Patents Represented by Attorney Gann G. Xu
  • Patent number: 8328410
    Abstract: The present invention is directed to an in-line mixer for mixing a plurality of fluids to produce a mixed product. The mixer includes one or more mixing chambers, an impeller in each of the mixing chambers, one or more inlets coupled to injection valves for conveying the fluids into the mixing chamber, and an outlet for conveying the mixed product out of the mixing chamber. The in-line mixer is well suited to components, such as those used in making automotive OEM and refinish paints.
    Type: Grant
    Filed: March 14, 2008
    Date of Patent: December 11, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventor: Antonio Retamal
  • Patent number: 8293321
    Abstract: A fast hardening clear coating composition for repairing a clear coat/color coat finish or a pigmented mono-coat of a vehicle comprising a film forming binder and an organic liquid carrier, where the binder contains a hydroxyl polymer component comprising (A) hydroxyl-containing acrylic polymer, (B) at least one hydroxyl-terminated component selected from the group consisting of (1) an organic diol having the formula where R1 and R2 are individually selected from the group of hydrogen and an alkyl group having 1, 3-5 carbon atoms and (2) a hydroxyl terminated reaction product of trimethylol propane and a lactone; (C) an organic polyisocyanate crosslinking component, at least portion of which comprises a trimer of isophorone diisocyanate or hexamethylene diisocyanate and the composition further contains, a curing catalyst, of a dialkyl tin aliphatic carboxylate, a tertiary aliphatic mono or diamine, an aliphatic carboxylic acid, and optionally, a zinc or calcium organic acid salt in an effective amount suc
    Type: Grant
    Filed: January 4, 2011
    Date of Patent: October 23, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Gia Huynh-Ba, Patrick Henry Corcoran
  • Patent number: 8270699
    Abstract: The present invention is directed to a method for obtaining appearance characteristics of a target coating containing effect pigments. The present invention is also directed to a method for comparing appearances of two or more coatings by comparing the appearance characteristics. The present invention is further directed to a system for obtaining appearance characteristics of one or more coatings and comparing said coating appearances.
    Type: Grant
    Filed: October 2, 2007
    Date of Patent: September 18, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Allan Blase Joseph Rodrigues, Arun Prakash, Judith Elaine Obetz
  • Patent number: 8210452
    Abstract: The present invention is directed to a delivery device and a system for introducing the catalyst into the atomized coating composition. This invention is also directed to a system for producing a mixed composition comprising two or more components.
    Type: Grant
    Filed: December 23, 2008
    Date of Patent: July 3, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: John Charles Larson, Alan Arthur Burmester
  • Patent number: 8131496
    Abstract: The present invention is directed to an apparatus and a method that characterizes the hiding of coating compositions, such as automotive OEM and refinishes paints. The method is directed to sequentially storing in a computing device hiding data obtained by measuring the color difference (?RGB) in reflections of light and dark portions of target areas of a monotonic coating resulting from a coating composition applied over hiding test panel and by measuring coating thicknesses of the monotonic coating that correspond to the target areas, classifying the type of the hiding data, selecting fitting equations applicable to the classified hiding data, fitting the selected equation to match the classified hiding data and locating a hiding thickness on the monotonic coating that corresponds to the threshold value of the color difference at that location to determine the hiding thickness of the coating composition.
    Type: Grant
    Filed: February 9, 2011
    Date of Patent: March 6, 2012
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Arun Prakash, John Paul Gallagher, Roger Albert Karmes, Allan Blase Joseph Rodrigues
  • Patent number: 8114481
    Abstract: The present invention is directed to a melamine containing coating composition curable at ambient temperatures and suitable for coating plastic substrates. The present invention is also directed to a process for coating plastic substrates with a melamine containing coating composition curable at ambient temperatures.
