Abstract: A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator a N-sulfonylazole of the formula ##STR1## where Z represents the number of carbon and nitrogen atoms necessary to complete a heterocyclic ring selected from the class consisting of pyrazole, pyrrole, triazole, and benzotriazole wherein said ring can be substituted with phenyl, alkyl of 1 to 10 carbon atoms, halogen, amino, cyano, nitro, alkoxy of 1 to 10 carbon atoms and R is an alkyl radical of 1 to 10 carbon atoms.Also described are dry blend compositions containing the bleach bath components.
Type:
Grant
Filed:
July 30, 1979
Date of Patent:
October 28, 1980
Assignee:
FMC Corporation
Inventors:
Joseph H. Finley, Gaylen R. Brubaker, Burton M. Baum
Abstract: A method of opening tapholes in a phosphorus furnace through which molten slag and metal are periodically removed comprises shooting one or more slugs into the taphole to fracture and break out the solidified material.
Abstract: The storage level of ore, supplied by an overhead loader to a bin or pile in the form of large, dense, hard fragments, up to a foot or more in diameter, is measured and controlled by repetitively lowering a line carrying a weight, having a mass at least as great as the largest ore fragments, from above the stored mass to the surface of the stored mass and measuring the distance traveled by the weight. Feed of ore is automatically stopped when maximum allowable level of stored mass is detected. Measurement of ore level is accomplished by counting, during the lowering of the weight, the pulses generated by a pulse generator operated by the turning of a winch upon which the line is reeled. The contact of the lowered weight with the stored ore mass is detected by the slowing of the rate of pulse generation as the weight ceases falling under the influence of gravity and the winch therefore ceases turning.
Type:
Grant
Filed:
September 5, 1978
Date of Patent:
August 26, 1980
Assignee:
Intermountain Research and Development Corporation
Abstract: Novel sulfate salts of C.sub.10 -C.sub.20 linear alkyl glyceryl ether alcohols, useful as biodegradable surfactants in detergent compositions, are prepared by reacting a stoichiometric excess of C.sub.10 -C.sub.20 linear alkyl alcohol with glycidol predissolved in hexyl acetate, to selectively produce C.sub.10 -C.sub.20 linear alkyl glyceryl ether alcohols containing 1-3 glyceryl units, sulfating said ether alcohols, and neutralizing the sulfates with base.
Abstract: A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator an heterocyclic sulfonate ester wherein the heterocyclic moiety includes a 5 to 6 membered heterocyclic ring containing 1 to 3 hetero atoms selected from the class consisting of --N--, --O-- and --S-- and the sulfonic acid is selected from the class consisting of an alkanesulfonic acid of 1 to 18 carbon atoms and an arenesulfonic acid of the benzene and naphthalene series.Also described are dry blend compositions containing the activator and peroxygen.
Abstract: Diallyl maleate in combination with alkyl phosphates, including mixed alkyl aryl phosphates, when added to styrene-unsaturated polyester resin systems and cured with a free-radical forming initiator provides a high level of flame resistance.
Abstract: A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator an organophosphorus chlorine compound selected from the class consisting of R.sub.1 OR.sub.2 OP(O)Cl, R.sub.1 R.sub.2 OP(O)Cl and R.sub.1 R.sub.2 P(O)Cl, wherein R.sub.1 and R.sub.2 represent the organic portion of the molecule.
Abstract: A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator an imidoyl compound of the formula ##STR1## wherein R.sub.1 is an organic radical selected from the group consisting of hydrogen; an aliphatic radical of 1 to 18 carbon atoms; an aromatic radical of the benzene and naphthalene series and a heterocyclic radial of 1 to 2 rings each containing 5 to 6 members of which 1 to 3 are heteroatoms selected from the class consisting of nitrogen, oxygen and sulfur; R.sub.2 is an organic radical selected from the group consisting of R.sub.1 and -OR wherein R is equal to R.sub.1 except for hydrogen and X is a leaving group, said radicals or leaving groups bearing non-interfering substituents.Also described are dry bleach compositions containing the bleach bath components.
Abstract: A plasticizing composition for polyvinyl chloride resin is prepared by mixing from about 20 to about 50 parts by weight of tris(alkoxyalkyl)phosphate having the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are alkoxyalkyl radicals having the formula: ##STR2## wherein n is an integer from 1 to 18; x is an integer from 1 to 2;R' is either hydrogen or an alkyl radical, andR" is either hydrogen or an alkyl radical;in combination with from about 80 to about 50 parts by weight of another phosphate ester selected from the group consisting triaryl phosphate, alkyl diphenyl phosphate, trialkyl phosphate, tris(alkylphenyl)phosphate, alkylphenyl/phenyl phosphate, and mixture thereof. Polyvinyl chloride resins plasticized with 30 or more parts per hundred of such phosphate ester plasticizer mixtures are heat stable, fire resistant and flexible at low temperatures.
Abstract: A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator a N-sulfonylazole of the formula ##STR1## where Z represents the number of carbon and nitrogen atoms necessary to complete a heterocyclic ring selected from the class consisting of pyrazole, pyrrole, triazole, and benzotriazole wherein said ring can be substituted with phenyl, alkyl of 1 to 10 carbon atoms, halogen, amino, cyano, nitro, alkoxy of 1 to 10 carbon atoms and R is an alkyl radical of 1 to 10 carbon atoms.Also described are dry blend compositions containing the bleach bath components.
