Abstract: The preparation and use of polyurethane-based hot melt adhesives which are cross-linked under the influence of heat comprising reacting(a) a polyisocyanate component containing at least one organic polyisocyanate with(b) a polyol component containing(b1) at least one organic polyhydroxyl compound having a hydroxyl number of 50 to 400 and optionally(b2) at least one organic polyhydroxyl compound having a hydroxyl number above 400 used in a quantity of 0 to 100 hydroxyl equivalents percent, based on component (b1), optionally with the addition of(c) auxiliary agents and additives conventionally used in polyurethane chemistry and/or the technology of adhesives is disclosed.The reaction is characterized in that the equivalent ratio of isocynate groups of component (a) to all the isocyanate reactive groups present in component (b) is from 1:1 to 1.

Abstract: The present invention is directed to a process for the preparation of finely divided solid polyisocyanates containing urea groups by reacting organic polyisocyanates which are free from urea groups with water in an aqueous emulsion, characterized in that the reaction is carried out in the presence of an emulsion- and dispersion-stabilizing compound.

Abstract: Oligoesters having hydroxyl groups and an OH number of from 200 to 600 mg KOH/g are made by reacting a cyclic dicarboxylic acid anhydride in which no halogen is present with a polyfunctional alcohol or dialkanolamine in a molar ratio of from 1:0.5 to 1:1.5 at a temperature of from 50.degree. to 150.degree. C. to form the corresponding dicarboxylic acid semiester and/or semiamide. This semiester and/or semiamide is then alkoxylated with ethylene oxide and/or propylene oxide in the presence of a catalyst at 80.degree. to 150.degree. C. The equivalent ratio of acid groups to alkylene oxide groups is from 1:0.8 to 1:1.7. The catalysts are reaction products of alkoxides with at least 3 C-atoms with ammonia, piperidine, piperazine and/or C.sub.2 -C.sub.6 aliphatic, polyamines, preferably diamines in which all of the NH-functional groups have been alkoxylated. The resultant oligoester may then be reacted with a polyisocyanate optionally in the presence of known additives, such as blowing agents and catalysts.

Abstract: The present invention is directed to an apparatus for the production of back-foamed cushions from cover materials and foam, comprising:(i) a mold comprising an upper mold half and a lower mold half, said lower mold half defining a cavity, the inside surface of which is capable of being covered by said cover material,(ii) a mix head associated with said mold, said mix head capable of introducing foam materials and/or reactants into said mold cavity,(iii) an upper ram provided above the lower mold half, and comprising several segments with contact pressure surfaces, which segments are mounted to be displaceable in guide bores of a supporting frame and wherein springs are associated with said segments, said springs acting on said segments in the direction of said mold cavity, and wherein when said upper ram is in the position of rest, the various contact pressure surfaces are located at different distances from the bottom of said mold cavity, and(iv) wherein said lower mold half is movable towards and away from

Abstract: The present invention is directed to a process for the continuous production of articles or coatings with contours wherein a liquid material is introduced at one end into the mold cavity formed between at least two travelling continous shaping faces, said material being cured in the mold cavity and subsequently removed from the mold, characterized in that (i) the travelling faces are moved downwards at least in the region of the material feed, (ii) the stream of material supplied is moved to and fro transversely to the direction of advance of the faces, and (iii) the quantity of material supplied is controlled so as to fill the mold cavity with a uniform coating and an apparatus for use therein.

Abstract: The present invention is directed to an apparatus for the production of back-foamed covers from cover materials and foam comprising(i) a mold comprising an upper mold half and a lower mold half, the lower mold half having a cavity therein, the inside surface of which is capable of being covered by the cover material,(ii) a mixhead associated with the mold, the mixhead capable of introducing foam materials and/or reactants into the mold cavity,(iii) a pusher bar arranged on a mount for pushing the cover material into the mold cavity and being arranged above the lower mold half, the pusher bar being constructed such that when the bar is pushing the cover material into the mold cavity, a gap is formed between the edge of the mold cavity and the edge of the pusher bar, the gap being less than the thickness of the cover material,(iv) the lower mold half being movable towards and/or away from the pusher bar, and(v) the surface of the pusher bar facing the mold cavity edge being a frictional surface.

