Patents Represented by Attorney Fred C. Philpitt
  • Patent number: 4804297
    Abstract: A method of formless underwater casting of cement is disclosed. The method involves the addition of silicate to water in which a structure bound with Portland cement or high-alumina cement is to be cast. The cementitious mixture as a slurry is then poured into the water to form a structure. The silicate and cementitious mixture can be placed in the water at the same time using concentric nozzle systems.
    Type: Grant
    Filed: October 8, 1987
    Date of Patent: February 14, 1989
    Assignee: PQ Corporation
    Inventors: Richard H. Reifsnyder, Robert W. Spencer, Robert A. Brennan
  • Patent number: 4797294
    Abstract: Combinations of silica gel and magnesium silicate have been found to be effective agents to prevent the formation of haze in beer. Said haze, often called chill haze, is prevented by contacting the ruh beer with the combination to remove some or all of the components that react to form the haze. The spent combination is removed from the beer in the usual manner.
    Type: Grant
    Filed: June 29, 1987
    Date of Patent: January 10, 1989
    Assignee: PQ Corporation
    Inventor: Kenneth A. Berg
  • Patent number: 4766000
    Abstract: The components of chill haze in beer can be removed by contacting said beer with a combination of silica hydrogel and partially hydrophobic adsorbent(s) for a time sufficient to complete adsorption of the components and removing said adsorbents from the beer.
    Type: Grant
    Filed: June 8, 1987
    Date of Patent: August 23, 1988
    Assignee: PQ Corporation
    Inventor: Michael T. Sobus
  • Patent number: 4752341
    Abstract: Zeolite of a small controlled particle size has been found to be a pigment component to be used with TiO.sub.2 in papermaking. Zeolite A wherein the sodium has been at least partially replaced with calcium and/or hydronium ion is widely useful with TiO.sub.2 in papermaking.
    Type: Grant
    Filed: June 1, 1987
    Date of Patent: June 21, 1988
    Assignee: PQ Corporation
    Inventor: Steven L. Rock
  • Patent number: 4741865
    Abstract: Polymer systems can be rendered flame retardant by adding a source of halogen and particles of antimony pentoxide that have been dried from colloidal dispersions that have been treated with certain metal ions. The properties of the polymer are conserved when the colloidal dispersion is treated with ions of metals that have insoluble antimonates before drying to form a powder.
    Type: Grant
    Filed: May 7, 1986
    Date of Patent: May 3, 1988
    Assignee: Nyacol Products, Inc.
    Inventors: Donald P. Kintz, Stephen N. Davis
  • Patent number: 4704424
    Abstract: Various type A zeolites can be combined with thermoplastic materials to provide antiblock and improved optical properties to films or sheets of said thermoplastic. The zeolites are of less than full hydration, and at least a portion of the sodium is replaced with multivalent ions such as calcium and magnesium. The zeolites can also be acid treated to provide zeolites that contain hydronium ions.
    Type: Grant
    Filed: May 21, 1986
    Date of Patent: November 3, 1987
    Assignee: PQ Corporation
    Inventor: Bruce W. Sands
  • Patent number: 4667650
    Abstract: A self-dressing mounting beam for slicing wafers from ingots of various materials, especially semiconductors, is described. The mounting beam is a composite material comprising an organic polymer, particles of abrasive and hollow microspheres. The ingot is mounted on the beam and sliced using an inside diameter saw. The saw penetrates the mounting beam as well as the ingot, so that the self-dressing feature is realized with each pass of the blade.
    Type: Grant
    Filed: November 21, 1985
    Date of Patent: May 26, 1987
    Assignee: PQ Corporation
    Inventors: Richard T. Girard, John R. McLaughlin
  • Patent number: 4664728
    Abstract: Water-based explosives that use siliceous boron-containing microspheres as sensitizing agents are stabilized by adding multivalent metal ions to the explosives. Zinc salts are especially useful.
    Type: Grant
    Filed: November 21, 1985
    Date of Patent: May 12, 1987
    Assignee: PQ Corporation
    Inventors: James P. Cunnion, Jr., Bruce W. Sands
  • Patent number: 4631193
    Abstract: The components of chill haze in beer can be removed by contacting said beer with a combination of silica hydrogel and gelatin for a time sufficient to complete adsorption of the components and removing said adsorbents from the beer.
    Type: Grant
    Filed: August 26, 1985
    Date of Patent: December 23, 1986
    Assignee: PQ Corporation
    Inventor: Michael T. Sobus
  • Patent number: 4626550
    Abstract: Self-warming personal care products such as lotions, creams and pastes can be prepared using Zeolite A that contains both sodium and potassium.
    Type: Grant
    Filed: October 7, 1985
    Date of Patent: December 2, 1986
    Assignee: PQ Corporation
    Inventor: Elliot P. Hertzenberg
  • Patent number: 4563441
    Abstract: Inorganic chill-proofing and other agents that are used to process stable beer often contain metals such as iron and copper that are soluble in beer or other beverages. A small addition of magnesium silicate added to said chill-proofing agents, particularly silica hydrogel, substantially averts metal contamination in the beer.
