Patents Represented by Attorney, Agent or Law Firm Frank P. Mallak
  • Patent number: 5869658
    Abstract: Described are novel photochromic indeno-fused naphthopyran compounds having certain substituents at the 2-position of the pyran ring and an alkoxy group at the number 6 carbon atom. Certain other substituents may also optionally be present at the number 5, 7, 8, 9, 10, 11, 12 or 13 carbon atoms of the compounds. These compounds may be represented by the following graphic formula: ##STR1## Also described are certain novel indeno-fused naphthols which are used to make the novel naphthopyran compounds. Further described are polymeric organic host materials that contain or that are coated with the novel naphthopyran compounds, or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, benzopyrans, and spiro(indoline)type compounds.
    Type: Grant
    Filed: December 15, 1997
    Date of Patent: February 9, 1999
    Assignee: PPG Industries, Inc.
    Inventors: Jibing Lin, Barry Van Gemert
  • Patent number: 5811034
    Abstract: Described are novel 7-methylidene-5-oxo-furo fused naphthopyran compounds having certain substituents at the 2 position of the pyran ring. Also described are polymeric organic host materials that contain or that are coated with such compounds.
    Type: Grant
    Filed: October 23, 1997
    Date of Patent: September 22, 1998
    Assignee: PPG Industries, Inc.
    Inventor: Jibing Lin
  • Patent number: 5808063
    Abstract: Described are novel photochromic spiro(indoline) fluoranthenoxazine compounds having certain substituents on the 1 and 3 positions of the indoline portion of the compounds and which may be represented by the following graphic formula: ##STR1## Also described are polymeric organic host materials that contain or that are coated with such compounds.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: September 15, 1998
    Assignee: PPG Industries, Inc.
    Inventor: Anil Kumar
  • Patent number: 5798860
    Abstract: Describes an electrochromically active iridium oxide film of iridium, oxygen and nitrogen, wherein the ratio of atomic oxygen to iridium is from 3.2:1 to 3.4:1 and the amount of nitrogen in the film is from 11 to 13 atomic percent. Describes also an electrochromic article, e.g., a plastic article such as a plastic lens, in which the aforedescribed iridium oxide film is paired with a cathodically coloring electrochromic film, such as tungsten oxide.
    Type: Grant
    Filed: January 14, 1997
    Date of Patent: August 25, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Phillip C. Yu, David L. Backfisch, Nada A. O'Brien, Bryant P. Hichwa
  • Patent number: 5783116
    Abstract: Described are novel pentahydrophenanthro?9,10-b!pyrans and tetrahydrocyclopenta?c!-naphtho?1,2-b!pyrans. Also described are polymeric organic host materials that contain or that are coated with such compounds.
    Type: Grant
    Filed: October 16, 1997
    Date of Patent: July 21, 1998
    Assignee: PPG Industries, Inc.
    Inventor: Jibing Lin
  • Patent number: 5770115
    Abstract: Describes a composition of a carrier, e.g., organic solvent or polymeric host material, photochromic naphthopyran material, and a stabilizer system comprising (a) polyphenolic antioxidant material, (b) ultraviolet light absorber and (c) hindered amine light stabilizer for said photochromic naphthopyran material. The stabilizer system is selected and used in amounts sufficient to provide at least a 30% reduction in % photopic fatigue of the naphthopyran material. The weight ratio of photochromic naphthopyran to the stabilizer system is from 2.5:1 to 1.5:1. The stabilizer system can comprise 5 to 50 weight percent of the antioxidant material, 5 to 50 weight percent of the ultraviolet light absorbent, and 10 to 90 weight percent of the hindered amine light stabilizer.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: June 23, 1998
    Assignee: PPG Industries, Inc.
    Inventor: Michael S. Misura
  • Patent number: 5753146
    Abstract: Described are novel compositions of a carrier and at least two photochromic naphthopyran compounds, selected on the basis of specific criteria, that when exposed to solar ultraviolet radiation, exhibit neutral colors of gray or brown contained within the a* and b* ranges of +10 to -10 in the CIELAB color system. Also described are carriers, i.e., organic solvents and organic polymeric host materials, such as optically clear articles, e.g., ophthalmic lenses or other plastic transparencies that contain or that are coated with the naphthopyran compounds.
    Type: Grant
    Filed: March 29, 1996
    Date of Patent: May 19, 1998
    Assignee: Transitions Optical, Inc.