    Type: Grant
    Filed: December 3, 2010
    Date of Patent: February 14, 2012
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Henry Stever Tremper, III, Valentina Gordin
  • Patent number: 8103491
    Abstract: This disclosure is directed to a method for matching color and appearance of an object. The method comprise the step of generating a bidirectional reflectance distribution function (BRDF) of a gonioapparent material containing effect flake pigments in a solid medium using limited measurement data.
    Type: Grant
    Filed: June 8, 2011
    Date of Patent: January 24, 2012
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Larry Eugene Steenhoek
  • Patent number: 8062761
    Abstract: This invention relates to a method for forming a multi-layer coating on a vehicle body, comprised of applying primer coating, base coating, and clear coat layers in a wet-on-wet-on-wet manner, and simultaneously curing the applied three layers together in a single baking step. The primer layer comprises a film-forming binder comprising two acrylic polymers, the first being a caprolactone-modified branched acrylic polymer and the second being a caprolactone-modified linear acrylic polymer; and a crosslinking agent selected from aminoplast resin, blocked polyisocyanates, or mixtures thereof, wherein the composition is, essentially free of crosslinked nonaqueous dispersion resin particles or crosslinked microgel resin particles or both. The resulting multi-layered coating has excellent aesthetic appearance, strike-in resistance, chipping resistance, sag resistance, and film build even when formed in a three wet layered application method.
    Type: Grant
    Filed: December 3, 2010
    Date of Patent: November 22, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Isidor Hazan, Jeffery W. Johnson, Robert R. Matheson, Delson J. Trindade, Peter W. Uhlianuk
  • Patent number: 8065314
    Abstract: The present invention is directed to a method for identifying one or more matching formulas for matching color and appearance of a target coating containing effect pigments. The present invention is also directed to a system for identifying one or more matching formulas for matching color and appearance of a target coating containing effect pigments.
    Type: Grant
    Filed: October 1, 2007
    Date of Patent: November 22, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Arun Prakash, Allan Blase Joseph Rodrigues, Judith Elaine Obetz, Wilhelm Kettler, John Paul Gallagher
  • Patent number: 8053541
    Abstract: Cobaloxime derivatives and methods of producing cobaloxime derivatives are disclosed herein. Methods of producing decolorized homo- and co-polymers through polymerization of monomers in presence of the cobaloxime derivatives and decolorization of the produced polymer by exposing the polymer to a sorbent and, optionally, a solvent are also disclosed herein.
    Type: Grant
    Filed: March 2, 2010
    Date of Patent: November 8, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Gregory A. Nikiforov, Alexei A. Gridnev
  • Patent number: 7991596
    Abstract: A computer-implemented process for generating a bidirectional reflectance distribution function (BRDF) of a gonioapparent material containing effect flake pigments in a solid medium using limited measurement data, comprising the following steps: (A) acquiring and inputting into a computing device (1) photometric data and (2) the refractive index of the solid medium of the gonioapparent material; (B) converting any non-linear photometric data from step A) above to linear photometric data; (C) using the illumination angle and the reflective scattering angle associated with the linear photometric data and the refractive index of the medium to calculate corresponding effect flake angles; (D) fitting the linear photometric data and the effect angle data with an equation; (E) calculating the corresponding effect flake angle needed to calculate the BRDF being generated in step (F); and (F) generating the BRDF from the corresponding effect flake angle from step (E) and the equation developed in step (D).