Abstract: The present invention is related to polycarbonate molding compositions containing a co-precipitate of a polycarbonate resin and a fluoropolymer. This co-precipitate was found to be suitable as an additive for polycarbonate resins because it offers improved dispersibility with the resin and good flammability performance as well as aesthetic characteristics. The co-precipitate is prepared by first mixing an aqueous dispersion of a fluoropolymer with a polycarbonate solution and then precipitating both using a suitable precipitation agent. After isolation washing and drying the co-precipitate of the invention is suitable for incorporation in a polycarbonate resin optionally with known flame retarding agents. Molded parts prepared from the compositions of the invention are characterized by their improved homogeneity and flame retardance.

Abstract: The present invention is directed to a laminated panel comprising(a) a facing material,(b) a rigid foam adhered to said facing material, and(c) a three dimensional, open mesh structure either attached to or being an integral part of the inside surface of said facing material, said three dimensional, open mesh structure characterized as(i) being produced from relatively long fibers having length to diameter ratios of 50 or more(ii) being sufficiently open so that said foam penetrates through it to said facing material,(iii) being sufficiently stiff so that it will substantially retain its original three dimensional structure in the laminated panel,(iv) being sufficiently adhered to said facing material so that it will not pull away from said facing material during the production of said panel, and(v) having a thickness of at least five times the diameter of the fiber used to produce said mesh structure.

Abstract: The present invention is directed to a mold release composition which is a solution, liquid at room temperature, of(A) at least one zinc salt of a straight chain or branched, saturated or unsaturated aliphatic carboxylic acid containing 8 to 24 carbon atoms in(B) at least one organic compound containing nitrogen which is liquid at room temperature, the solution containing the zinc salt in a quantity of about 10 to 75% by weight, based on the total weight of the composition.The present invention is additionally directed to an isocyanate reactive mixture containing isocyanate reactive compounds and the above described mold release composition. The present invention is further directed to a process for the preparation of molded products based on the above mixture and to the molded products obtained according to this process.

Abstract: Printing inks are described which utilize a unique class of coloring agents which are the reaction products of free NCO group bearing resins and dyestuffs bearing reactive hydrogens. A novel class of such adducts which contain monocarboxylic acid residues are also described. These printing inks, which may also contain traditional pigments, find particular utility in letterpress or offset printing.

Abstract: The present invention relates to an improvement in preparing foamed thermoplastic articles. It was found that a chemical blowing agent concentrate which contains a blowing agent which produces primary amines upon decomposition and additionally contains an anhydride compound which contains at least one cyclic anhydride in its structure, offers surprising advantages over the prior art process in terms of improved impact strength and process flexibility.

Abstract: Polyisocyanate addition products, particularly polyurethane foams having improved flame resistance are obtained by reacting a combustion modified isocyanate with an isocyanate reactive component containing an isocyanate reactive material, a phosphorus containing combustion modifier and a blowing agent. The combustion modified isocyanate is made up of an organic polyisocyanate and a brominated diphenylether.

Abstract: The invention relates to a nozzle for mixing at least two flowable (and in particular foam-forming) reaction components comprising a housing; component supply pipes leading into the housing; a housing bore arranged in the housing having a coaxial outlet channel in its end face; at least one needle casing arranged coaxially in the housing bore; an injection needle guided coaxially in the needle casing; a first chamber arranged between the wall of the housing bore and the needle casing with one of the component supply pipes opening into said first chamber; a second chamber arranged between the needle casing and the injection needle, with another component supply pipe opening into said second chamber; wherein in the closed state, said injection needle forms a tight fit with the internal end face of the needle casing, and the external end face of said needle casing forms a tight fit with the internal end face of the housing bore; and wherein in the open state, said injection needle frees a coaxial nozzle opening

Abstract: Mixtures of water with water-miscible solvent(s) containing suspended, emulsified and/or colloidal impurities are purified by contacting the water-solvent mixture with an at least partially open celled foam containing 1-75 weight percent active pulverulent additives. The liquid and solid phases are then separated. The active pulverulent additives which may be incorporated into the foam by means of a binder or by incorporation in the reactants used to form the foam include active coals, brown coal dust, peat, iron oxides and brown coal coke dust.