    Inventors: Barry Van Gemert, Delbert G. Kish
  • Patent number: 5744243
    Abstract: Describes a composition for producing durable coatings and a process for preparing a single-layer broad band antireflective coating on solid substrates, such as glass, ceramics, metals, and organic polymeric materials. The coating composition comprises, in combination, acid catalyzed hydrolysis and condensation products of water-silane monomer mixture and a film forming amount of a polymer having functional groups selected from amino, hydroxy and carboxy, hydroxy and amino, amino and carboxy, and amino, hydroxy and carboxy. The described process comprises applying the aforesaid coating composition (or an acid catalyzed sol-gel coating composition) substantially free of preformed oxide sol and water soluble metal salt to the surface of a solid substrate, curing the applied coating, and treating the cured coating with an aqueous electrolyte solution for a time sufficient to produce a coating having graded porosity which is antireflective over a broad band of the visible spectrum.
    Type: Grant
    Filed: September 10, 1996
    Date of Patent: April 28, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Huawen Li, Alan E. Wang, Suryya K. Das
  • Patent number: 5744070
    Abstract: Described are novel reversible photochromic naphthopyran compounds, examples of which are 3H-naphtho?2,1-b!pyrans having an acyl or aroyl oxy-bearing substituent at the number 6 carbon atom and certain substituents at the 3-position of the pyran ring. Certain substituents may also be present at the number 5, 7, 8, 9 or 10 carbon atom of the naphthopyran. These compounds may be represented by the following graphic formula: ##STR1## Also described are polymeric organic host materials that contain or that are coated with such compounds. Optically clear articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, benzopyrans, and spiro(indoline)type compounds, are also described.
    Type: Grant
    Filed: December 20, 1995
    Date of Patent: April 28, 1998
    Assignee: Transitions Optical, Inc.
    Inventor: Anil Kumar
  • Patent number: 5723072
    Abstract: Described are novel photochromic heterocyclic fused indenonaphthopyran compounds having a substituted or unsubstituted heterocyclic ring fused to the g, h, i, n, o or p side of the indenonaphthopyran. These compounds may be represented by either of the following graphic formulae: ##STR1## Also described are polymeric organic host materials that contain or that are coated with such compounds.
    Type: Grant
    Filed: March 18, 1997
    Date of Patent: March 3, 1998
    Assignee: PPG Industries, Inc.
    Inventor: Anil Kumar
  • Patent number: 5718801
    Abstract: Describes flotation deinking of secondary fiber using a froth moderating agent, a composition of the froth moderating agent with flotation deinking chemicals, and reducing the amount of stickies in separated secondary fiber. The froth moderating agent is selected from the group consisting of:(a) nonionic surfactant material represented by the formula:R--C.sub.6 H.sub.4 O--(C.sub.2 H.sub.4 O).sub.m --(C.sub.3 H.sub.6 O).sub.n --(C.sub.4 H.sub.8 O).sub.p --R.sup.1wherein R is an aliphatic hydrocarbon group containing from about 5 to 20 carbon atoms, R.sup.1 is selected from the group consisting of chloro, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: February 17, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Chin Li, David A. Longhini, Bhima R. Vijayendran
  • Patent number: 5716419
    Abstract: Mineral salts, e.g., potassium chloride, are crystallized from aqueous solutions thereof in the presence of a crystal growth promoting amount of lecithin or lecithin containing compositions. Mineral salts include alkali metal and alkaline-earth metal chloride, sulfate, carbonate, phosphate and nitrate salts. The process is described as providing increased amounts of large crystals and a narrower and more uniform crystal size distribution.
    Type: Grant
    Filed: July 31, 1996
    Date of Patent: February 10, 1998
    Assignee: PPG Industries, Inc.
    Inventor: David A. Larsen
  • Patent number: 5698141
    Abstract: Described are novel photochromic heterocyclic fused indenonaphthopyran compounds having a substituted or unsubstituted heterocyclic ring fused to the g, h, i, n, o or p side of the indenonaphthopyran. These compounds may be represented by either of the following graphic formulae: ##STR1## Also described are polymeric organic host materials that contain or that are coated with such compounds.
    Type: Grant
    Filed: January 16, 1997
    Date of Patent: December 16, 1997
    Assignee: PPG Industries, Inc.
    Inventor: Anil Kumar
  • Patent number: 5674432
    Abstract: Described are novel reversible photochromic diaryl-3H-naphtho?2,1-b!pyran compounds having a substituted or unsubstituted, five or six member heterocyclic ring fused to the g, i, or l side of the naphthopyran. The heterocyclic ring contains an oxygen or nitrogen atom and is attached to the number 5, 6, 7, 8, 9, or 10 carbon atom of the naphtho portion of the naphthopyran. Also described are organic host materials containing such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(indoline)oxazine-type compounds, are also described.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: October 7, 1997
    Assignee: Transitions Optical, Inc.
