Abstract: A process for substantially decreasing fouling in a refinery unit. The process comprises preheating a feed to said refinery unit reactor zone and there-after introducing the feed into said refinery unit reactor zone for reaction. The feed is preheated for a time and at a temperature sufficient to cause an effective amount of any polymers and/or oligomers contained in feed to decompose or unzip to substantially reduce fouling in the refinery unit.
Type:
Grant
Filed:
December 3, 2002
Date of Patent:
August 10, 2004
Assignee:
ExxonMobil Research and Engineering Company
Abstract: A process for preparing a lubricating oil basestock containing at least about 90% saturates. The process employs a bulk catalyst comprising at least one non-noble Group VIII metal and two Group VIB metals and wherein said metal catalyst further comprises a non-noble Group VIII molybdate in which at least a portion but less than all of molybdenum is replaced by tungsten.
Type:
Grant
Filed:
July 9, 2001
Date of Patent:
July 6, 2004
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Slyvain S. Hantzer, Kenneth Lloyd Riley
Abstract: Hydroconversion process of petroleum and chemical feedstocks using bulk Group VIII/Group VIB catalysts. Preferred catalysts include those comprised of Ni—Mo—W.
Type:
Grant
Filed:
August 22, 2001
Date of Patent:
September 16, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Richard Alan Demmin, Kenneth Lloyd Riley, Stuart Leon Soled, Sabato Miseo
Abstract: Sulfur content of distillate feedstock, which is greater than 3,000 wppm, is reduced using multi-stage hydrodesulfurization by reacting the feestream in stages with reaction zone(s) containing bulk multimetallic catalyst comprised of Group VIII non-noble metal(s) and at least two group VIB metals. The ratio of Group VIB to Group VIII non-noble metals is 10:1 to 1:10.
Type:
Grant
Filed:
August 22, 2001
Date of Patent:
June 24, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Kenneth Lloyd Riley, Darryl Patrick Klein, Zhiguo Hou, Stuart Leon Soled, Michael Charles Kerby, Gary Brice McVicker, Edward Stanley Ellis, Michele Sue Touvelle, Sabato Miseo
Abstract: A process for decreasing fouling in a refinery unit comprising preheating a hydrocarbon feed to a refinery unit reactor zone and thereafter introducing the feed into the refinery unit reactor zone for reaction. The feed contains polymers and oligomers, and is preheated for a time and at a temperature sufficient such that when the feed is introduced into the refinery unit reaction zone for reaction, the combination of the pre-heating and heating attributable to the reaction zone causes at least 85% of the polymers and oligomers contained in the feed to unzip and wherein no more than about 5 wt % coke is formed in said feed during the preheating step.
Type:
Grant
Filed:
March 9, 2001
Date of Patent:
March 18, 2003
Assignee:
ExxonMobil Research and Engineering Company
Abstract: This invention is a fuel composition comprising a major amount of base fuel and at least 3% w/w of an ester additive mixture derivable by reacting together either
(a) (i) a saturated, aliphatic polyhydric alcohol having three or more primary alcohol groups, (ii) a C2-C15 saturated, aliphatic branched chain monohydric alcohol and (iii) a saturated, aliphatic C4-C10 dicarboxylic acid, or
(b) a saturated aliphatic polyhydric alcohol having three or more primary alcohol groups with a C6-C15 saturated, aliphatic straight chain or branched chain monocarboxylic acid, or
(c) a C2-C15 branched chain saturated aliphatic alcohol with a saturated, aliphatic dicarboxylic acid having 6-10 carbon atoms.
The ester additive has a boiling point ≧150° C., a molecular weight ≧200 and an oxygen content ≧13% by weight of said ester additive mixture. The additive significantly reduces particulate emissions from the exhausts of diesel powered engines.
Abstract: A method for mitigating the condensation of liquid hydrocarbons and subsequent coke deposition in refinery reactor units by dew point suppression.
Type:
Grant
Filed:
October 10, 2000
Date of Patent:
June 18, 2002
Assignee:
ExxonMobil Research and Engineering Co.
Inventors:
Nicholas Charles Nahas, Dean Clise Draemel, Richard Edwards Walter, Michael Siskin, Glen Edward Phillips