Type:
Grant
Filed:
October 10, 1978
Date of Patent:
June 10, 1980
Assignee:
FMC Corporation
Inventors:
Joseph H. Finley, Gaylen R. Brubaker, Burton M. Baum
Abstract: Diallyl maleate in combination with triethyl phosphate, when added to styrene-unsaturated polyester resin systems and cured with a free-radical forming initiator provides a high level of flame resistance.
Abstract: A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator a carbodiimide of the formula:R.sub.1 --(X).sub.n-1 --N.dbd.C.dbd.N--(X').sub.n-1 --R.sub.2wherein R.sub.1 and R.sub.2 each represent alkyl of 1 to 16 carbon atoms; cycloalkyl of 3 to 7 carbon atoms; phenyl; lower alkylphenyl; lower alkylnaphthyl; naphthyl and heterocyclic of 1 to 2 fused rings each having 5 to 6 members of which 1 to 2 are heteroatoms selected from the class consisting of nitrogen, oxygen and sulfur, it being provided that the aforesaid values of R.sub.1 and R.sub.2 may bear optional substituents selected from the group consisting of --NO.sub.2, --Cl, --Br, alkoxyl, amino, cyano, hydroxyl, --O--, --NH--, quaternary nitrogen, --SO.sub.3 H and --COOH.Also described are dry blend compositions containing the activator and peroxygen.
Abstract: A process for removing arsenic from aqueous mediums by adding, in the presence of phosphorus, sufficient calcium hydroxide to adjust the aqueous medium to a pH of from about 7.0 to 11.5, whereby precipitates of both arsenic and phosphorus are formed and are subsequently separated from the aqueous medium. As a secondary treatment, calcium salts of arsenic and phosphorus in oxidation states lower than +5, and thus dissolved in the aqueous medium are oxidized, as by the addition of chlorine or hypochloride to such medium, and thereby converted to more insoluble forms which are separated from the aqueous medium as precipitates.
Abstract: A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator an N-acyl-cyano cyclic amine selected from the class consisting of ##STR1## wherein R is a hydrocarbon radical selected from the group consisting of aliphatic of 1 to 18 carbon atoms and aromatic of the benzene and naphthalene series and X is selected from the class consisting of --C(O)-- and --S(O.sub.2)--, it being provided that the cyclic amine may contain a non-interfering substituent.Also described are dry blend compositions containing the activator and peroxygen.
Abstract: Anhydrous sodium carbonate is crystallized from saturated aqueous sodium carbonate solutions at temperatures in the range of 104.degree. to below 109.degree. C. by adding to the solution very small proportions of additives which function to reduce the transition temperature of monohydrate to anhydrous sodium carbonate.
Abstract: Off gases from electric furnace production of phosphorus, consisting essentially of carbon monoxide and phosphine, are heated to 700.degree.-800.degree. C. to decompose the phosphine to red phosphorus and hydrogen; the red phosphorus is separated from the gas--most desirably by passing the gas through aqueous hydrogen peroxide which oxidizes the phosphorus to phosphoric acid,--to obtain a clean gas which can be used as a fuel.
Abstract: In the manufacture of zeolite A crystals, characterized by a size in the range of about 1 to about 10 .mu.m (micrometers or microns) the crystal size is controlled to within the range of .+-. 1 .mu.m by seeding a sodium aluminum silicate gel that is free of nucleating particles with a predetermined number of comminuted zeolite A crystals having a number average particle size less than about 0.5 .mu.m.
Abstract: Peroxycarboxylic acids are prepared by the oxidation of a fatty acid with an excess of hydrogen peroxide in the presence of a strong acid catalyst. The yield is improved and the reaction time is reduced by intimately dispersing throughout the reaction mixture an inert water immiscible solvent for the peroxycarboxylic acid. The product may be recovered in crystalline form from the solvent phase.
Abstract: A turbine lubricant having outstanding oxidation stability, corrosion resistance and good viscosity stability is based on an alkyl phenyl phosphate ester and contains small amounts of benzotriazole, a mixed mono- and dialkylphosphate of the formula RH.sub.2 PO.sub.4 and R.sub.2 HPO.sub.4, wherein R is an alkyl group of 8-12 carbon atoms, and an antioxidant selected from the group consisting of:(a) a C.sub.12 to C.sub.18 alcohol ester of 3,3'-thiodipropionic acid;(b) pentaerythritol tetra(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, and(c) 4,4'-thiobis-(3-methyl-6-tert-butylphenol).
Abstract: A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator, an anhydride of a carboxylic acid with a sulfonic acid selected from the formulae consisting ofR.sub.1 --(SO.sub.2 OC(O)--R.sub.2).sub.n and (R.sub.1 --SO.sub.2 OC(O)).sub.n R.sub.2wherein n is an integer of 1 to 3; each of R.sub.1 and R.sub.2, which may be alike or different, is selected from the class consisting of a 1 to 3 valent hydrocarbon radical derived from an alkane of 1 to 16 carbon atoms, a cycloalkane of 3 to 7 carbon atoms and an arene of 6 to 12 aromatic carbon atoms while taken together R.sub.1 and R.sub.
Type:
Grant
Filed:
April 10, 1978
Date of Patent:
October 9, 1979
Assignee:
FMC Corporation
Inventors:
Joseph H. Finley, John H. Blumbergs, Clifford A. Erickson