Patents Represented by Attorney, Agent or Law Firm Gary A. Samuels
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Patent number: 6951962Abstract: A water-dispersible oil/grease-sizing and water-sizing agent that provides oil/grease and water-sizing for paper and other cellulosic materials. The agent works effectively for both oil/grease and water sizing at high temperatures. The polymeric agent's key features include a polyamine component which is a repeating monomer unit with cellulose-reactive and fluorinated groups substituted on the polyamine.Type: GrantFiled: April 12, 2002Date of Patent: October 4, 2005Assignee: Hercules IncorporatedInventor: Kyle J. Bottorff
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Patent number: 6908983Abstract: The present invention contemplates a process for forming polyaminoamide polymers formed by the reaction of a dibasic acid/ester with excess amounts of an amine; the intermediate polymer resulting therefrom; a process for synthesizing effective, high solids resins resulting from the reaction of intermediate polymers with an epihalohydrin; and the resultant high, solids resin. These resins may be used as wet strength resins in the papermaking industry.Type: GrantFiled: April 1, 2003Date of Patent: June 21, 2005Assignee: Hercules CorporationInventor: William W. Maslanka
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Patent number: 6586520Abstract: The present invention relates to aqueous compositions comprising component (A) which comprises at least one water-soluble component comprising at least one functional group that undergoes a crosslinking reaction, preferably upon drying and/or heating; and component (B) which comprises at least one film-forming material. In particular the composition is a coating composition comprises: (A) at least one polyamidoamine-epihalohydrin resin; and (B) at least one material selected from flexibilizing materials, crosslink inhibiters and combinations thereof in an amount sufficient to impart a cuttability value of less than about 15 to a substrate coated with the coating composition. Component (B) is preferably at least one polymer comprising repeating units derived from an alkyl halide having at least one double bond and an alkene, such as ethylene vinyl chloride.Type: GrantFiled: July 10, 2000Date of Patent: July 1, 2003Assignee: Hercules IncorporatedInventors: James Canorro, Robert A. Gelman, Matthew B. Howle, Andrea Keys, JoAnne Lefever, William W. Maslanka, Jeffrey I. Melzer, Kevin M. Mottern, Michael T. Raab, William Rodriquez, Richard A. Stuhrke, Jennifer E. Steed, Robert G. Szewczyk
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Patent number: 6558513Abstract: Disclosed is a method of improving the release of paper webs from the surface of press rolls or other paper making or converting equipment by applying to such a surface non-aqueous, non-curing hydrocarbon polymer compositions. The non-curing hydrocarbon polymers have the formula (CH3)3C—[—C(R1)(R2)—C(R3)(R4)—]n—C(R5)═C(CH3)2 (I) wherein R1 through R5 are hydrogen or —CH3, with at least one of R1 through R4 being —CH3, and n is such that the number average molecular weight of such hydrocarbon polymers is from 50 to 3000. They may be hydrogenated. Preferred non-curing hydrocarbon polymers are polybutenes of the formula (CH3)3C—[—CH2—C(CH3)2—]n—CH═C(CH3)2 (II). Preferred compositions comprise at least one such hydrocarbon polymer component having a number average molecular weight from 400 to 700 and a second such component having a number average molecular weight of 100 to 400.Type: GrantFiled: May 29, 2001Date of Patent: May 6, 2003Assignee: Hercules IncorporatedInventors: Jacqueline K. Pease, William A. Hendriks
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Patent number: 6554961Abstract: Processes for rendering a polyamine-epihalohydrin resin storage stable, including processes that prepare a storage stable resin and/or processes that treat resins. A composition containing a polyamine-epihalohydrin resin which includes CPD-forming species can be treated with at least one agent under conditions to at least one of inhibit, reduce and remove the CPD-forming species to obtain a reduced CPD-forming resin so that a composition containing the reduced CPD-forming polyamine-epihalohydrin resin when stored for 2 weeks at 50° C., and a pH of about 2.5 to 3.5 contains less than about 250 ppm dry basis of CPD. The invention is also directed to a gelation storage stable reduced CPD-forming resin so that a composition containing the reduced CPD-forming polyamine-epihalohydrin resin, when stored at pH 1 for 24 hours at 50° C. and measured at 24 hours, produces less than about 1000 ppm dry basis of CPD.Type: GrantFiled: June 12, 2000Date of Patent: April 29, 2003Assignee: Hercules IncorporatedInventors: Richard James Riehle, Anthony J. Allen, Michaela Hofbauer, Alfred Jacques Haandrikman, Ronald Busink, Mark T. Crisp, John James Hoglen, Huai Nan Cheng, Francis J. Carlin, Jr., John Arthur Lapre, Harold Jabloner
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Proteins and polymers for use as pitch and stickies control agents in pulp and papermaking processes
Patent number: 6461477Abstract: Methods for inhibiting the depositions of organic contaminants from pulp in pulp and papermaking systems are disclosed. A combination of a protein and a cationic polymer is added to the pulp or applied to deposition prone surfaces of a papermaking system.Type: GrantFiled: March 22, 2001Date of Patent: October 8, 2002Assignee: Hercules IncorporatedInventors: Duy T. Nguyen, Qu-Ming Gu -
