydroxyl groups in the molecule, a hydroxyl number of from about 15 to about 600 and an average molecular weight of from about 290 to about 6,000. The carboxylic acid anhydride mentioned has at least one intramolecular carboxylic anhydride group. The polycaprolactone derivatives are water insoluble.
    Type: Grant
    Filed: April 20, 1978
    Date of Patent: August 21, 1979
    Assignee: Union Carbide Corporation
    Inventors: Oliver W. Smith, Joseph V. Koleske
  • Patent number: 4163114
    Abstract: Novel ester diol alkoxylates produced by the reaction of an ester diol and an alkylene oxide. The reaction product is a vehicle useful in ink or paint formulations, as a solvent, and in adhesive formulations; it is also useful as an intermediate in the production of other valuable compounds and as a surfactant.
    Type: Grant
    Filed: September 29, 1977
    Date of Patent: July 31, 1979
    Assignee: Union Carbide Corporation
    Inventors: Joseph V. Koleske, Robert J. Knopf
  • Patent number: 4163113
    Abstract: Novel ester diol alkoxylate acrylates prepared by the reaction of an ester diol and an alkylene oxide to produce an ester diol alkoxylate that is subsequently reacted with acrylic acid or methacrylic acid. The novel derivatives are useful as vehicles in coating and ink compositions and as monomers in the production of polymers.
    Type: Grant
    Filed: September 29, 1977
    Date of Patent: July 31, 1979
    Assignee: Union Carbide Corporation
    Inventors: Robert J. Knopf, Joseph V. Koleske
  • Patent number: 4163029
    Abstract: High solids coating compositions comprising a polycaprolactone derivative and a mixture of a methylolated melamine and a low molecular weight polyol; and, optionally, solvent and catalyst. The polycaprolactone derivative used in the coating compositions is the reaction products of a polycaprolactone polyol, a diepoxide and an anhydride of a polycarboxylic acid; the polycaprolactone polyol has an average of at least two hydroxyl groups in the molecule, a hydroxyl number of from about 15 to about 600 and an average molecular weight of from about 290 to about 6,000. The carboxylic acid anhydride mentioned has at least one intramolecular carboxylic anhydride group. The polycaprolactone derivatives are water insoluble.
    Type: Grant
    Filed: April 20, 1978
    Date of Patent: July 31, 1979
    Assignee: Union Carbide Corporation
    Inventors: Oliver W. Smith, Joseph V. Koleske
  • Patent number: 4158652
    Abstract: Compositions comprising an ester diol alkoxylate in conjunction with crosslinkers, or polycaprolactone polyols or derivatives thereof, or low molecular weight polyols, or isocyanates, or latexes have been produced that are useful as coatings, inks and adhesives.
    Type: Grant
    Filed: September 29, 1977
    Date of Patent: June 19, 1979
    Assignee: Union Carbide Corporation
    Inventors: Joseph V. Koleske, Robert J. Knopf, Oliver W. Smith
  • Patent number: 4157947
    Abstract: Compositions of urethane derivatives of acrylated epoxidized soybean oil, which are the reaction products of an organic isocyanate with the reaction product of epoxidized soybean oil with acrylic acid or methacrylic acid, and an acrylyl compound are useful as coatings and inks; photosensitizers and/or pigments can optionally be present. The compositions can be cured by radiation.
    Type: Grant
    Filed: March 22, 1973
    Date of Patent: June 12, 1979
    Assignee: Union Carbide Corporation
    Inventors: George W. Borden, Oliver W. Smith, David J. Trecker
  • Patent number: 4157321
    Abstract: Copolymer of an ethylenically unsaturated organic monomer and an unsaturated organosilane monomer is stabilized against viscosity increase and gelation by the addition thereto of a monomeric hydrolytically reactive compound chosen from the group consisting of (i) monomeric hydrolytically reactive organosilanes and (ii) trialkyl orthoformates; and an alkyl alcohol.
    Type: Grant
    Filed: July 18, 1978
    Date of Patent: June 5, 1979
    Assignee: Union Carbide Corporation
    Inventors: James H. Kawakami, Robert J. Ward, Neil J. McCarthy
  • Patent number: 4156072
    Abstract: A process for producing polyesters and copolyesters, useful for making films and fibers, by the polycondensation of dicarboxylic acids and aliphatic glycols using coordinations complexes of metal halides and silicon compounds as catalysts.
