Abstract: Copolyester plasticizers useful for the formulation of PVC refrigerator gaskets which exhibit improved resistance to migration and marring and improved processing characteristics are provided. The copolyesters are obtained by reacting an acid component consisting of a mixture of a benzene dicarboxylic acid (or anhydride or methyl ester thereof) and an aliphatic C.sub.5-12 saturated dicarboxylic acid (or methyl ester) with an alcohol component consisting of a mixture of neopentyl glycol and ethylene glycol. An aliphatic C.sub.6-13 saturated monofunctional alcohol or aliphatic C.sub.6-13 saturated monocarboxylic acid terminating agent is also included in the reaction.

Abstract: A composition of matter is disclosed comprising a saturated elastomer having an active halogen-containing cure site, sulfur and a quaternary ammonium salt of a mineral acid. The invention also provides a process for vulcanizing the above composition.

Abstract: An improved emulsion polymerization process for the preparation of high Mooney viscosity terpolymers of ethylene, vinyl acetate, and reactive halogen-containing monomers is provided. In the process, the reactive halogen-containing monomer is added during the polymerization. The ethylene pressure may also be increased during the polymerization.

Abstract: Copolyester plasticizers useful for the formulation of PVC refrigerator gaskets which exhibit improved resistance to migration and marring and improved processing characteristics are provided. The copolyesters are obtained by reacting an acid component consisting of a mixture of a benzene dicarboxylic acid (or anhydride or methyl ester thereof) and an aliphatic C.sub.5-12 saturated dicarboxylic acid (or methyl ester) with an alcohol component consisting of a mixture of neopentyl glycol and ethylene glycol. An aliphatic C.sub.6-13 saturated monofunctional alcohol or aliphatic C.sub.6-13 saturated monocarboxylic acid terminating agent is also included in the reaction.

Abstract: A composition of matter is disclosed comprising a saturated elastomer having an active halogen-containing cure site, sulfur and a quaternary ammonium salt of a mineral acid. The invention also provides a process for vulcanizing the above composition.

Abstract: A composition of matter is disclosed comprising (1) a saturated elastomer having an active halogen-containing cure site, (2) a soap/sulfur cure system, and (3) a phase transfer compound. The phase transfer catalyst comprises a quaternary ammonium or phosphonium salt of a mineral acid or an alkylene oxide polymer. The phase transfer compounds accelerate soap/sulfur cures and make it possible to obtain acceptable cure rates with higher fatty acid soaps.

Abstract: This invention relates to an efficient cis-to-trans isomerization of 1,4-dihalobutene-2 by means of a thiol or hydrogen bromide or hydrogen chloride catalyzed reaction.

Abstract: Aqueous compositions suitable for the treatment of alfalfa are provided herein. The aqueous compositions contain a hydrocarbon, a lower alkyl ester of a fatty acid and/or alkali metal carbonate. A process for applying said aqueous compositions to the alfalfa at the time of cutting to reduce drying time is also provided.

Abstract: Improved wax compositions suitable for the preparation of candles, as the sole fuel component or as an overdip applied to a paraffin or paraffin/fatty acid candle, are provided. The compositions of this invention are a blend of a paraffin, a C.sub.16 or C.sub.18 saturated fatty acid or mixture of said fatty acids, and an alpha-alkyl-branched carboxylic acid obtained by the free radical addition of a C.sub.20-44 alpha-olefin or alpha-olefin mixture and a carboxylic acid having 3 to 36 carbon atoms. A process for improving the surface characteristics of paraffin or paraffin/fatty acid candles by applying the present wax compositions thereto as an overdip and the resulting improved candles obtained therefrom are also disclosed.

Abstract: A versatile current source inverter power supply for an ozonator in which a gating control circuit controls the gating of a thyristor bridge inverter power supply in a manner in which the output current to the ozonator is controlled and regulated. The current source inverter power supply circuit includes a DC/AC thyristor bridge inverter circuit coupled at its input terminals to a direct current power source and at its output terminals to an electrical network which includes the capacitative ozonator load. The thyristor bridge inverter includes a first pair of thyristors and diodes coupled to conduct current in a first direction through the electrical network, and a second pair of thyristors and diodes coupled to conduct current in a second, opposite direction through the electrical network. The electrical network includes a step up high voltage transformer, with its primary winding coupled to the thyristor bridge inverter and its secondary winding coupled to the ozonator load.