Abstract: The present application is concerned with an extrusion process for an elongated stiff but bendable plastic article which finds particular utility in highway delineators. The article has a central lens shape in the cross-section perpendicular to its major axis which is formed by joining two sheets along both of their longitudinal edges. The sheets both have parallel longitudinal edges and are configured in an arc in their shorter dimension. A reverse radius is provided in each longitudinal edge just before it joins the similar edge of the other sheet to allow the article to be bent 90.degree. across its major axis in the plane of its minor axis without significant plastic deformation. The article is constructed by pressing the cooled edges of thermoplastic sheets that can sustain substantial elastic deformation.

Abstract: The present invention is directed to a process for the production of polyisocyanates containing isocyanurate groups by trimerizing a mixture of aliphatic-cycloaliphatic diisocyanates having a sterically unhindered isocyanate group bound to a primary aliphatic carbon atom and a sterically hindered isocyanate group bound to a tertiary carbon atom which forms a part of a cycloaliphatic ring system and 1,6-diisocyanatohexane. The present invention is also directed to the polyisocyanates containing isocyanurate groups produced according to this process and to their use, optionally in blocked form, as an isocyanate component in the production of polyisocyanate polyaddition products, preferably polyurethane lacquers.

Abstract: Metallic surfaces are coated with vitreous enamel by a process in which a cleaning pretreatment of the metal surface to remove surface oil is not required. An enamel-forming material is applied to metal surface coated with a polybutene as the surface oil. The thus-coated metal surface is fired at a temperature sufficiently high to cause the enamel-forming material to form a vitreous enamel coating. The preferred method for applying the enamel-forming material is electrostatic deposition.

Abstract: Molded polyurea foam parts having densities of from 200 to 600 kg/m.sup.3 and a compact skin are made by reacting a polyisocyanate component with a polyamine component in a closed mold at an isocyanate index of from 70 to 130. The polyamine component generally includes (1) an aminopolyether having a molecular weight of from 1800 to 12,000 and 2 to 3 isocyanate reactive groups of which at least 90% are aromatically bound primary and/or secondary amino groups, (2) an aromatic diamine, (3) a foaming agent and optionally (4) known auxiliaries and additives. The polyisocyanate component includes any aromatic di- and/or poly-isocyanate. Parts produced by this process have excellent mechanical properties and a well-defined solid skin.

Abstract: The present invention relates to thermoplastic moulding compositions containing (A) 20 to 80 parts by weight of a polydiorganosiloxane/polycarbonate block copolymer, (B) 70 to 5 parts by weight of a graft polymer in particle form and (C) 5 to 60 parts by weight of a rubber-free, thermoplastic vinyl polymer, the total of parts by weight of components (A)+(B)+(C) being in each case 100 parts by weight, and, if appropriate, other known additives.

Abstract: The invention relates to a simplified, economic process for the production of polyamines by the alkaline hydrolysis of compounds containing terminal aromatic and/or aliphatic isocyanate groups (including modified isocyanates or NCO-prepolymers and semi-prepolymers with NCO-contents of from 0.5 to 40% by weight), with strong aqueous bases, direct isolation of the polyamines from the carbamate stage being possible by thermal carbamate decomposition and/or solvent extraction.The invention also relates to the use of the aromatic and/or aliphatic polyamines containing primary NH.sub.2 -groups obtainable by the process according to the invention for the production of polyurethanes, such as optionally cellular polyurethane plastics and polyurethane foams.