    Inventors: David B. Knowles, Barry Van Gemert
  • Patent number: 5660684
    Abstract: Describes a composition for use in flotation deinking of secondary fiber containing electrostatic ink and/or stickies and optionally conventional impact ink. The composition consists essentially of displector deinking chemicals having an HLB value greater than 10 and non-ionic surfactant deinking additives such as (i) capped aliphatic and alicyclic alkoxylates, e.g., chloride capped C.sub.5 -C.sub.20 alkyl ethoxylates, (ii) alkyl phenol ethoxylates, e.g., octyl phenol ethoxylates, and (iii) a combination of (i) and (ii). Also described is a method for using the composition in a deinking process that includes a flotation step.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: August 26, 1997
    Assignee: PPG Industries, Inc.
    Inventors: Chin Li, David A. Longhini
  • Patent number: 5658500
    Abstract: Described are novel reversible photochromic 2H-naphtho[1,2-b]pyran compounds, examples of which are compounds having certain substituents at the number 5 carbon atom of the naphtho-portion of the naphthopyran and at the 2-position of the pyran ring. Certain substituents may also be present at the number 6, 7, 8, 9 or 10 carbon atoms of the naphtho portion of the naphthopyran. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(indoline) type compounds, are also described.
    Type: Grant
    Filed: June 14, 1995
    Date of Patent: August 19, 1997
    Assignee: Transitions Optical, Inc.
    Inventors: Anil Kumar, David B. Knowles, Barry Van Gemert
  • Patent number: 5658501
    Abstract: Described are novel reversible photochromic 2H-naphtho[1,2-b] pyran compounds, examples of which are compounds having certain substituents at the number 5 carbon atom of the naphtho-portion of the naphthopyran and at the 2-position of the pyran ring. Certain substituents may also be present at the number 6, 7, 8, 9 or 10 carbon atoms of the naphtho portion of the naphthopyran. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(indoline) type compounds, are also described.
    Type: Grant
    Filed: June 14, 1995
    Date of Patent: August 19, 1997
    Assignee: Transitions Optical, Inc.
    Inventors: Anil Kumar, David B. Knowles, Barry Van Gemert
  • Patent number: 5656206
    Abstract: Described are novel reversible photochromic 2H-naphtho[1,2-b]pyran compounds, examples of which are compounds having certain substituents at the number 5 carbon atom of the naphtho portion of the naphthopyran and at the 2-position of the pyran ring. Certain substituents may also be present at the number 6, 7, 8, 9 or 10 carbon atoms of the naphtho portion of the naphthopyran. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(indoline) type compounds, are also described.
    Type: Grant
    Filed: June 14, 1995
    Date of Patent: August 12, 1997
    Assignee: Transitions Optical, Inc.
    Inventors: David B. Knowles, Barry Van Gemert, Anil Kumar
  • Patent number: 5651923
    Abstract: Described are novel reversible photochromic 2H-naphtho[1,2-b]pyran compounds, examples of which are compounds fused on the naphtho-portion of the naphthopyran ring with an indeno group or certain heterocyclic substituents. Certain substituents are also present at the 2 and 5 positions and sometimes at the 6 position of the naphthopyran ring. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(indoline) type compounds, are also described.
    Type: Grant
    Filed: December 12, 1995
    Date of Patent: July 29, 1997
    Assignee: Transitions Optical, Inc.
    Inventors: Anil Kumar, David B. Knowles, Barry Van Gemert
  • Patent number: 5650098
    Abstract: Described are novel reversible photochromic 2H-naphtho[1,2-b]pyran compounds, examples of which are compounds having certain substituents at the 5 and 6-positions of the naphtho portion of the naphthopyran and at the 2-position of the pyran ring, e.g., 2,2-bis(4-methoxy phenyl)-5-methoxycarbonyl-6-morpholino-2H-naphtho[1,2-b]pyran. Certain substituents may also be present at the number 7, 8, 9 or 10 carbon atoms of the naphtho portion of the naphthopyran. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(indoline) type compounds, are also described.
    Type: Grant
    Filed: October 13, 1995
    Date of Patent: July 22, 1997
    Assignee: Transitions Optical, Inc.
    Inventors: Anil Kumar, David B. Knowles, Barry Van Gemert