Patents Represented by Attorney George F. Helfrich
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Patent number: 5128949Abstract: The invention, a method and circuit for controlling the evolution time interval of a laser output pulse, comprises means for pumping a laser medium 13 in a resonator 10 that includes a Q-switch 22 and polarizer 26 that act in combination to control the loss in the resonator 10. A photodiode 11 senses the resulting fluorescence 12 which is applied to a two level Q-switch driver 27 the output of which selectively adjusts the level of loss in the Q-switch 22 and polarizer 26 from high to intermediate to substantially zero loss states to control the evolution time interval of the resulting laser output pulse.Type: GrantFiled: May 31, 1989Date of Patent: July 7, 1992Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventor: Norman P. Barnes
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Patent number: 5118781Abstract: Poly(1,3,4-oxadiazoles) (POX) are prepared by the aromatic nucleophilic displacement reaction of di(hydroxyphenyl)-1,3,4-oxadiazole monomers with activated aromatic dihalides or activated aromatic dinitro compounds. The polymerizations are carried out in polar aprotic solvents such as sulfolane or diphenylsulfone using alkali metal bases such as potassium carbonate at elevated temperatures under nitrogen. The di(hydroxyphenyl)-1,3,4-oxadiazole monomers are synthesized by reacting 4-hydroxybenzoic hydrazide with phenyl-4-hydrobenzoate in the melt and also by reacting aromatic dihydrazides with two moles of phenyl-4-hydroxybenzoate in the melt. This synthetic route has provided high molecular weight POX of new chemical structure, is economically and synthetically more favorable than other routes, and allows for facile chemical structure variation due to the large variety of activated aromatic dihalides which are available.Type: GrantFiled: January 22, 1991Date of Patent: June 2, 1992Assignee: Administrator of the National Aeronautics and Space AdministrationInventors: John W. Connell, Paul M. Hergenrother, Peter Wolf
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Patent number: 5116934Abstract: Polyimidazoles (Pl) are prepared by the aromatic nucleophilic displacement reaction of di(hydroxyphenyl)imidazole monomers with activated aromatic dihalides or activated aromatic dinitro compounds. The reactions are carried out in polar aprotic solvents such as N,N-dimethylacetamide, sulfolane, N-methylpyrrolidinone, dimethylsulfoxide, or diphenylsulfone using alkali metal bases such as potassium carbonate at elevated temperatures under nitrogen. The di(hydroxyphenyl)imidazole monomers are prepared by reacting an aromatic aldehyde with a dimethoxybenzil or by reacting an aromatic dialdehyde with a methoxybenzil in the presence of ammonium acetate. The di(methoxyphenyl)imidazole is subsequently treated with aqueous hydrobromic acid to give the di(hydroxyphenyl)imidazole monomer.Type: GrantFiled: July 19, 1991Date of Patent: May 26, 1992Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: John W. Connell, Paul M. Hergenrother
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Patent number: 5116939Abstract: A process for preparing polyimides having enhanced melt flow properties is described. The process consists of heating a mixture of a high molecular weight poly(amic acid) or polyimide with a low molecular weight amic acid or imide additive in the range of 0.05 to 15% by weight of additive. The polyimide powders so obtained show improved processability, as evidenced by lower melt viscosity by capillary rheometry. Likewise, films prepared from mixtures of polymers with additives show improved processability with earlier onset of stretching by TMA.Type: GrantFiled: August 11, 1987Date of Patent: May 26, 1992Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: James C. Fletcher, J. Richard Pratt, Terry L. St. Clair, Diane M. Stoakley, Harold D. Burks
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Patent number: 5112923Abstract: Imide/arylene ether block copolymers are prepared by reacting anhydride terminated poly(amic acids) with amine terminated poly(arylene ethers) in polar aprotic solvents and chemically or thermally cyclodehydrating the resulting intermediate poly(amic acids). The resulting block copolymers have one glass transition temperature or two, depending upon the particular structure and/or the compatibility of the block units. Most of these block copolymers form tough, solvent resistant films with high tensile properties.Type: GrantFiled: November 21, 1989Date of Patent: May 12, 1992Assignee: Administrator of the National Aeronautics and Space AdministrationInventors: Brian J. Jensen, Paul M. Hergenrother, Robert G. Bass
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Patent number: 5112120Abstract: The invention is a natural flow wing and a method for constructing the same. The method comprises contouring a three-dimensional upper surface and a three-dimensional lower surface of the natural flow wing independently of one another into a prescribed shape. Experimental data and theoretical analysis show that flow and pressure-loading over an upper surface of a wing tend to be conical about an apex of the wing, producing favorable and unfavorable regions of performance based on drag. The method reduces these unfavorable regions by shaping the upper surface such that a maximum thickness near a tip of the natural flow wing moves aft, thereby contouring the wing to coincide more closely with the conical nature of the flow on the upper surface. Nearly constant compressive loading characterizes the flow field over a lower surface of the conventional wing.Type: GrantFiled: July 31, 1990Date of Patent: May 12, 1992Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Richard M. Wood, Steven X. S. Bauer