    Type: Grant
    Filed: May 22, 1978
    Date of Patent: May 22, 1979
    Assignee: Union Carbide Corporation
    Inventors: Kurt Weinberg, Gordon C. Johnson
  • Patent number: 4153778
    Abstract: The reaction produces of (A) polyoxytetramethylene diols or polycaprolactone polyols, (B) diisocyanates and (C) di- or tri-methylol carboxylic acids are capped with (D) certain defined acrylyl compounds to produce terminally unsaturated oligomers that readily cure by thermal or radiation means to soft, tack-free products. The oligomers can be used as coatings; binders and adhesives.
    Type: Grant
    Filed: March 30, 1978
    Date of Patent: May 8, 1979
    Assignee: Union Carbide Corporation
    Inventors: Kisoon Park, George M. Bryant, Frazier G. Carr
  • Patent number: 4151056
    Abstract: Alkanediones or cycloalkanediones are employed as low-toxicity constituents in radiation curable coating compositions.
    Type: Grant
    Filed: September 29, 1977
    Date of Patent: April 24, 1979
    Assignee: Union Carbide Corporation
    Inventor: Kisoon Park
  • Patent number: 4151055
    Abstract: Compositions containing poly(vinyl alkyl ether), multifunctional acrylates, and optionally, monoacrylates and photoinitiators, when cured by exposure to radiation, produce pressure sensitive adhesives having good adhesive properties, such as peel strength, quick stick and shear time.
    Type: Grant
    Filed: April 5, 1976
    Date of Patent: April 24, 1979
    Assignee: Union Carbide Corporation
    Inventors: Kenneth C. Stueben, Raymond G. Azrak, Michael F. Patrylow
  • Patent number: 4146585
    Abstract: Novel compounds comprising organic copolymer or terpolymer backbones having pendent hydrolyzable organosilicon groups bonded thereto, are disclosed. Treatment of inorganic oxide surfaces with the novel compounds renders them adherent to and/or compatible with resinous media.
    Type: Grant
    Filed: March 2, 1977
    Date of Patent: March 27, 1979
    Assignee: Union Carbide Corporation
    Inventors: Robert J. Ward, Richard J. Burns
  • Patent number: 4143057
    Abstract: A process for producing polyesters and copolyesters, useful for making films and fibers, by the polycondensation of dicarboxylic acids and aliphatic glycols using coordinations complexes of metal halides and silicon compounds as catalysts.
    Type: Grant
    Filed: February 28, 1977
    Date of Patent: March 6, 1979
    Assignee: Union Carbide Corporation
    Inventors: Kurt Weinberg, Gordon C. Johnson
  • Patent number: 4143013
    Abstract: Tetraethylorthosilicate or tetraethoxyethylorthosilicate is employed as a low-toxicity diluent in radiation curable coating compositions containing acrylyl or methacrylyl functional oligomer. The orthosilicate compound imparts improved leveling and surface characteristics to said coating compositions.
    Type: Grant
    Filed: February 22, 1978
    Date of Patent: March 6, 1979
    Assignee: Union Carbide Corporation
    Inventors: Richard D. Jenkinson, Charles H. Carder
  • Patent number: 4139514
    Abstract: Aqueous, translucent to clear, water-borne vehicles of emulsion polymerized mixture of acrylic acid or methacrylic acid, an acrylate ester and, optionally, a styrene compound. Blends thereof with latexes and clear and pigmented compositions thereof.
    Type: Grant
    Filed: June 29, 1977
    Date of Patent: February 13, 1979
    Assignee: Union Carbide Corporation
    Inventor: David R. Bassett
  • Patent number: 4137279
    Abstract: Mixtures of the unsaturated maleic anhydride modified adduct of a polycaprolactone polyol and an ethylenically unsaturated monomer are copolymerized. The resulting polymers are useful as coatings or in the production of films and shaped molded articles.
    Type: Grant
    Filed: December 27, 1977
    Date of Patent: January 30, 1979
    Assignee: Union Carbide Corporation
    Inventors: Oliver W. Smith, Joseph V. Koleske
  • Patent number: 4134841
    Abstract: Fiber lubricant compositions of enhanced heat stability comprise a nonhindered polyphenol stabilizer and a polyether lubricant.
    Type: Grant
    Filed: March 10, 1978
    Date of Patent: January 16, 1979
    Assignee: Union Carbide Corporation
    Inventors: Kisoon Park, Robert H. Lowery