    Type: Grant
    Filed: November 19, 2007
    Date of Patent: August 2, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Larry Eugene Steenhoek
  • Patent number: 7968206
    Abstract: This invention relates to a method for forming a multi-layer coating, comprising sequentially applying a primer surfacer, a basecoat, and a clear coat composition on an automotive substrate in a wet-on-wet-on-wet manner, and simultaneously curing the applied three layers together in a single baking step, wherein the primer surfacer comprises: a film forming binder, a volatile organic liquid carrier, and pigment(s); and the binder contains about: (a) about 30 to 80% by weight, based on the weight of the binder, of a hydroxyl functional polyester resin; (b) about 10 to 30% by weight, based on the weight of the binder, of a crosslinking agent selected from the group consisting of a melamine resin, a blocked polyisocyanate resin, or a mixture thereof; (c) about 10 to 40% by weight, based on the weight of the binder, of a dispersed graft polymer comprising a non-crosslinked core of acrylic polymer which is substantially non-soluble in non-polar organic solvent and, grafted to the core, one end of an acrylic sta
    Type: Grant
    Filed: March 18, 2010
    Date of Patent: June 28, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Jeffery W. Johnson, San C. Yuan
  • Patent number: 7910644
    Abstract: The present disclosure is directed to a coating composition that is capable of producing coatings being sag-free at high coating thicknesses, having excellent adhesion to substrates, and good appearance. This disclosure is further directed to a coating composition comprising components derived from renewable resources.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: March 22, 2011
    Assignee: E.I. du Pont de Nemours & Company
    Inventors: Rajesh Gopalan Saliya, Ayumu Yokoyama, Patricia Mary Ellen Sormani, Sheau-Hwa Ma, Eric C. Houze, Delson Jayme Trindade
  • Patent number: 7911615
    Abstract: An apparatus for inspection of fluids having a fluid analysis cell with a cavity therein enclosed by two light transmitting windows and having a spacer member fixedly positioned therebetween which provides a fluid analysis chamber of fixed pathlength where fluid flows by the windows and preferably wherein the flow laminar and at a uniform shear to provide accurate color measurements. Light transmitting and receiving probes are positioned adjacent to the viewing windows and wherein the faces of each probe are contiguous and flush with the viewing windows but are separated from the flow by the viewing windows, so that transmission measurements can be taken orthogonal to the direction of flow. The apparatus is particularly useful in the manufacture of dispersions and tints used in the manufacture of paints, so that the color of material being made can be accurately matched to a standard color in the wet state with confidence that the color will match in the dry state.
    Type: Grant
    Filed: March 22, 2005
    Date of Patent: March 22, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Anthony J. Martino, Ken Stephen Schermacher, Larry Eugene Steenhoek, Timothy Aaron Snyder, Robert Averitt, Robert E. Bucher
  • Patent number: 7897676
    Abstract: The present invention is directed to two component coating compositions that cure under ambient conditions and more particularly to those having low VOC (volatile organic content) that are suitable for use in automotive refinish and Original Equipment Manufacturing (OEM) applications. The coating composition includes crosslinkable and crosslinking components, wherein the crosslinkable component includes a low polydispersity, low molecular weight copolymer having on an average 2 to 25 functional groups, such as hydroxyl, carboxyl, acetoacetoxy, primary and secondary amine, and epoxy. The copolymer is polymerized from a monomer mixture that includes one or more non-functional acrylate monomers and one or more functional methacrylate monomers provided with the functional groups. The crosslinking component includes polyisocyanate, polyamine, ketimine, melamine, epoxy, polyacid or a combination thereof. The invention is also directed to coating produced from the coating composition.
    Type: Grant
    Filed: November 15, 2010
    Date of Patent: March 1, 2011
    Assignee: E. I. du Pont de Nemours & Company
    Inventors: Robert John Barsotti, Laura Ann Lewin, Carl Brent Douglas, Michael Charles Grady, Donald Albert Paquet, Jr.
  • Patent number: 7888440
    Abstract: The present process is directed to preparation of addition polymers in diluents that are subsequently reactive in coatings during cure, instead of in traditional hydrocarbon solvents. The polymers so prepared can be used as the main film-forming polymer in high solids coating compositions, especially those useful for finishing automobiles and truck exteriors.
    Type: Grant
    Filed: December 7, 2007
    Date of Patent: February 15, 2011
    Assignee: E. I. du Pont de Nemours & Co.