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Patent number: 5098961Abstract: This invention is a semi-interpenetrating polymer network which includes a high performance thermosetting polyimide having a nadic end group acting as a crosslinking site and a high performance linear thermoplastic polyimide having the following repeating unit: ##STR1## Provided is an improved high temperature matrix resin which is capable of performing at 316.degree. C. in air for several hundreds of hours. This resin has significantly improved toughness and microcracking resistance, excellent processability and mechanical performance, and cost effectiveness.Type: GrantFiled: January 26, 1989Date of Patent: March 24, 1992Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventor: Ruth H. Pater
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Patent number: 5095666Abstract: Disclosed is a device for protecting a roof gutter so that the gutter will remain clean for the free flow of rain water therethrough. The device is a lid in the form of a curb overlying the rim of the gutter along the length thereof. The curb has a raised, porous edge rising above the rim of the gutter and forming a wall for catching and holding debris, while allowing rain water to pass therethrough. Special advantages are obtained when the device additionally includes a strip or toe section which is contiguous with the curb section and overlies that portion of the roof which is adjacent to the gutter. Both the curb section and the toe section of the device are advantageously porous throughout, being made from a meshed fabric.Type: GrantFiled: April 2, 1987Date of Patent: March 17, 1992Inventor: Marvin G. Williams, Jr.
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Patent number: 5093453Abstract: A high-temperature stable, optically transparent, low dielectric aromatic polyimide is prepared by chemically combining equimolar quantities of an aromatic dianhydride reactant and an aromatic diamine reactant, which are selected so that one reactant contains at least one Si(CH.sub.3).sub.2 group in its molecular structure, and the other reactant contains at least one --CH.sub.3 group in its molecular structure. The reactants are chemically combined in a solvent medium to form a solution of a high molecular weight polyamic acid, which is then converted to the corresponding polyimide.Type: GrantFiled: December 12, 1989Date of Patent: March 3, 1992Assignee: Administrator of the National Aeronautics and Space AdministrationInventors: Anne K. St. Clair, Terry L. St. Clair, J. Richard Pratt
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Patent number: 5081198Abstract: A tough, high performance polyimide is provided by reacting a triple bond conjugated with an aromatic ring in a bisethynyl compound with the active double bond in a compound containing a double bond activated toward the formation of a Diels-Adler type adduct, especially a bismaleimide, a biscitraconimide, or a benzoquinone, or mixtures thereof. Addition curing of this product produces a highly linear polymeric structure and heat treating the highly linear polymeric structure produces a thermally-stable aromatic addition-type thermoplastic polyimide, which finds utility in the preparation of molding compounds, adhesive compositions, and polymer matrix composites.Type: GrantFiled: November 13, 1989Date of Patent: January 14, 1992Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventor: Ruth H. Pater
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Patent number: 5066811Abstract: Polyimidazoles (Pl) are prepared by the aromatic nucleophilic displacement reaction of di(hydroxyphenyl)imidazole monomers with activated aromatic dihalides or activated aromatic dinitro compounds. The reactions are carried out in polar aprotic solvents such as N,N-dimethylacetamide, sulfolane, N-methylpyrroldinone, dimethylsulfoxide, or diphenylsulfone using alkali metal bases such as potassium carbonate at elevated temperature under nitrogen. The di(hydroxyphenyl)imidazole monomers are prepared by reacting an aromatic aldehyde with a dimethoxybenzil or by reacting an aromatic dialdehyde with a methoxybenzil in the presence of ammonium acetate. The di(methoxyphenyl)imidazole is subsequently treated with aqueous hydrobromic acid to give the di(hydroxyphenyl)imidazole monomer.Type: GrantFiled: April 12, 1990Date of Patent: November 19, 1991Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: John W. Connell, Paul M. Hergenrother
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Patent number: 5064111Abstract: The invention is an apparatus and method for wire splicing using an explosive joining process. The apparatus consists of a prebent, U-shaped strap of metal that slides over prepositioned wires. A standoff means separates the wires from the strap before joining. An adhesive means holds two ribbon explosives in position centered over the U-shaped strap. A detonating means connects to the ribbon explosives. The process involves spreading strands of each wire to be joined into a flat plane. The process then requires alternating each strand in alignment to form a mesh-like arrangement with an overlapped area. The strap slides over the strands of the wires, and the standoff means is positioned between the two surfaces. The detonating means then initiates the ribbon explosives that drive the strap to accomplish a high velocity, angular collision between the mating surfaces. This collision creates surface melts and collision bonding results in electron-sharing linkups.Type: GrantFiled: October 2, 1990Date of Patent: November 12, 1991Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Laurence J. Bement, Anne C. Kushnick