Patent number: 6379501Abstract: Processes for preparing cellulose products, such as paper products which include substantially simultaneously or sequentially adding at least one aluminum compound and at least one silicate to a cellulose slurry, to a cellulose slurry such as a paper slurry. In particular, the present invention is directed to processes for preparing the cellulose products, such as paper products which include substantially simultaneously or sequentially adding at least one aluminum compound and at least one monovalent silicate or water-soluble metal silicate complex to a cellulose slurry, such as a paper slurry. Compositions containing at least one aluminum compound and at least one water-soluble metal silicate, and cellulose products, such as paper products containing at least one water-soluble metal silicate complex.Type: GrantFiled: December 14, 1999Date of Patent: April 30, 2002Assignee: Hercules IncorporatedInventors: Fushan Zhang, Jimei Tong
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Patent number: 6316095Abstract: Fine paper that is sized with a 2-oxetanone alkaline sizing agent and that does not encounter machine feed problems in high speed converting or reprographic machines, including continuous forms bond paper and adding machine paper, processes for converting the paper into envelopes, continuous forms bond paper and adding machine paper, and paper products of the processes.Type: GrantFiled: October 18, 1999Date of Patent: November 13, 2001Assignee: Hercules IncorporatedInventors: Donald K. Black, Kyle J. Bottorff, Clement Linus Brungardt, David Howard Dumas, Susan Merrick Ehrhardt, John Charles Gast, Jian-Jian Zhang
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Patent number: 6294645Abstract: The invention relates to resin systems useful for imparting dry-strength to paper without substantially increasing the paper's wet-strength wherein the resin system comprises a cationic component and an anionic component. The invention also relates to the process for incorporating these resin systems into paper and the paper produced containing the resin systems.Type: GrantFiled: July 25, 1997Date of Patent: September 25, 2001Assignee: Hercules IncorporatedInventors: Anthony J. Allen, Elliott Echt, William W. Maslanka, Jeffrey C. Peters
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Patent number: 6294584Abstract: The present invention provides for methods for fumigating soil containing deleterious organisms such as nematodes. The methods utilize an effective amount of acrolein over sole demand for acrolein which when added to the soil will control the organisms but will not exhibit phytotoxicity towards the existing or future plant life.Type: GrantFiled: January 29, 1999Date of Patent: September 25, 2001Assignee: Betzdearborn Inc.Inventors: Edmund J. Bockowski, Dwight P. Davis
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Patent number: 6273998Abstract: A drainage/retention aid comprising a combination of a) microparticles; and b) a vinylamine copolymer having the general structure: wherein m is from 1-99 mol %, n is from 0 to 50 mol % and o is from 1 to 99 mol %; A is selected from the group consisting of one or more repeating units having the following general structures: and salts thereof wherein p, q and r are mol percentages from 1 to 99, each R1 is independently H or CH3, and X is —CN, —COOR2, —CONR3R4, —OR5, —OCOR6, and mixtures thereof; wherein R2, R3, R4, R5, R6 are independently selected from H or C1 to C4 alkyl; and wherein the vinylamine copolymer has a charge density in a range of from 2 to 24 mEq/g.Type: GrantFiled: August 16, 1994Date of Patent: August 14, 2001Assignee: Betzdearborn Inc.Inventors: Lawrence Lu Kuo, Roger Yiming Leung, Steven R. Prescott, Thord Hassler
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Patent number: 6273997Abstract: Discloses is a method for sizing paper at a pH of about 5.0 to about 8.5 by incorporating a sizing composition consisting essentially of (a) rosin, (b) at least one hydrocarbon resin, (c) a cationic component consisting essentially of a cationic polyamine resin at a weight ration of the rosin/hydrocarbon resin blend to cationic polyamine of about 5:1 to about 1:2, and (d) up to 0.3% alum. The cationic polyamine resin is selected from the group consisting of polyalkyleneamine-epihalohydrin resins, polyalkyleneamine-dicyandiamide-epihalohydrin resins, poly(diallylamine•HCl)-epihalohydrin resins, poly(methyldiallylamine•HCl)-epihalohydrin resins, epihalohydrin-modified polyethyleneimine resins, amine-modified poly(methyldiallylamine•HCl)-epihalohydrin resins, and mixtures thereof.Type: GrantFiled: July 17, 2000Date of Patent: August 14, 2001Assignee: Hercules IncorporatedInventors: Susan M. Ehrhardt, D. Bruce Evans
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Patent number: 6245861Abstract: High vinyl styrene-butadiene rubber is cured through the use of organic peroxides. The organic peroxide may be used singly or in combination with sulfur curing ingredients to cure the high vinyl styrene-butadiene rubber wherein the organic peroxide to sulfur curing ingredient is at a molar ratio of from about 3:1 to about 1:3.Type: GrantFiled: September 10, 1998Date of Patent: June 12, 2001Assignee: Hercules IncorporatedInventor: Jay Bernard Class