    Type: Grant
    Filed: December 3, 1984
    Date of Patent: January 7, 1986
    Assignee: PQ Corporation
    Inventors: John R. McLaughlin, Elliot P. Hertzenberg
  • Patent number: 4540629
    Abstract: Hollow microspheres of reduced surface energy and reactivity and of improved packing and sphericity are prepared by simultaneously forming said microspheres and reacting them with an organosilicon compound. The microspheres are prepared by spray drying a solution of alkali metal silicate and a "polysalt." The organosilicon is present as the microspheres are formed, penetrates and reacts to form a shell consisting of a silicate, polysalt and the organosilicon compound. The resulting product is more discrete, more free-flowing, has better packaging characteristics, improved packing factor and improved filler properties when compared to prior-art microspheres.
    Type: Grant
    Filed: February 27, 1984
    Date of Patent: September 10, 1985
    Assignee: PQ Corporation
    Inventors: Bruce W. Sands, Robert J. Nehring, Jr.
  • Patent number: 4528276
    Abstract: Alkali metal silicates and zeolites can be agglomerated to form granules that are of particular value in detergents. These agglomerates are formed when hydrated alkali metal silicate particles are tumbled with hydrated zeolites of small particle size while moisture and then heat are introduced to achieve granulation. The product is a free-flowing granular material has numerous desirable characteristics for detergents.
    Type: Grant
    Filed: January 3, 1983
    Date of Patent: July 9, 1985
    Assignee: PQ Corporation
    Inventors: Thomas C. Cambell, Howard S. Sherry, George C. Schweiker, James S. Falcone, Jr., Robert H. Sams, deceased
  • Patent number: 4508856
    Abstract: Polymers that are stable under aqueous conditions of high ionic strength are combined with non-fused, silicate based microspheres that are modified with multivalent metals but not washed or dried, said microspheres being present as filters.
    Type: Grant
    Filed: October 28, 1983
    Date of Patent: April 2, 1985
    Assignee: PQ Corporation
    Inventors: Christopher G. Smith, John F. Peters
  • Patent number: 4508742
    Abstract: Inorganic chill-proofing and other agents that are used to process stable beer often contain metals such as iron and copper that are soluble in beer or other beverages. A small addition of magnesium silicate added to said chill-proofing agents, particularly silica hydrogel, substantially averts metal contamination in the beer.
    Type: Grant
    Filed: May 6, 1983
    Date of Patent: April 2, 1985
    Assignee: PQ Corporation
    Inventors: John R. McLaughlin, Elliot P. Hertzenberg
  • Patent number: 4474594
    Abstract: Forming discrete bodies such as briquettes of glass forming raw materials is often advantageous in melting such materials to form said glasses. Such discrete bodies are formed by combining the particulate raw materials with a liquid binder and compressing the combination. This process is improved by using a dilute silicate solution as the liquid binder and by adding the maximum amount of the silicate solution to the raw materials that still provides a free-flowing dry appearing material. This amount of silicate solution results in a maximum crush strength when the discrete bodies are prepared.
    Type: Grant
    Filed: February 14, 1983
    Date of Patent: October 2, 1984
    Assignee: PQ Corporation
    Inventor: Frank J. Lazet
  • Patent number: 4421562
    Abstract: More perfect, less porous hollow microspheres can be prepared by spray-drying dispersions of alkali metal silicate and "polysalt" that contain certain organic liquids. The organics are water-miscible and have boiling points of 100.degree. C. or more. The solvent is added just prior to spray drying and the resulting product has fewer cracks and/or holes.
    Type: Grant
    Filed: March 23, 1983
    Date of Patent: December 20, 1983
    Assignee: PQ Corporation
    Inventor: Bruce W. Sands
  • Patent number: 4420442
    Abstract: More perfect, less porous hollow microspheres can be prepared by spray-drying dispersions of film-forming solids that contain certain organic solvents. The organic solvents are water-miscible and have boiling points of 100.degree. C. or more. The solvent is added just prior to spray drying and the resulting product has fewer cracks and/or holes. This improvement is especially beneficial to preparation systems involving alkali metal silicates and "polysalts.
    Type: Grant
    Filed: September 21, 1982
    Date of Patent: December 13, 1983
    Assignee: PQ Corporation
    Inventor: Bruce W. Sands
  • Patent number: 4411847
    Abstract: Non-fused hollow glass microspheres that consist primarily of silicate are rendered more water-resistant by treatment with multivalent metals. The hollow microspheres are slurried with water and then a solution of a multivalent metal salt such as Al.sub.2 (SO.sub.4).sub.3 is added to the slurry. The rate of the addition is controlled so that the pH can be regulated. Separating, washing and drying complete the preparation.
    Type: Grant
    Filed: May 27, 1982
    Date of Patent: October 25, 1983
    Assignee: PQ Corporation
    Inventors: David I. Netting, Bruce D. Spivack, James P. Cunnion, Jr.
  • Patent number: 4409158
    Abstract: Hollow fibers are prepared by spray drying a solution of a film-former in a volatile solvent. The viscosity of the solution must be 1.5 to 10 times the viscosity that usually results in spheres or microspheres. The preferred film-forming substance is a combination of sodium silicate and a "polysalt.
    Type: Grant
    Filed: April 2, 1982
    Date of Patent: October 11, 1983
    Assignee: PQ Corporation
    Inventor: Bruce D. Spivak