    Inventors: Jeffery W. Johnson, Robert R. Matheson, Donald A. White, Neville Everton Drysdale, Patrick Henry Corcoran, Laura Ann Lewin
  • Patent number: 7888431
    Abstract: A fast hardening clear coating composition for repairing a clear coat/color coat finish or a pigmented mono-coat of a vehicle comprising a film forming binder and an organic liquid carrier, where the binder contains a hydroxyl polymer component comprising (A) hydroxyl-containing acrylic polymer, (B) at least one hydroxyl-terminated component selected from the group consisting of (1) an organic diol having the formula where R1 and R2 are individually selected from the group of hydrogen and an alkyl group having 1, 3-5 carbon atoms and (2) a hydroxyl terminated reaction product of trimethylol propane and a lactone; (C) an organic polyisocyanate crosslinking component, at least portion of which comprises a trimer of isophorone diisocyanate or hexamethylene diisocyanate and the composition further contains, a curing catalyst, of a dialkyl tin aliphatic carboxylate, a tertiary aliphatic mono or diamine, an aliphatic carboxylic acid, and optionally, a zinc or calcium organic acid salt in an effective amount s
    Type: Grant
    Filed: February 7, 2007
    Date of Patent: February 15, 2011
    Assignee: E.I. du Pont de Nemours & Co.
    Inventors: Gia Huynh-Ba, Patrick Henry Corcoran
  • Patent number: 7867569
    Abstract: This invention relates to a method for forming a multi-layer coating on a vehicle body, comprised of applying primer coating, base coating, and clear coat layers in a wet-on-wet-on-wet manner, and simultaneously curing the applied three layers together in a single baking step. The primer layer comprises a film-forming binder comprising two acrylic polymers, the first being a caprolactone-modified branched acrylic polymer and the second being a caprolactone-modified linear acrylic polymer; and a crosslinking agent selected from aminoplast resin, blocked polyisocyanates, or mixtures thereof, wherein the composition is, essentially free of crosslinked nonaqueous dispersion resin particles or crosslinked microgel resin particles or both. The resulting multi-layered coating has excellent aesthetic appearance, strike-in resistance, chipping resistance, sag resistance, and film build even when formed in a three wet layered application method.
    Type: Grant
    Filed: October 5, 2006
    Date of Patent: January 11, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Isidor Hazan, Jeffery W. Johnson, Robert R. Matheson, Delson Jayme Trindade, Peter William Uhlianuk
  • Patent number: 7867617
    Abstract: The present invention is directed to a melamine containing coating composition curable at ambient temperatures and suitable for coating plastic substrates. The present invention is also directed to a process for coating plastic substrates with a melamine containing coating composition curable at ambient temperatures.
    Type: Grant
    Filed: September 25, 2007
    Date of Patent: January 11, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Henry Stever Tremper, III, Valentina Gordin
  • Patent number: 7858692
    Abstract: The present invention is directed to two component coating compositions that cure under ambient conditions and more particularly to those having low VOC (volatile organic content) that are suitable for use in automotive refinish and Original Equipment Manufacturing (OEM) applications. The coating composition includes crosslinkable and crosslinking components, wherein the crosslinkable component includes a low polydispersity, low molecular weight copolymer having on an average 2 to 25 functional groups, such as hydroxyl, carboxyl, acetoacetoxy, primary and secondary amine, and epoxy. The copolymer is polymerized from a monomer mixture that includes one or more non-functional acrylate monomers and one or more functional methacrylate monomers provided with the functional groups. The crosslinking component includes polyisocyanate, polyamine, ketimine, melamine, epoxy, polyacid or a combination thereof. The invention is also directed to coating produced from the coating composition.
    Type: Grant
    Filed: July 11, 2003
    Date of Patent: December 28, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Donald Albert Paquet, Jr., Robert John Barsotti, Laura Ann Lewin, Carl Brent Douglas, Michael Charles Grady