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Patent number: 5061783Abstract: The process of the present invention includes first treating a polyamide-acid (such as LARC-TPI polyamide-acid) in an amide-containing solvent (such as N-methylpyrrolidone) with an aprotic organic base (such as triethylamine), followed by dehydrating with an organic dehydrating agent (such as acetic anhydride). The level of crystallinity in the linear aromatic polyimide so produced is maximized without any degradation in the molecular weight thereof.Type: GrantFiled: April 30, 1990Date of Patent: October 29, 1991Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventor: Terry L. St. Clair
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Patent number: 5058591Abstract: A device and method rapidly quantifying the relative distention of the bladder of a human subject are disclosed. Ultrasonic transducer 1, which is positioned on subject 2 in proximity to bladder 16, is excited by pulser 3A under command of microprocessor 4 to launch an acoustic wave into patient 2. This wave interacts with bladder walls 12,13 and is reflected back to ultrasonic transducer 1, whence it is received, amplified, and processed by receiver 3B. The resulting signal is digitized by analog-to-digital converter 5 under command of microprocessor 4, and is stored in data memory 6B. The software in microprocessor 4 determines the relative distention of bladder 16 as a function of the propagated ultrasonic energy; and based on programmed scientific measurements and past history with the specific subject as contained in program memory 6A, sends out a signal to turn on any or all of the audible alarm 7, the visible alarm 8, the tactile alarm 9, and the remote wireless alarm 10.Type: GrantFiled: May 26, 1989Date of Patent: October 22, 1991Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: John A. Companion, Joseph S. Heyman, Beth A. Mineo, Albert R. Cavalier, Travis N. Blalock
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Patent number: 5057338Abstract: This invention is a process for the uniform application of polymer powder particles to a filamentary material in a continuous manner to form a uniform composite prepreg material. A tow of the filamentary material is fed under carefully controlled tension into a spreading unit, where it is spread pneumatically into an even band. The spread filamentary tow is then coated with polymer particles from a fluidized bed, after which the coated filamentary tow is fused before take-up on a package for subsequent utilization. This process produces a composite prepreg uniformly without imposing severe stress on the filamentary material, and without requiring long, high temperature residence times for the polymer.Type: GrantFiled: May 16, 1990Date of Patent: October 15, 1991Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Robert M. Baucom, John J. Snoha, Joseph M. Marchello
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Patent number: 5052817Abstract: An apparatus for testing ignitability of an initiator includes a body having a central cavity, initiator holder for holding the initiator over the central cavity of the body, an ignition material holder disposed in the central cavity of the body and having a cavity facing the initiator holder which receives a measured quantity of ignition material to be ignited by the initiator and a chamber in communication with the cavity of the ignition material and the central cavity of the body, and a measuring system for analyzing pressure characteristics generated by ignition of the ignition material by the initiator. The measuring system includes at least one transducer coupled to an oscillograph for recording pressure traces generated by ignition.Type: GrantFiled: October 4, 1990Date of Patent: October 1, 1991Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Laurence J. Bement, James W. Bailey, Morry L. Schimmel
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Patent number: 5053341Abstract: A tissue simulating gel and a method for preparing the tissue simulating gel are disclosed. The tissue simulating gel is prepared by a process using water, gelatin, ethylene glycol, and a cross-linking agent. In order to closely approximate the characteristics of the type of tissue being simulated, other material has been added to change the electrical, sound conducting, and wave scattering properties of the tissue simulating gel. The result of the entire process is a formulation that will not melt at the elevated temperatures involved in hyperthermia medical research. Furthermore, the tissue simulating gel will not support mold or bacterial growth, is of a sufficient mechanical strength to maintain a desired shape without a supporting shell, and is non-hardening and non-drying.Type: GrantFiled: October 6, 1989Date of Patent: October 1, 1991Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventor: John A. Companion
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Patent number: D326989Type: GrantFiled: May 30, 1989Date of Patent: June 16, 1992Assignee: The Tri-V CorporationInventors: Frank R. Button, Alvin E. Taylor
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Patent number: D327402Type: GrantFiled: May 30, 1989Date of Patent: June 30, 1992Assignee: The TRI-V CorporationInventors: Frank R. Button, Alvin E. Taylor
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Patent number: D328847Type: GrantFiled: May 30, 1989Date of Patent: August 25, 1992Assignee: Tri-V CorporationInventors: Frank R. Button, Alvin E. Taylor