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Patent number: 6197919Abstract: This invention relates to resins useful for imparting dry-strength and temporary wet-strength to paper, the process of incorporating these resins into paper and the paper produced containing the resins. The resin comprises an amphoteric polymer produced through polymerization of an anionic monomer, a monomer containing aldehyde functionality and a cationic monomer.Type: GrantFiled: May 30, 1997Date of Patent: March 6, 2001Assignee: Hercules IncorporatedInventors: Mark T. Crisp, Richard J. Riehle
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Patent number: 6197417Abstract: A 2-oxetanone sizing agent that is made from fatty acid(s) containing linoleic acid. Paper that is sized with the 2-oxetanone alkaline sizing agent does not encounter machine feed problems in high speed converting or reprographic machines, so the sizing agent is useful for paper including continuous forms bond paper and adding machine paper, processes for converting the paper into envelopes, continuous forms bond paper and adding machine paper.Type: GrantFiled: December 22, 1998Date of Patent: March 6, 2001Assignee: Hercules IncorporatedInventor: Kyle J. Bottorff
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Patent number: 6175022Abstract: Nucelophilic group, such as alcohol, terminated 2-oxetanone multimers, process of making same by reacting e.g. alcohol and dicarboxylic acid chloride in the presence of triethylamine, and their use for sizing paper.Type: GrantFiled: December 30, 1998Date of Patent: January 16, 2001Assignee: Hercules IncorporatedInventors: Clement L. Brungardt, Richard J. Riehle, Ian Vallance, Jian Jian Zhang
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Patent number: 6162328Abstract: There is disclosed a method for sizing paper by adding to the surface of the paper a sizing composition comprising cellulose reactive and cellulose non-reactive size. The sized paper performs better in ink jet printing than does paper that is the same except that the size composition contains only cellulose reactive size or only cellulose non-reactive size, when the printing is evaluated for at least one property selected from the group consisting of optical density, feathering, wicking, edge roughness and bleed. The sized paper also has higher toner adhesion, a higher coefficient of friction and a lower coefficient of friction bandwidth than does paper that is the same except that the size composition contains only cellulose reactive size. The paper is also capable of performing effectively in tests that measure its convertibility on state-of-the-art converting equipment and its performance on high speed end-use machinery.Type: GrantFiled: September 30, 1997Date of Patent: December 19, 2000Assignee: Hercules IncorporatedInventors: Marco Franco Cenisio, Edwin Rene Hensema, Andrew Mears, Daniel Felix Varnell
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Patent number: 6128785Abstract: A waterproof glove with a shaft incorporating a hand insertion opening and a shaft edge located at the hand insertion opening side and consisting of a shell material. A waterproof cuff sleeve with a lower cuff edge is arranged inside of the shaft such that it lies below the shaft edge by a predetermined underlength and is connected with the shaft edge and with an upper cuff edge that projects over the shaft edge by a predetermined overlength. A sleeve accomodation groove is formed between the shaft and the sleeve cuff so that a lower end area of a wearer's garment sleeve can be inserted into the sleeve accomodation groove. A groove base formed in the lower cuff edge is sealed so that water from the sleeve accomodation groove cannot reach the interior of the glove. The overlength of the cuff sleeve is dimensioned such that when the wearer holds the hand in such a position that water can accumulate in the sleeve groove, water from the sleeve groove cannot reach the upper edge of the cuff.Type: GrantFiled: January 9, 1997Date of Patent: October 10, 2000Assignee: W. L. Gore & Associates, Inc.Inventor: Reinhard Sommeregger
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Patent number: 6123760Abstract: Compositions and methods useful stabilizing dispersions containing paper sizing agents are provided. The dispersions comprise a hydrophobically modified water-soluble polymer having a viscosity average molecular weight less than about 200,000. Dispersions containing sizing agents and other agents for treating paper can be made according to the methods of the invention.Type: GrantFiled: October 28, 1998Date of Patent: September 26, 2000Assignee: Hercules IncorporatedInventor: Daniel Felix Varnell
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Patent number: 6046271Abstract: An aqueous microemulsion polymerization procedure is described in which very small colloidal melt-processible fluoropolymer particles are produced from at least one monomer and optionally TFE. The polymerization procedure involves initiating polymerization by adding a free-radical initiator to a microemulsion of at least one liquid organic compound and at least one free-radical polymerizable monomer to the microemulsion.Type: GrantFiled: May 27, 1997Date of Patent: April 4, 2000Assignee: W. L. Gore & Associates, Inc.Inventors: Huey Shen Wu, Jack Hegenbarth, Xin Kang Chen, Jian Guo Chen