Abstract: Aromatic nitro compounds are disclosed where the aromatic ring contains electron-withdrawing groups and said aromatic nitro compound is capable of undergoing intramolecular nucleophilic displacement after reduction of the nitro group. The compounds are especially useful in photographic elements where an image dye-providing material or a photographic reagent are released upon cleavage from the compound.

Abstract: Photographic elements, processes for forming images in photographic elements and new compounds are disclosed. Generally, the invention relates to ballasted electron-accepting nucleophilic displacement compounds; after acceptance of at least one electron (reduction) by a nucleophile precursor group, the compounds are capable of undergoing intramolecular nucleophilic displacement to release a diffusible moiety, such as an image dye or a photographic reagent. In certain embodiments, the ballasted electron-accepting nucleophilic displacement compounds are used in combination with electron donors and electron-transfer agents. The processes disclosed are particularly useful in providing positive transfer images using negative-working silver halide emulsions.

Abstract: Photographic elements, processes for forming images in photographic elements and new compounds are disclosed. Generally, the invention relates to immobile compounds which can be used to provide positive images from negative recording-developing photographic materials such as negative silver halide emulsions. The compounds contain a photographically useful group such as a dye or dye precursor and are capable of releasing said photographically useful group under alkaline conditions, and are also capable of reaction with an oxidized silver halide developing agent before substantial release of said photographically useful group occurs, to provide a reaction product having a substantially lower rate of release of said photographically useful group. In specific embodiments, the compounds of this invention contain an electrophilic cleavage group located in the linkage between a ballast group and a photographically useful moiety wherein said electrophilic cleavage group is a carbamic acid derivative.

Abstract: Photographic elements are disclosed which contain a blocked development restrainer which is designed to provide timely release of a development restrainer when the photographic element is processed with an alkaline processing composition. The photographic elements are especially useful in image-transfer film units where the blocked development restrainers will permit initial development to occur and, upon cleavage, will substantially restrain further development.

Abstract: An improvement is provided in processes wherein an oxidation-reduction reaction is utilized to form an image. In one aspect of this invention, the improvement comprises employing an oxidizing agent and a reducing agent which undergo imagewise redox reaction in the presence of catalytic material, the oxidizing agent and the reducing agent being so chosen that the reaction products are noncatalytic for the oxidation-reduction reaction. In another aspect of this invention, a substitution inert metal complex is utilized as the oxidant in oxidation-reduction image-forming processes. In a specific aspect, image-transfer film units and processes of forming image records in image-transfer film units are disclosed wherein an inert transition metal complex and a reducing agent, which undergo redox reaction in the presence of a catalytic material, are present during processing of said film unit.

Abstract: An improvement is provided in processes wherein an oxidation-reduction reaction is utilized to form an image. In one aspect of this invention, the improvement comprises employing an oxidizing agent and a reducing agent which undergo imagewise redox reaction in the presence of catalytic material, the oxidizing agent and the reducing agent being so chosen that the reaction products are noncatalytic for the oxidation-reduction reaction. In another aspect of this invention, a substitution inert metal complex is utilized as the oxidant in oxidation-reduction, image-forming processes. Novel processing compositions and photographic materials are also described.

Abstract: Photographic elements, processes for forming images in photographic elements and new compounds are disclosed. Generally, the invention relates to immobile compounds which can be used to provide positive images from negative recording-developing photographic materials such as negative silver halide emulsions. The compounds contain a photographically useful group such as a dye or dye precursor and are capable of releasing said photographically useful group under alkaline conditions, and are also capable of reaction with an oxidized silver halide developing agent before substantial release of said photographically useful group occurs, to provide a reaction product having a substantially lower rate of release of said photographically useful group. In specific embodiments, the compounds of this invention contain an electrophilic cleavage group located in the linkage between a ballast group and a photographically useful moiety wherein said electrophilic cleavage group is a carbamic acid derivative.

Abstract: An improvement is provided in processes wherein an oxidation-reduction reaction is utilized to form an image. In one aspect of this invention, the improvement comprises employing an oxidizing agent and a reducing agent which undergo imagewise redox reaction in the presence of catalytic material, the oxidizing agent and the reducing agent being so chosen that the reaction products are noncatalytic for the oxidation-reduction reaction. In another aspect of this invention, a substitution inert metal complex is utilized as the oxidant in oxidation-reduction image-forming processes. Novel processing compositions and photographic materials are also described. In a specific aspect, this divisional application relates to processes for tanning a crosslinkable colloid with the reaction products of the above redox reaction.

Abstract: 4,4-Dihalo-5-pyrazolones react with unoxidized aromatic primary aromatic amines or alkyl or hydrazines to give azomethine dyes, azo dyes or hydrazones which are useful in photographic systems.

Abstract: Stabilized oxichromic compounds are disclosed, along with processes for stabilizing oxichromic compounds. In one aspect, the stabilized compounds are O-acylated compounds which contain a reduced azomethine linkage. In another aspect, the stabilized compounds are O-acylated compounds which can undergo base catalyzed chromogenic oxidation to produce a yellow dye.

Abstract: Oxichromic compounds which contain a reduced azomethine linkage are disclosed with processes for making same. In one aspect, the oxichromic compounds are N-stabilized compounds which have an acyl stabilizing group on the nitrogen atom of the reduced azomethine linkage. The compounds undergo chromogenic oxidation to produce dyes.

Abstract: Oxichromic compounds which contain a reduced azomethine linkage are disclosed with processes for making same. In one aspect, the oxichromic compounds are N-stabilized compounds which have an acyl stabilizing group on the nitrogen atom of the reduced azomethine linkage. The compounds undergo chromogenic oxidation to produce dyes.