Abstract: Coal-water slurries containing a rheological additive are disclosed. The rheological additives employed for the preparation of the present coal-water slurries are ester products obtained from the reaction of a polycarboxylic organic acid with two or more hydroxylic compounds. Salts of these reaction products may also be employed. The rheological additive is employed in an amount from about 0.1 to about 4 percent by weight of the slurry, the slurry having from about 60 to about 80 percent by weight solids, the balance being water.

Abstract: This invention relates to compounds of the general structure ##STR1## wherein R and R.sup.1 are lower alkyl having from 1 to 2 carbon atoms useful as fragrance additives and to the fragrance compositions containing the same.

Abstract: Improved wax compositions suitable for the preparation of candles, as the sole fuel component or as an overdip applied to a paraffin or paraffin/fatty acid candle, are provided. The compositions of this invention are a blend of a paraffin, a C.sub.16 or C.sub.18 saturated fatty acid or mixture of said fatty acids, and an alpha-alkyl-branched carboxylic acid obtained by the free radical addition of a C.sub.20-44 alpha-olefin or alpha-olefin mixture and a carboxylic acid having 3 to 36 carbon atoms. A process for improving the surface characteristics of paraffin or paraffin/fatty acid candles by applying the present wax compositions thereto as an overdip and the resulting improved candles obtained therefrom are also disclosed.

Abstract: This invention relates to a two-step synthesis of high purity dialkyl 2-vinyl-cyclopropane-1,1-dicarboxylate in which a mixture of trans- and cis-1,4-dihalobutene-2 is first isomerized to essentially trans-1,4-dihalobutene-2 followed immediately by cyclocondensing the resultant trans-1,4-dihalobutene-2 with a malonic ester in the presence of an alcoholic solution of a metallic alkoxide.

Abstract: A versatile pulsed voltage resonant inverter power supply for an ozonator which results in the efficient operation thereof. A resonant inverter ozonator power supply comprises a DC power source and a DC/AC thyristor inverter coupled at its outputs to the primary winding of a high voltage transformer. The ozonator load is connected across the secondary winding of transformer and provides a discharge path during each high frequency cycle. First and second embodiments of control circuits are disclosed for generating gating control signals for the thyristors. The switching frequency at which the thyristors are triggered is selected to be lower than the circuit resonant frequency in order that the load voltage supplied by the inverter is substantially pulsed, and a pulse burst modulation mode is also disclosed.

Abstract: This invention relates to the preparation of dialkyl-2-vinylcyclopropane-1,1-dicarboxylates involving the addition of an alcoholic metallic alkoxide to an organic solution of a 1,4-dihalobutene-2 and a malonic ester.

Abstract: The catalytic thermal depolymerization of polyesters to produce macrocyclic esters suitable for fragrance applications is carried out using an olefin polymer. High yields of the corresponding macrocyclic ester are produced at high rates while substantially eliminating reactor fouling and the formation of undesirable by-products. The depolymerization is most advantageously conducted using polyethylene.

Abstract: Liquid copolyesters useful as plasticizers for vinyl resins are provided. The copolyesters are obtained by the esterification of specific aliphatic dicarboxylic acid ester mixtures with 1,4-butanediol and an aliphatic saturated monofunctional alcohol. The copolyesters have acceptably low solidification points; they are resistant to hydrocarbon extraction; and they impart good low-temperature flexibility to PVC compositions plasticized therewith.

Abstract: Liquid copolyesters useful as plasticizers for vinyl resins are provided. The copolyesters are obtained by the esterification of specific aliphatic dicarboxylic acid ester mixtures with 1,4-butanediol and an aliphatic saturated monofunctional alcohol. The copolyesters have acceptably low solidification points; they are resistant to hydrocarbon extraction; and they impart good low-temperature flexibility to PVC compositions plasticized therewith.

Abstract: Pillar candles which upon burning develop a decorative, aesthetically pleasing, free-standing shell having a filigree or lace-like pattern are provided. The candles consist of a fatty acid fuel composition, predominantly stearic acid and palmitic acid, and a 27-45 ply flat cotton wick. To obtain the desired decorative effect, the ratio of wick size to candle diameter is maintained at 12 to 19 plies per inch.